EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
1
APPENDIX
E.
QUALITY
ASSURANCE/
QUALITY
CONTROL
SUMMARY,
TECHNICAL
BACKGROUND
DOCUMENT:
MERCURY
WASTES,
EVALUATION
OF
TREATMENT
OF
BULK
ELEMENTAL
MERCURY,
FINAL
REPORT
FEBRUARY
8,
2002
SUBMITTED
TO:
U.
S.
ENVIRONMENTAL
PROTECTION
AGENCY
ARIEL
RIOS
BUILDING
OFFICE
OF
SOLID
WASTE
1200
PENNSYLVANIA
AVENUE,
N.
W.
WASHINGTON,
D.
C.
20460
SUBMITTED
BY:
SCIENCE
APPLICATIONS
INTERNATIONAL
CORPORATION
ENGINEERING
AND
ENVIRONMENTAL
MANAGEMENT
GROUP
11251
ROGER
BACON
DRIVE
RESTON,
VIRGINIA
20190
EPA
CONTRACT
NO.
68­
W­
98­
025
WORK
ASSIGNMENT
NO.
3­
8
SAIC
PROJECT
NO.
06­
0758
 
08­
1373­
000
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
2
APPENDIX
E.
QUALITY
ASSURANCE/
QUALITY
CONTROL
SUMMARY
Raw
data
from
the
analytical
instrument
is
reported
to
the
nearest
one­
hundredth
of
a
µ
g/
L
(
i.
e.,
0.01),
and
the
calibration
standards
vary
from
0.50
to
40.00
µ
g/
L.
Therefore,
to
avoid
extrapolation
outside
of
the
calibration
range,
the
reported
detection
limit
is
0.50
µ
g/
L
and
any
sample
that
exceeds
40.00
µ
g/
L
is
diluted
and
rerun.
Based
on
the
calibration
standards
and
instrument
measurement,
raw
data
will
have
as
few
as
2
and
as
many
as
4
significant
figures.
Reported
results
are
rounded
to
3
significant
figures,
which
will
be
dropped
to
2
significant
figures
when
the
result
is
less
than
1.00
µ
g/
L.
This
convention
is
carried
through
when
data
are
reported
as
mg/
L,
rather
than
µ
g/
L.
Several
examples
follow:
1)
a
raw
data
result
of
3.45
µ
g/
L
is
associated
with
a
dilution
factor
of
1,000
and
the
result
may
be
reported
as
3,450
µ
g/
L
or
3.45
mg/
L;
2)
a
raw
data
result
of
0.76
µ
g/
L
is
associated
with
a
dilution
factor
of
1,000
and
the
result
may
be
reported
as
760
µ
g/
L
or
0.76
mg/
L;
and
3)
a
raw
data
result
of
21.34
is
associated
with
a
dilution
factor
of
1,000
and
the
result
may
be
reported
as
21,300
µ
g/
L
or
21.3
mg/
L.

E.
1
Laboratory
QA/
QC
for
EEI
Work
Order
01­
01­
549
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
Results
of
this
review
are
provided
in
Table
E­
1.

A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L.
Measurement
of
these
standards
produced
a
linear
trend
with
an
acceptable
correlation
coefficient
of
0.999817.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
(
recovery
was
101
%
for
the
initial
sample
and
103
to
108
%
for
continuing
samples),
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
value
of
11.00
µ
g/
L
(
110
%
of
the
known
value)
is
within
acceptable
limits.

The
sample
digestion
log
indicates
the
initial
sample
dilution
factors,
0.2
g
of
solid
per
20
mL
of
digestion
reagent
and
20
mL
of
TCLP
leachate
per
20
mL
of
digestion
reagent.
Additional
notes
in
the
laboratory
QC
report
indicate
the
reagents
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors
of
1,000,000
for
the
solid
samples
and
100,000
for
the
TCLP
leachate.
The
precision
and
accuracy
summary
provided
for
one
of
the
digested
solid
samples
(
05A,
05A­
duplicate,
05A­
spike)
and
one
of
the
TCLP
leachates
(
01A,
01A­
duplicate,
01A­
spike)
show
acceptable
precision
(
±
25
%)
and
accuracy
results
(
75
 
125
%).
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
3
Table
E­
1
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
01­
549
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

