

[Federal Register: June 27, 2007 (Volume 72, Number 123)]
[Notices]               
[Page 35237-35242]
From the Federal Register Online via GPO Access [wais.access.gpo.gov]
[DOCID:fr27jn07-61]                         

-----------------------------------------------------------------------

ENVIRONMENTAL PROTECTION AGENCY

[EPA-HQ-OPP-2006-0936; FRL-8133-4]

 
Notice of Filing of Pesticide Petitions for Residues of Pesticide 
Chemicals in or on Various Commodities

AGENCY: Environmental Protection Agency (EPA).

ACTION: Notice.

-----------------------------------------------------------------------

SUMMARY: This notice announces the initial filing of pesticide 
petitions proposing the establishment or modification of regulations 
for residues of pesticide chemicals in or on various commodities.

DATES: Comments must be received on or before July 27, 2007.

[[Page 35238]]


ADDRESSES: Submit your comments, identified by docket identification 
(ID) number and the pesticide petition number (PP) of interest, by one 
of the following methods:
     Federal eRulemaking Portal:  http://www.regulations.gov. 

Follow the on-line instructions for submitting comments.
     Mail: Office of Pesticide Programs (OPP) Regulatory Public 
Docket (7502P), Environmental Protection Agency, 1200 Pennsylvania 
Ave., NW., Washington, DC 20460-0001.
     Delivery: OPP Regulatory Public Docket (7502P), 
Environmental Protection Agency, Rm. S-4400, One Potomac Yard (South 
Bldg.), 2777 S. Crystal Dr., Arlington, VA. Deliveries are only 
accepted during the Docket's normal hours of operation (8:30 a.m. to 4 
p.m., Monday through Friday, excluding legal holidays). Special 
arrangements should be made for deliveries of boxed information. The 
Docket Facility telephone number is (703) 305-5805.
    Instructions: Direct your comments to the assigned docket ID number 
and the pesticide petition number of interest. EPA's policy is that all 
comments received will be included in the docket without change and may 
be made available on-line at http://www.regulations.gov, including any 

personal information provided, unless the comment includes information 
claimed to be Confidential Business Information (CBI) or other 
information whose disclosure is restricted by statute. Do not submit 
information that you consider to be CBI or otherwise protected through 
regulations.gov or e-mail. The regulations.gov website is an 
``anonymous access'' system, which means EPA will not know your 
identity or contact information unless you provide it in the body of 
your comment. If you send an e-mail comment directly to EPA without 
going through regulations.gov, your e-mail address will be 
automatically captured and included as part of the comment that is 
placed in the docket and made available on the Internet. If you submit 
an electronic comment, EPA recommends that you include your name and 
other contact information in the body of your comment and with any disk 
or CD-ROM you submit. If EPA cannot read your comment due to technical 
difficulties and cannot contact you for clarification, EPA may not be 
able to consider your comment. Electronic files should avoid the use of 
special characters, any form of encryption, and be free of any defects 
or viruses.
    Docket: All documents in the docket are listed in the docket index 
available in regulations.gov. To access the electronic docket, go to 
http://www.regulations.gov, select ``Advanced Search,'' then ``Docket 

Search.'' Insert the docket ID number where indicated and select the 
``Submit'' button. Follow the instructions on the regulations.gov 
website to view the docket index or access available documents. 
Although listed in the index, some information is not publicly 
available, e.g., CBI or other information whose disclosure is 
restricted by statute. Certain other material, such as copyrighted 
material, is not placed on the Internet and will be publicly available 
only in hard copy. Publicly available docket materials are available 
electronically at http://www.regulations.gov, or, if only available in 

hard copy, at the OPP Regulatory Public Docket in Rm. S-4400, One 
Potomac Yard (South Bldg.), 2777 S. Crystal Dr., Arlington, VA. The 
hours of operation of this Docket Facility are from 8:30 a.m. to 4 
p.m., Monday through Friday, excluding legal holidays. The Docket 
Facility telephone number is (703) 305-5805.

FOR FURTHER INFORMATION CONTACT: The person listed at the end of the 
pesticide petition summary of interest.

