BIODEGRADATION
(BOD/
COD)

TEST
SUBSTANCE
Identity:
Perfluorooctanoic
acid,
ammonium
salt:
may
also
be
referred
to
as
PFOA
ammonium
salt,
Ammonium
perfluorooctanoate,
PFO,
FC116
FC­
126,
FC­
169,
or
FC­
143.
(Octanoic
acid,
pentadecafluorot
ammonium
salt,
CAS
#
3825­
26­
l)

Remarks:
The
3M
production
lot
number
was
37.
The
test
sample
is
FC143
It's
purity
was
not
sufficiently
characterized,
though
current
information
indicates
it
is
a
mixture
of
96.5
­
100%
test
substance
and
0
­
3.5%
CS,
C7,
and
CS
perfluoro
analogue
compounds.

METHOD:

Method:
Not
noted.
Type:
Aerobic
GLP:
No
Year
completed:
1980
Contact
time:
20
days
Inoculum:
Sewage
taken
from
the
treatment
system
at
3M
Chemolite,
Cottage
Grove,
MN.
,

RESULTS
Chemical
Oxygen
Demand
(COD):
570
­
870
mg/
kg*
Biochemical
Oxygen
Demand
(BOD):
5­
Day:
~38
mg/
kg
1
O­
Day:
~38
mglkg
20­
Day:
~38
mg/
kg
*
Two
tests
were
conducted.
The
raw
data
sheets
are
not
available.
The
summary
sheet
states
"a
fraction
of
the
sample
went
up
into
the
condenser
each
time,
so
the
results
are
not
consistent
when
run
in
duplicate".

CONCLUSIONS
No
reliable
conclusions
can
be
derived
from
this
study.

Submitter:
3M
Company,
Environmental
Laboratory,
P.
O.
Box
33331,
St.
Paul,
Minnesota,
55133
DATA
QUALITY
Reliability:
Klimisch
ranking
3.
Study
lacks
description
and
records
of
the
method
followed.
The
inoculum
is
not
properly
characterized.
There
is
no
analytical
measurement
of
the
test
substance
in
the
solutions.
Test
substance
was
not
characterized
for
purity.

REFERENCES
The
COD
and
BOD
studies
were
conducted
the
3M
Company,
Environmental
Laboratory,
St.
Paul,
MN,
Lab
Request
number
5625S,
1980.

OTHER
Last
changed:
5/
24/
00
Form
10620.
NW0
cw
Li+
B
UgQlJEST
BOOK
­
42.5W
.
.
3
PRODUCT
REQUEST
ECOLOGICAL
ASSESSMENT
3m
XCttMZPOPl
FOR
LABORATORY
WORK
LAB
REQUEST
NO.
S&
X5
Name:
t'r/
REQUESTER
rntf
Phone
No.
507
9
Request
Date:
&p//
/
//
_
I
9W
Project
No.:
`953
001
2400
Prob.
No.

Sample
Date:
L/
­
I/­
/
9m
Date
Needed
:

Description:
Fc
­/
y3
Lof
3
7
Purpose
of
Tests:
Enu
soctr)
4
fo
Cd­
ifrn
­bad­
2,
d&=.
Date
Received
.!&
JI
Analyst:
Date
Completed:­
'
zw...`
I
Hours
Spent:
>
LABORATORY
IQ
Please
Call
Requester
If
Delays
Are
Encountered(.
+*
h]

PHYSICAL
&CHEMICAL
PROPERTIES
Heatof
Combustion
Cal/
G
(BTU/
Lb.)

Density
Ash
Other
BIOASSAY
96
l)
r
up
Specify
Organism
and
Method:

.4SE
fifh&
J
@mwd
`­
6/
oec
'
76
LEACHATE
FROM
LEACHING
TEST
PH
COD
BOO5
`­..

BOD,
Ultimate
TOC
OTHER
mltls
No.
.jnjtial
DB.
pnrnt
0.0.
0.0.
Dqhtkn
:
­
w
w
(Cl
`C21
Almr~
0.0.

??
7!?;
1.
2
.­
a­/­.
`go0
lc45
0,557
3'
._
-gy5
aqo
.
0
.
5
0
0.48
A
8;
so
molea
No.
w-
tnIda4
0.0.
Raeitt
0.0.
D.
O.
lhpktion
lmlt
(W
(II,
­
B2)
.

`Gboso
­
Ghmmk
Acid
SMdrd
`.
j
SotthNo.
lnltid
D.
O.
W.$,
D".
fowl
0.0.
sunpI.&`.
.
,
lDtl
DlplotIon
oophtion
Dw
2
lD1
­D$.
To
Standard
I
2.25
/
7/
'
.
/
71.

I
5
0
3,
75
?.;`.
I
.
193
0
5.
50
I
213
,

Potadum
Hydrogm
PhthJ;
O
S,
tWdUd
fopdonJ)

­,
Idud
0.0.
Ramnt
D.
O.
Total
0.0.
DI@
etion
ow
.hY
Aver*
aotth
No.
uQl=
01)
(D21
oophtion
TO
stmbd
*
BOO
­DW
(01
­
021
600
..
i
.

L
Fotm
1975S
PVVCJ
J
fk'W8t
No.
+

­
Day
BOD
Readings
I
eotthNo.
­'
I
~8mi@
a8'8@
I
hltWD.
0.
ml,
I
I
I
I
.

haant
DD.
0.0.
D@
Wm
IL1
ml
­82,
`.

potus&
Jm
HydrogM
PItudm
easdud
bptkmd)

Bollk
No.
smmplo
@Ia.
InNhI
0.0.
Pronnt
0.0.
(01)
ID,)

I
f


TotdD.
0.
won
(`
3
­W
yJt&
­­­­
mfD'y
Avrlpr
­DW
,­
m­­
17
i
amp18
bmrlption
:
Fc­
/r'3
Inkit
Dilution
.'
!nidJ
Ditution
Factoc
..,
.:
*
.­
.

of
Sample
diluted
to
ml
with
DI
water
(Dilution
factor
=
1
if
undiluted)

1
I
I'
I
I
.
­
`..
,'
I
I
I
I
I
I
I
I
I
B­.

Note
1.
­by,
~C&
umtratl~
of
sample
(ml/
l
or
mg/
l)
in
BOO
bottles.
:
7
;.,;
,."."
i.
;

.
i.­
c
Samtie
Si"
­~
rq!~,~~~
of
sample
or
d@
Md
sample
added
to
BOD
Bottle.
*
L..,..­
q
$y
,.;`­,_/
:'
:.
.
"
`1:
0.
!.
.'
'
i,
c
.

.
.

Form
19766
PWO
of
Samph
diluted
to
.
ml
witi
01
water
(0llutlon
factbr
­
1
ii&
ilu+
d)

I
I
c
.

4
1
1
.
I
.

.
Hqaa:
1.
Cork,
­
CoircMiirtioh
of
sahple
(mlfl
or
mgA)
in
800
bottla.
.

2
.
Sernph
S&*
nil
of
0
Of
8htplr
or
diluted
sample
u&
d
to
800
Bottlo.
*
;
,'

/.,


.
,
.
.,
.,
­.
­.
1
1
'
)
'
)
.'
.'
.'
.'
­

7
7
of
Sanpb
d/
Mod
to
.
ml
with
DI
Wa?
er.

5
TaU
0
.0
.
UB.
DSA
`.
:'
y%
S'
no0
`.

,
"