ICV
5.00
5.05
101
na
na
na
CCV1
5.00
5.15
103
na
na
na
CCV2
5.00
5.17
103
na
na
na
CCV3
5.00
5.29
106
na
na
na
CCV4
5.00
5.46
109
na
na
na
CCV5
5.00
5.42
108
na
na
na
LCS
10.00
11.00
110
na
na
na
ICB
unknown
0.05
na
na
na
<
0.50
CCB1
unknown
 
0.05
na
na
na
<
0.50
CCB2
unknown
 
0.09
na
na
na
<
0.50
CCB3
unknown
 
0.10
na
na
na
<
0.50
CCB4
unknown
0.03
na
na
na
<
0.50
CCB5
unknown
 
0.01
na
na
na
<
0.50
01A
na
1.71
na
6.65
100,000
171,000
01A­
duplicate
na
1.60
na
100,000
160,000
01A­
spike
5.00
5.31
106
na
na
na
05A
na
3.04
na
 
18.0
1,000,000
(
3,040,000)

05A­
duplicate
na
3.64
na
1,000,000
(
3,640,000)

05A­
spike
5.00
5.32
106
na
na
na
E.
2
Laboratory
QA/
QC
for
EEI
Work
Order
01­
03­
491
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
The
raw
data
logs
indicate
that
the
total
mercury
and
TCLP
results
were
run
in
separate
batches.
Results
of
this
review
are
provided
in
Table
E­
2.

A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L
for
each
of
the
runs.
Measurement
of
these
standards
produced
a
linear
trend
with
an
acceptable
correlation
coefficient
of
0.999720
for
the
TCLP
run
and
0.999733
for
the
total
mercury
run.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
for
both
runs,
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
values
are
within
acceptable
limits.
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
4
Table
E­
2
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
03­
491
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

TCLP
Run
ICV
5.00
4.94
98.8
na
na
na
CCV1
5.00
5.02
100
na
na
na
CCV2
5.00
4.98
99.6
na
na
na
CCV3
5.00
5.05
101
na
na
na
LCS
10.00
9.55
95.5
na
na
na
ICB
unknown
0.04
na
na
na
<
0.50
CCB1
unknown
0.05
na
na
na
<
0.50
CCB2
unknown
0.16
na
na
na
<
0.50
CCB3
unknown
0.19
na
na
na
<
0.50
01A
na
11.28
na
0.18
10,000
113,000
01A­
duplicate
na
11.26
na
10,000
113,000
01A­
spike
5.00
5.27
105
na
na
na
Total
Mercury
Run
ICV
5.00
5.20
104
na
na
na
CCV1
5.00
5.06
101
na
na
na
CCV2
5.00
5.00
100
na
na
na
LCS
10.00
9.55
95.5
na
na
na
ICB
unknown
0.05
na
na
na
<
0.50
CCB1
unknown
0.08
na
na
na
<
0.50
CCB2
unknown
0.10
na
na
na
<
0.50
05A
na
5.27
na
21.0
1,000,000
(
5,270,000)

05A­
duplicate
na
4.27
na
1,000,000
(
4,270,000)

05A­
triplicate
na
4.45
na
na
1,000,000
(
4,450,000)

05A­
spike
5.00
5.19
104
na
na
na
The
sample
digestion
log
indicates
the
initial
sample
dilution
factors,
0.2
g
of
solid
per
20
mL
of
digestion
reagent
and
20
mL
of
TCLP
leachate
per
20
mL
of
digestion
reagent.
Additional
notes
in
the
laboratory
QC
report
indicate
the
reagents
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors
of
1,000,000
for
the
solid
samples
and
10,000
for
the
TCLP
leachate.
The
precision
and
accuracy
summary
provided
for
one
of
the
digested
solid
samples
(
05A,
05A­
duplicate,
05A­
spike)
and
one
of
the
TCLP
leachates
(
01A,
01A­
duplicate,
01A­
spike)
show
acceptable
precision
(
±
25
%)
and
accuracy
results
(
75
 
125
%).
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
5
E.
3
Laboratory
QA/
QC
for
EEI
Work
Order
01­
05­
904
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
Results
of
this
review
are
provided
in
Table
E­
3.