SUPPLEMENTARY INFORMATION:

I. General Information

A. Does this Action Apply to Me?

    You may be potentially affected by this action if you are an 
agricultural producer, food manufacturer, or pesticide manufacturer. 
Potentially affected entities may include, but are not limited to:
     Crop production (NAICS code 111).
     Animal production (NAICS code 112).
     Food manufacturing (NAICS code 311).
     Pesticide manufacturing (NAICS code 32532).
    This listing is not intended to be exhaustive, but rather provides 
a guide for readers regarding entities likely to be affected by this 
action. Other types of entities not listed in this unit could also be 
affected. The North American Industrial Classification System (NAICS) 
codes have been provided to assist you and others in determining 
whether this action might apply to certain entities. If you have any 
questions regarding the applicability of this action to a particular 
entity, consult the person listed at the end of the pesticide petition 
summary of interest.

B. What Should I Consider as I Prepare My Comments for EPA?

     1. Submitting CBI. Do not submit this information to EPA through 
regulations.gov or e-mail. Clearly mark the part or all of the 
information that you claim to be CBI. For CBI information in a disk or 
CD-ROM that you mail to EPA, mark the outside of the disk or CD-ROM as 
CBI and then identify electronically within the disk or CD-ROM the 
specific information that is claimed as CBI. In addition to one 
complete version of the comment that includes information claimed as 
CBI, a copy of the comment that does not contain the information 
claimed as CBI must be submitted for inclusion in the public docket. 
Information so marked will not be disclosed except in accordance with 
procedures set forth in 40 CFR part 2.
     2. Tips for preparing your comments. When submitting comments, 
remember to:
    i. Identify the document by docket ID number and other identifying 
information (subject heading, Federal Register date and page number).
    ii. Follow directions. The Agency may ask you to respond to 
specific questions or organize comments by referencing a Code of 
Federal Regulations (CFR) part or section number.
    iii. Explain why you agree or disagree; suggest alternatives and 
substitute language for your requested changes.
    iv. Describe any assumptions and provide any technical information 
and/or data that you used.
    v. If you estimate potential costs or burdens, explain how you 
arrived at your estimate in sufficient detail to allow for it to be 
reproduced.
    vi. Provide specific examples to illustrate your concerns and 
suggest alternatives.
    vii. Explain your views as clearly as possible, avoiding the use of 
profanity or personal threats.
    viii. Make sure to submit your comments by the comment period 
deadline identified.

II. Docket ID Numbers

    When submitting comments, please use the docket ID number and the 
pesticide petition number of interest, as shown in the table.


[[Page 35239]]



----------------------------------------------------------------------------------------------------------------
                            PP Number                                             Docket ID Number
----------------------------------------------------------------------------------------------------------------
PP 5F6904                                                                                   EPA-HQ-OPP-2005-0157
----------------------------------------------------------------------------------------------------------------
PP 6E7144                                                                                   EPA-HQ-OPP-2007-0020
----------------------------------------------------------------------------------------------------------------
PP 6F7134                                                                                   EPA-HQ-OPP-2007-0178
----------------------------------------------------------------------------------------------------------------
PP 6F7145                                                                                   EPA-HQ-OPP-2007-0193
----------------------------------------------------------------------------------------------------------------
PP 6E7132                                                                                   EPA-HQ-OPP-2007-0300
PP 6E7133........................................................                           EPA-HQ-OPP-2007-0300
----------------------------------------------------------------------------------------------------------------
PP 6E7153                                                                                   EPA-HQ-OPP-2007-0301
----------------------------------------------------------------------------------------------------------------
PP 6E7167                                                                                   EPA-HQ-OPP-2007-0302
----------------------------------------------------------------------------------------------------------------
PP 7E7187                                                                                   EPA-HQ-OPP-2007-0303
----------------------------------------------------------------------------------------------------------------
PP 6E7151                                                                                   EPA-HQ-OPP-2007-0308
----------------------------------------------------------------------------------------------------------------
PP 6E7150                                                                                   EPA-HQ-OPP-2007-0309
----------------------------------------------------------------------------------------------------------------
PP 6E7097                                                                                   EPA-HQ-OPP-2007-0311
----------------------------------------------------------------------------------------------------------------
PP 7E7183                                                                                   EPA-HQ-OPP-2007-0312
----------------------------------------------------------------------------------------------------------------
PP 6E7081                                                                                   EPA-HQ-OPP-2007-0338
----------------------------------------------------------------------------------------------------------------
PP 7E7172                                                                                   EPA-HQ-OPP-2007-0339
----------------------------------------------------------------------------------------------------------------
PP 7F7190                                                                                   EPA-HQ-OPP-2007-0366
----------------------------------------------------------------------------------------------------------------
PP 7F7169                                                                                   EPA-HQ-OPP-2007-0377
----------------------------------------------------------------------------------------------------------------
PP 7E7204                                                                                   EPA-HQ-OPP-2007-0398
----------------------------------------------------------------------------------------------------------------
PP 6F7161                                                                                   EPA-HQ-OPP-2007-0029
----------------------------------------------------------------------------------------------------------------