Table
E­
3.
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
05­
904
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

ICV
5.00
4.95
99.0
na
na
na
CCV1
5.00
4.85
97.0
na
na
na
CCV2
5.00
4.83
96.6
na
na
na
CCV3
5.00
4.87
97.4
na
na
na
LCS
10.00
10.42
104
na
na
na
ICB
unknown
0.06
na
na
na
<
0.50
CCB1
unknown
0.03
na
na
na
<
0.50
CCB2
unknown
0.03
na
na
na
<
0.50
CCB3
unknown
0.08
na
na
na
<
0.50
08A
na
6.60
na
1.65
1,000
6,600
08A­
duplicate
na
6.71
na
1,000
6,710
08A­
spike
10.00
9.82
98.2
na
na
na
A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L.
Measurement
of
these
standards
produced
a
linear
trend
with
an
acceptable
correlation
coefficient
of
0.99995.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
(
recovery
was
99.0
%
for
the
initial
sample
and
96.6
to
97.4
%
for
continuing
samples),
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
value
of
10.42
µ
g/
L
(
104
%
of
the
known
value)
is
within
acceptable
limits.

A
sample
digestion
log
identifies
the
reagents
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors.
The
precision
and
accuracy
summary
provided
for
one
of
the
digested
solid
samples
(
08A,
08A­
duplicate,
08A­
spike)
shows
acceptable
precision
(
±
25
%)
and
accuracy
results
(
75
 
125
%).

E.
4
Laboratory
QA/
QC
for
EEI
Work
Order
01­
07­
213
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
The
raw
data
logs
indicate
that
the
solids
were
run
in
a
single
batch
and
constant
pH/
TCLP
results
were
run
in
two
batches.
Results
of
this
review
are
provided
in
Table
E­
4.
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
6
Table
E­
4.
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
07­
213
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)
Solids
ICV
5.00
4.99
99.8
na
na
na
CCV1
5.00
4.67
93.4
na
na
na
CCV2
5.00
4.94
98.8
na
na
na
CCV3
5.00
4.94
98.8
na
na
na
CCV4
5.00
4.88
97.6
na
na
na
LCS
(
3,940)
34.51
85.0
na
97.1
L/
kg
(
3,350)
ICB
unknown
0.02
na
na
na
<
0.50
CCB1
unknown
0.07
na
na
na
<
0.50
CCB2
unknown
 
0.14
na
na
na
<
0.50
CCB3
unknown
 
0.02
na
na
na
<
0.50
CCB4
unknown
 
0.10
na
na
na
<
0.50
10A
na
9.07
na
8.25
913,000
(
8,280,000)
10A­
duplicate
na
9.85
na
917,000
(
9,030,000)
10A­
spike
10.00
11.94
119
na
na
na
Constant
pH/
TCLP
leachates
ICV
5.00
4.87
97.4
na
na
na
CCV1
5.00
4.70
94.0
na
na
na
CCV2
5.00
4.62
92.4
na
na
na
LCS
10.00
9.16
91.6
na
na
na
ICB
unknown
 
0.02
na
na
na
<
0.50
CCB1
unknown
0.03
na
na
na
<
0.50
CCB2
unknown
0.05
na
na
na
<
0.50
13A
na
9.70
na
2.85
100
970
13A­
duplicate
na
9.98
na
100
998
13A­
spike
10.00
9.36
93.6
na
na
na
Constant
pH/
TCLP
leachates
ICV
5.00
4.90
98.0
na
na
na
CCV1
5.00
4.92
98.4
na
na
na
CCV2
5.00
5.14
103
na
na
na
CCV3
5.00
5.45
109
na
na
na
LCS
10.00
9.49
94.9
na
na
na
ICB
unknown
0.03
na
na
na
<
0.50
CCB1
unknown
0.06
na
na
na
<
0.50
CCB2
unknown
0.08
na
na
na
<
0.50
CCB3
unknown
0.16
na
na
na
<
0.50
21A
na
5.93
na
4.66
10
59.3
21A­
duplicate
na
5.66
na
10
56.6
21A­
spike
40.00
21.30
107*
na
2
42.6
*
Percent
recovery
calculated
with
the
reported
value
and
true
value,
due
to
the
dilution
factor.

A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L
for
each
of
the
runs.
Measurement
of
these
standards
produced
a
linear
trend
with
an
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
7
acceptable
correlation
coefficient
of
0.999713
for
the
solid
run
and
0.999642
and
0.999632
for
the
constant
pH/
TCLP
runs.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
for
both
runs,
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
values
are
within
acceptable
limits.

The
sample
digestion
log
indicates
the
initial
sample
dilution
factors,
0.2
g
of
solid
per
20
mL
of
digestion
reagent
and
20
mL
of
TCLP
leachate
per
20
mL
of
digestion
reagent.
Additional
notes
in
the
laboratory
QC
report
indicate
the
reagents
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors
for
the
solid
and
leachate
samples.
The
precision
and
accuracy
summary
provided
for
one
of
the
digested
solid
and
leachate
samples
show
acceptable
precision
(
±
25%)
and
accuracy
results
(
75
 
125
%).

E.
5
Laboratory
QA/
QC
for
EEI
Work
Order
01­
08­
371
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
The
raw
data
logs
indicate
that
the
solids
were
run
in
two
batches
and
constant
pH/
TCLP
results
were
run
in
two
batches.
Results
of
this
review
are
provided
in
Table
E­
5.

A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L
for
each
of
the
runs.
Measurement
of
these
standards
produced
a
linear
trend
with
an
acceptable
correlation
coefficient
of
0.999848
and
0.999613
for
the
solid
runs
and
0.99983
and
0.999668
for
the
constant
pH/
TCLP
runs.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
for
both
runs,
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
values
are
within
acceptable
limits.

The
sample
digestion
log
indicates
the
reagents
used
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors
for
the
solid
and
leachate
samples.
The
precision
and
accuracy
summary
provided
for
one
of
the
digested
solid
and
leachate
samples
show
acceptable
precision
(
±
25%)
and
accuracy
results
(
75
 
125
%).
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
8
Table
E­
5
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
08­
371
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

Constant
pH/
TCLP
leachates
ICV
5.00
5.05
101
na
na
na
CCV1
5.00
5.22
104
na
na
na
CCV2
5.00
5.35
107
na
na
na
CCV3
5.00
5.05
101
na
na
na
LCS
10.00
10.12
101
na
na
na
ICB
unknown
0.07
na
na
na
<
0.50
CCB1
unknown
0.10
na
na
na
<
0.50
CCB2
unknown
0.20
na
na
na
<
0.50
CCB3
unknown
0.06
na
na
na
<
0.50
01A
na
12.79
na
0.86
1
12.8
01A­
duplicate
na
12.90
na
1
12.9
01A­
spike
5.00
4.20
84.0
na
na
na
Constant
pH/
TCLP
leachates
ICV
5.00
4.86
97.2
na
na
na
CCV1
5.00
5.08
102
na
na
na
CCV2
5.00
5.05
101
na
na
na
CCV3
5.00
4.91
98.2
na
na
na
LCS
10.00
10.14
101
na
na
na
ICB
unknown
0.04
na
na
na
<
0.50
CCB1
unknown
0.09
na
na
na
<
0.50
CCB2
unknown
0.04
na
na
na
<
0.50
CCB3
unknown
0.04
na
na
na
<
0.50
29A
na
2.34
na
11.8
1,000,000
2,340,000
29A­
duplicate
na
2.08
na
1,000,000
2,080,000
29A­
spike
10.00
10.01
100
na
na
na
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
9
Table
E­
5.
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
08­
371
(
Continued)

Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

Solids
ICV
5.00
5.25
105
na
na
na
CCV1
5.00
5.39
108
na
na
na
CCV2
5.00
4.91
98.2
na
na
na
CCV3
5.00
4.91
98.2
na
na
na
CCV4
5.00
4.74
94.8
na
na
na
LCS
(
3,940)
36.99
93.9
na
100
L/
kg
(
3,700)

ICB
unknown
0.03
na
na
na
<
0.50
CCB1
unknown
 
0.01
na
na
na
<
0.50
CCB2
unknown
0.01
na
na
na
<
0.50
CCB3
unknown
0.04
na
na
na
<
0.50
CCB4
unknown
0.05
na
na
na
<
0.50
18A
na
3.83
na
10.6
500,000
(
1,920,000)

18A­
duplicate
na
4.26
na
500,000
(
2,130,000)

18A­
spike
10.00
9.69
96.9
na
na
na
Solids
ICV
5.00
5.06
101
na
na
na
CCV1
5.00
4.93
98.6
na
na
na
CCV2
5.00
4.89
97.8
na
na
na
LCS
(
3,940)
3.54
89.8
na
1,000
L/
kg
(
3,540)

ICB
unknown
0.05
na
na
na
<
0.50
CCB1
unknown
 
0.08
na
na
na
<
0.50
CCB2
unknown
 
0.09
na
na
na
<
0.50
24A
na
2.09
na
6.93
1,000,000
(
2,090,000)

24A­
duplicate
na
2.24
na
1,000,000
(
2,240,000)

24A­
spike
10.00
9.69
96.9
na
na
na
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
10
E.
6
Laboratory
QA/
QC
for
EEI
Work
Order
01­
09­
416
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
The
raw
data
logs
indicate
that
the
samples
were
run
in
three
batches;
two
batches
of
constant
pH
and
TCLP
leachates
and
one
batch
of
solid
samples.
Results
of
this
review
are
provided
in
Table
E­
6.