III. What Action is the Agency Taking?

    EPA is printing notice of the filing of pesticide petitions 
received under section 408 of the Federal Food, Drug, and Cosmetic Act 
(FFDCA), 21 U.S.C. 346a, proposing the establishment or modification of 
regulations in 40 CFR part 180 for residues of pesticide chemicals in 
or on various food commodities. EPA has determined that the pesticide 
petitions described in this notice contain data or information 
regarding the elements set forth in section 408(d)(2) of FFDCA; 
however, EPA has not fully evaluated the sufficiency of the submitted 
data at this time or whether the data support granting of the pesticide 
petitions. Additional data may be needed before EPA rules on these 
pesticide petitions.
    Pursuant to 40 CFR 180.7(f), a summary of each of the petitions 
included in this notice, prepared by the petitioner, is included in a 
docket EPA has created for each rulemaking. The docket for each of the 
petitions is available on-line at http://www.regulations.gov.


New Tolerances

    1. PP 5F6904. (Docket ID number EPA-HQ-OPP-2005-0157). ABERCO, 
Inc., 9430 Lanham-Severn Road, Seabrook, MD 20706, proposes to 
establish a tolerance for residues of the fungicide propylene oxide in 
or on food commodities: Grape, raisin at 1.0 parts per million (ppm); 
fig at 3.0 ppm and plum, prune, dried at 2.0 ppm. ABERCO has submitted 
an enforcement method for determination of residues of propylene oxide, 
propylene chlorohydrin, and propylene bromohydrin in nutmeats, cocoa, 
and dried spices. Contact: Tony Kish, telephone number: (703) 308-9943; 
e-mail address: kish.tony@epa.gov.
    2. PP 6E7144. (Docket ID number EPA-HQ-OPP-2007-0020). Tamico, 
Inc., 1950 Lake Park Dr., Smyrna, GA 30080, proposes to establish 
import tolerances for residues of the fungicide thiram in or on food 
commodities: Banana, whole at 0.5 ppm and banana, pulp at 0.3 ppm. 
Banana samples were analyzed according to analytical method meth-100, 
revision 4 , ``Determination of Thiram in Raw Agricultural 
Commodities, Processed Commodities and Other Plant Material''. 
Detection and quantitation for thiram (as CS2) were conducted using gas 
chromatography (GC) employing sulfur-specific flame photometric 
detection (FPD). The limit of quantitation (LOQ) was 0.05 ppm. Contact: 
Bryant Crowe, telephone number: (703) 305-0025; e-mail address: 
crowe.bryant@epa.gov.

    3. PP 6F7134. (Docket ID number EPA-HQ-OPP-2007-0178). Bayer 
CropScience, P.O. Box 12014, 2 T.W. Alexander Dr., Research Triangle 
Park, NC 27709, proposes to establish a tolerance for residues of the 
fungicide prothioconazole and its desthio metabolite in or on food 
commodities: Beet, sugar, roots at 0.25 ppm and beet, sugar, tops at 
9.0 ppm. The analytical method for determining residues of concern in 
plant extract residues of prothioconazole and JAU6476-desthio and 
converts the prothioconazole to JAU6376-desthio and JAU6476-sulfonic 
acid. Following addition of internal standards the sample extracts are 
analyzed by liquid chromatography/tandem mass spectrometry (LC/MS/MS). 
Radiovalidation and independent laboratory validation have shown that 
the method adequately quantifies prothioconazole residues in treated

[[Page 35240]]