Table
E­
6
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
09­
416
Sample
ID
True
mg/
L
(
mg
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg
/
kg)

Constant
pH/
TCLP
leachates
ICV
5.00
5.05
101
na
na
na
CCV1
5.00
5.22
104
na
na
na
CCV2
5.00
5.28
106
na
na
na
CCV3
5.00
5.29
106
na
na
na
CCV4
5.00
5.20
104
na
na
na
CCV5
5.00
5.26
105
na
na
na
CCV6
5.00
5.27
105
na
na
na
LCS1
10.00
10.65
107
na
na
na
LCS2
10.00
10.31
103
na
na
na
ICB
unknown
0.03
na
na
na
<
0.50
CCB1
unknown
0.00
na
na
na
<
0.50
CCB2
unknown
 
0.01
na
na
na
<
0.50
CCB3
unknown
0.04
na
na
na
<
0.50
CCB4
unknown
0.08
na
na
na
<
0.50
CCB5
unknown
0.18
na
na
na
<
0.50
CCB6
unknown
0.13
na
na
na
<
0.50
15A
na
6.01
na
2.36
10
60.1
15A­
duplicate
na
5.87
na
10
58.7
15A­
spike
40.00
20.45
102a
na
2
40.9
18A
na
10.79
na
2.29
1
10.8
18A­
duplicate
na
11.04
na
1
11.0
18A­
spike
5.00
4.87
97.4
na
na
na
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
11
Table
E­
6
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
09­
416
(
Continued)

Sample
ID
True
mg/
L
(
mg
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg
/
kg)

Constant
pH/
TCLP
leachates
ICV
5.00
4.95
99.0
na
na
na
CCV1
5.00
4.89
97.8
na
na
na
CCV2
5.00
4.89
97.8
na
na
na
CCV3
5.00
4.70
94.0
na
na
na
LCS
10.00
11.15
112
na
na
na
ICB
unknown
 
0.02
na
na
na
<
0.50
CCB1
unknown
0.00
na
na
na
<
0.50
CCB2
unknown
0.00
na
na
na
<
0.50
CCB3
unknown
0.06
na
na
na
<
0.50
29A
na
19.19
na
0.675
10
192
29A­
duplicate
na
19.32
na
10
193
29A­
spike
10.00
10.01
100
na
na
na
Solids
ICV
5.00
5.24
105
na
na
na
CCV1
5.00
5.16
103
na
na
na
CCV2
5.00
5.22
104
na
na
na
LCS
(
3,940)
38.02
96.4
na
100
L/
kg
(
3,800)

ICB
unknown
0.05
na
na
na
<
0.50
CCB1
unknown
 
0.02
na
na
na
<
0.50
CCB2
unknown
 
0.02
na
na
na
<
0.50
41A
na
1.38
na
2.86
1,000,000
(
1,380,000)

14A­
duplicate
na
1.42
na
1,000,000
(
1,420,000)

41A­
spike
40.00
20.16
101*
na
2
40.3
*
Percent
recovery
calculated
with
the
reported
value
and
true
value,
due
to
the
dilution
factor.

A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L
for
each
of
the
three
batch
runs.
Measurement
of
these
standards
produced
a
linear
trend
with
acceptable
correlation
coefficients
of
0.999997,
0.999632,
and
0.999639.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
for
both
runs,
and
the
initial
and
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
12
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
values
are
within
acceptable
limits.

The
sample
digestion
log
indicates
the
reagents
used
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors
for
the
solid
and
leachate
samples.
The
precision
and
accuracy
summary
provided
for
the
leachate
samples
show
acceptable
precision
(
±
25%)
and
accuracy
results
(
75
 
125
%).

E.
7
Laboratory
QA/
QC
for
EEI
Work
Order
01­
10­
360
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
Results
of
this
review
are
provided
in
Table
E­
7.

Table
E­
7
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
10­
360
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

ICV
5.00
5.19
104
na
na
na
CCV1
5.00
4.88
97.6
na
na
na
CCV2
5.00
5.01
100
na
na
na
CCV3
5.00
4.98
99.6
na
na
na
LCS1
10.00
10.57
106
na
na
na
LCS2
10.00
10.18
102
na
na
na
ICB
unknown
0.09
na
na
na
<
0.50
CCB1
unknown
0.04
na
na
na
<
0.50
CCB2
unknown
0.20
na
na
na
<
0.50
CCB3
unknown
0.16
na
na
na
<
0.50
01A
na
4.26
na
5.69
1,000
4,260
01A­
duplicate
na
4.51
na
1,000
4,510
01A­
spike
10.00
10.01
100
na
na
na
16A
na
8.90
na
12.7
1
8.90
16A­
duplicate
na
10.11
na
1
10.1
16A­
spike
5.00
5.45
109
na
na
na
A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L.
Measurement
of
these
standards
produced
a
linear
trend
with
an
acceptable
correlation
coefficient
of
0.999705.
The
initial
and
continuing
calibration
standards
are
within
the
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
13
acceptable
range,
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
value
is
within
acceptable
limits.

A
sample
digestion
log
identifies
the
reagents
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors.
The
precision
and
accuracy
summary
provided
for
one
of
the
digested
solid
samples
shows
acceptable
precision
(
±
25
%)
and
accuracy
results
(
75
 
125
%).

E.
8
Laboratory
QA/
QC
for
EEI
Work
Order
01­
10­
674
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
The
raw
data
logs
indicate
that
the
samples
were
run
in
three
batches;
two
batches
of
constant
pH
and
TCLP
leachates
and
one
batch
of
solid
samples.
Results
of
this
review
are
provided
in
Table
E­
8.

Table
E­
8
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
10­
674
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

Constant
pH
leachates
ICV
5.00
4.80
96.0
na
na
na
CCV1
5.00
4.65
93.0
na
na
na
CCV2
5.00
4.66
93.2
na
na
na
LCS
10.00
8.95
89.5
na
na
na
ICB
unknown
0.02
na
na
na
<
0.50
CCB1
unknown
0.06
na
na
na
<
0.50
CCB2
unknown
0.06
na
na
na
<
0.50
16A
na
1.84
na
5.01
1
1.84
16A­
duplicate
na
1.75
na
1
1.75
16A­
spike
5.00
4.92
98.5
na
na
na
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
14
Table
E­
8
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
10­
674
(
Continued)

Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

Constant
pH/
TCLP
leachates
ICV
5.00
5.14
103
na
na
na
CCV1
5.00
4.94
98.8
na
na
na
CCV2
5.00
4.97
99.4
na
na
na
CCV3
5.00
4.96
99.2
na
na
na
LCS
10.00
10.52
105
na
na
na
ICB
unknown
0.06
na
na
na
<
0.50
CCB1
unknown
0.06
na
na
na
<
0.50
CCB2
unknown
0.13
na
na
na
<
0.50
CCB3
unknown
0.13
na
na
na
<
0.50
31A
na
1.88
na
1.86
1
1.88
31A­
duplicate
na
1.84
na
1
1.84
31A­
spike
5.00
4.33
86.6
na
na
na
Solids
ICV
5.00
4.99
99.8
na
na
na
CCV1
5.00
4.99
99.8
na
na
na
CCV2
5.00
4.92
98.4
na
na
na
CCV3
5.00
4.98
99.6
na
na
na
CCV4
5.00
4.95
99.0
na
na
na
LCS
(
3,940)
35.19
89.3
na
100
L/
kg
(
3,520)

ICB
unknown
0.05
na
na
na
<
0.50
CCB1
unknown
0.03
na
na
na
<
0.50
CCB2
unknown
0.10
na
na
na
<
0.50
CCB3
unknown
0.23
na
na
na
<
0.50
CCB4
unknown
0.09
na
na
na
<
0.50
39A
na
4.36
na
18.1
100,000
(
436,000)

39A­
duplicate
na
5.23
na
100,000
(
523,000)

39A­
spike
40.00
20.78
103*
na
2
41.6
*
Percent
recovery
calculated
with
the
reported
value
and
true
value,
due
to
the
dilution
factor.
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
15
A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L
for
each
of
the
three
batch
runs.
Measurement
of
these
standards
produced
a
linear
trend
with
acceptable
correlation
coefficients
of
0.999791,
0.999858,
and0.999852.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
for
both
runs,
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
values
are
within
acceptable
limits.

The
sample
digestion
log
indicates
the
reagents
used
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors
for
the
leachate
samples.
The
precision
and
accuracy
summary
provided
for
the
leachate
samples
show
acceptable
precision
(
±
25%)
and
accuracy
results
(
75
 
125
%).

E.
9
Laboratory
QA/
QC
for
EEI
Work
Order
01­
10­
676
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
Results
of
this
review
are
provided
in
Table
E­
9.

Table
E­
9
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
10­
676
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

ICV
5.00
5.07
101
na
na
na
CCV1
5.00
5.01
100
na
na
na
CCV2
5.00
4.95
99.0
na
na
na
LCS
10.00
10.18
102
na
na
na
ICB
unknown
0.04
na
na
na
<
0.50
CCB1
unknown
 
0.01
na
na
na
<
0.50
CCB2
unknown
 
0.02
na
na
na
<
0.50
02A
na
7.98
na
3.21
100
798
02A­
duplicate
na
8.24
na
100
824
02A­
spike
10.00
10.01
100
na
na
na
A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L.
Measurement
of
these
standards
produced
a
linear
trend
with
an
acceptable
correlation
coefficient
of
0.999858.
The
initial
and
continuing
calibration
standards
are
within
the
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
16
acceptable
range,
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
value
is
within
acceptable
limits.

A
sample
digestion
log
identifies
the
reagents
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors.
The
precision
and
accuracy
summary
provided
for
one
of
the
digested
solid
samples
shows
acceptable
precision
(
±
25
%)
and
accuracy
results
(
75
 
125
%).

E.
10
Laboratory
QA/
QC
for
EEI
Work
Order
01­
12­
039
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
The
raw
data
logs
indicate
that
the
samples
were
run
in
two
batches;
one
batch
of
constant
pH
and
TCLP
leachates
and
one
batch
of
solid
samples.
Results
of
this
review
are
provided
in
Table
E­
10.

A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L
for
each
of
the
two
batch
runs.
Measurement
of
these
standards
produced
a
linear
trend
with
acceptable
correlation
coefficients
of
0.999817
and
0.999755.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
for
both
runs,
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
values
are
within
acceptable
limits.

The
sample
digestion
log
indicates
the
reagents
used
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors
for
the
leachate
samples.
The
precision
and
accuracy
summary
provided
for
the
leachate
samples
show
acceptable
precision
(
±
25%)
and
accuracy
results
(
75
 
125
%).

E.
11
Laboratory
QA/
QC
for
EEI
Work
Order
01­
12­
515
To
assess
the
control
of
laboratory
QA/
QC,
a
review
was
made
of
the
instrument
calibration
curve,
initial
and
continuing
calibration
samples
(
ICV
and
ICCV),
initial
and
continuing
blank
samples
(
ICB
and
ICCB),
laboratory
control
sample
(
LCS),
raw
data
sheets,
sample
digestion
log,
dilution
factors,
and
precision
and
accuracy
summary
sheets.
The
raw
data
logs
indicate
that
the
samples
were
run
in
two
batches;
one
batch
of
constant
pH
and
TCLP
leachates
and
one
batch
of
solid
samples.
Results
of
this
review
are
provided
in
Table
E­
11.
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
17
Table
E­
10.
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
12­
039
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

Constant
pH/
TCLP
leachates
ICV
5.00
4.85
97.0
na
na
na
CCV1
5.00
4.93
98.6
na
na
na
CCV2
5.00
4.96
99.2
na
na
na
CCV3
5.00
4.88
97.6
na
na
na
CCV4
5.00
4.95
99.0
na
na
na
LCS
10.00
10.52
105
na
na
na
ICB
unknown
0.01
na
na
na
<
0.50
CCB1
unknown
0.00
na
na
na
<
0.50
CCB2
unknown
0.01
na
na
na
<
0.50
CCB3
unknown
 
0.01
na
na
na
<
0.50
CCB4
unknown
 
0.01
na
na
na
<
0.50
04A
na
2.01
na
16.1
1
2.01
0
4
A
­
duplicate
na
1.71
na
1
1.71
04A­
spike
5.00
5.42
108
na
na
na
Solids
ICV
5.00
5.00
100
na
na
na
CCV1
5.00
5.15
103
na
na
na
CCV2
5.00
5.20
104
na
na
na
CCV3
5.00
5.19
104
na
na
na
LCS
(
3,940)
4.21
107
na
1,000
L/
kg
(
4,210)

ICB
unknown
0.07
na
na
na
<
0.50
CCB1
unknown
0.10
na
na
na
<
0.50
CCB2
unknown
0.07
na
na
na
<
0.50
CCB3
unknown
0.08
na
na
na
<
0.50
29A
na
4.45
na
4.35
1,000,000
(
4,450,000)

2
9
A
­
duplicate
na
4.25
na
1,000,000
(
4,250,000)

29A­
spike
40.00
21.23
106*
na
2
42.46
*
Percent
recovery
calculated
with
the
reported
value
and
true
value,
due
to
the
dilution
factor.
QUALITY
UALITY
ASSURANCE
SSURANCE/
Q
/
QUALITY
UALITY
CONTROL
ONTROL
SUMMARY
UMMARY
E­
18
Table
E­
11.
Laboratory
QC
Data
for
Mercury
 
EEI
Work
Order
01­
12­
515
Sample
ID
True
mg/
L
(
mg/
kg)
Found
mg/
L
Percent
Recovery
RPD
%
Dilution
Factor
Reported
Result
mg/
L
(
mg/
kg)

Constant
pH/
TCLP
leachates
ICV
5.00
4.89
97.8
na
na
na
CCV1
5.00
4.85
97.0
na
na
na
CCV2
5.00
4.71
94.2
na
na
na
CCV3
5.00
4.81
96.2
na
na
na
LCS
10.00
9.89
98.9
na
na
na
ICB
unknown
0.06
na
na
na
<
0.50
CCB1
unknown
0.02
na
na
na
<
0.50
CCB2
unknown
 
0.01
na
na
na
<
0.50
CCB3
unknown
0.02
na
na
na
<
0.50
01A
na
1.90
na
1.56
1,000
1,900
01A­
duplicate
na
1.93
na
1,000
1,930
01A­
spike
40.00
21.29
108*
na
2
42.6
30A
na
1.50
na
0.00
100
150
30A­
duplicate
na
1.50
na
100
150
30A­
spike
40.00
20.15
101*
na
2
40.3
Solids
ICV
5.00
5.22
104
na
na
na
CCV1
5.00
5.09
102
na
na
na
CCV2
5.00
5.19
104
na
na
na
CCV3
5.00
4.93
98.6
na
na
na
LCS
(
3,940)
37.51
95.2
na
100
L/
kg
(
3,750)

ICB
unknown
0.01
na
na
na
<
0.50
CCB1
unknown
0.07
na
na
na
<
0.50
CCB2
unknown
0.09
na
na
na
<
0.50
CCB3
unknown
0.08
na
na
na
<
0.50
19A
na
35.44
na
2.66
100,000
(
3,540,000)

19A­
duplicate
na
34.51
na
100,000
(
3,450,000)

19A­
spike
40.00
37.12
92.8
na
na
na
*
Percent
recovery
calculated
with
the
reported
value
and
true
value,
due
to
the
dilution
factor.
EVALUATION
OF
VALUATION
TREATMENT
OF
REATMENT
BULK
ULK
ELEMENTAL
LEMENTAL
MERCURY
ERCURY
E­
19
A
five­
point
calibration
curve
was
constructed
with
standard
mercury
concentrations
of
0.50
to
40.00
µ
g/
L
for
each
of
the
two
batch
runs.
Measurement
of
these
standards
produced
a
linear
trend
with
acceptable
correlation
coefficients
of
0.999547
and
0.999759.
The
initial
and
continuing
calibration
standards
are
within
the
acceptable
range
for
both
runs,
and
the
initial
and
continuing
blanks
are
all
below
the
reporting
detection
limit
of
0.50
µ
g/
L.
A
laboratory
control
standard
was
run
prior
to
analyzing
the
samples,
and
the
reported
values
are
within
acceptable
limits.

The
sample
digestion
log
indicates
the
reagents
used
in
the
initial
dilution
and
how
the
samples
achieved
their
final
dilution
factors
for
the
leachate
samples.
The
precision
and
accuracy
summary
provided
for
the
leachate
samples
show
acceptable
precision
(
±
25%)
and
accuracy
results
(
75
 
125
%).