commodities. The analytical method for analysis of large animal tissues 
includes extraction of the residues of concern, followed by addition of 
an internal standard to the extract. The extract is then hydrolyzed to 
release conjugates, partitioned and analyzed by LC/MS/MS as 
prothioconazole, JAU6476-desthio and JAU6476-4-hydroxy. The method for 
analysis of milk eliminated the initial extraction step in the tissue 
method. Contact: Bryant Crowe, telephone number: (703) 305-0025; e-mail 
address: crowe.bryant@epa.gov.
    4. PP 6F7145. (Docket ID number EPA-HQ-OPP-2007-0193). FMC 
Corporation, 1735 Market St., Philadelphia, PA 19203, proposes to 
establish a tolerance for residues of the herbicide carfentrazone-
ethyl, (ethyl--2-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-
oxo-1H-1,2,4-triazol-1-yl]-4-fluorobenzene-propanoate) and the 
metabolite carfentrazone-ethyl, chloropropionic acid (, 2-dichloro-5-
[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-yl]-
4-fluorobenzenepropanoic acid) in or on food commodities: Grain, 
cereal, group 15 (except rice grain and sorghum grain at 0.10 ppm; 
rice, grain at 1.3 ppm; sorghum, grain at 0.25 ppm; grain, cereal, 
stover at 0.80 ppm; grain, cereal, straw at 3.0 ppm; soybean, seed at 
0.10 ppm; barley, flour at 0.80 ppm; barley, bran at 0.80 ppm; millet, 
flour at 0.80 ppm; oat, flour at 0.80 ppm; rice, hulls at 3.5 ppm; rye, 
flour at 0.80 ppm; rye, bran at 0.80 ppm; wheat, bran at 0.80 ppm; 
wheat, flour at 0.80 ppm; wheat, middlings at 0.80 ppm; wheat, shorts 
at 0.80 ppm; wheat, germ at 0.80 ppm; aspirated grain fractions at 1.8 
ppm; hog, meat at 0.10 ppm; hog, meat byproducts at 0.10 ppm; hog, fat 
at 0.10 ppm; poultry, meat byproducts at 0.10 ppm; and sugarcane at 
0.15 ppm. The analytical method involves separate analyses for parent 
and its metabolites. The parent is analyzed by GC/electron capture 
detection (ECD). The metabolites are derivatized with boron trifluoride 
and acetic anhydride for analysis by GC/mass spectrometry detection 
(MSD) using selective ion monitoring. Contact: Joanne I. Miller, 
telephone number: (703) 305-6224; e-mail address: 
miller.joanne@epa.gov.

    5. PP 6E7132 and 6E7133. (Docket ID number EPA-HQ-OPP-2007-0300). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the insecticide Z-cypermethrin, (S-cyano(3-
phenoxyphenyl) methyl ())(cis-trans 3-(2,2-
dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate and its inactive 
R-isomers in or on food commodities: PP 6E7132 - Rice, wild, grain at 
1.50 ppm; okra at 0.20 ppm; safflower, seed at 0.20 ppm; and PP 6E7133 
- Fruit, citrus, group 10 at 0.25 ppm; citrus, dried, pulp at 0.50 ppm; 
and citrus, oil at 0.90 ppm. There is a practical analytical method for 
detecting and measuring levels of cypermethrin in or on food with a 
limit of detection (LOD) that allows monitoring of food with residues 
at or above the levels set in these tolerances (GC/ECD). Contact: 
Sidney Jackson, telephone number: (703) 305-7610; e-mail address: 
jackson.sidney@epa.gov.

    6. PP 6E7153. (Docket ID number EPA-HQ-OPP-2007-0301). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the herbicide chlorimuron-ethyl [ethyl 2-
[[[[(4-chloro-6-methoxypyrimidin-2yl) amino]carbonyl] amino]sulfonyl] 
benzoate] in or on food commodities: Cranberry; bearberry; bilberry; 
lowbush berry; cloudberry; lingonberry; muntries; and partridgeberry at 
0.02 ppm. The nature of residues of chlorimuron-ethyl is adequately 
understood and an acceptable analytical method is available for 
enforcement purposes. The LOQ allows monitoring of crops with 
chlorimuron-ethyl residues at or above the levels proposed in this 
tolerance. Contact: Sidney Jackson, telephone number: (703) 305-7610; 
e-mail address: jackson.sidney@epa.gov.
    7. PP 6E7167. (Docket ID number EPA-HQ-OPP-2007-0302. Interregional 
Research Project Number 4 (IR-4), 500 College Road East, Suite 201 W, 
Princeton, NJ 08540-6635, proposes to establish a tolerance for 
residues of the miticide bifenazate, (1-methylethyl 2-(4-methoxy[1,1'-
biphenyl]-3-yl)hydrazinecarboxylate) and diazinecarboxylic acid, 2-(4-
methoxy-[1,1'-biphenyl]-3-yl), 1-methylethyl ester (expressed as 
bifenazate) in or on food commodities: Papaya, star apple, black 
sapote, mango, sapodilla, canistel, and mamey sapote at 6.0 ppm; 
lychee, longan, Spanish lime, rambutan, and pulasan at 4.0 ppm; feijoa, 
guava, jaboticaba, wax jambu, starfruit, passionfruit, and acerola at 
0.9 ppm; caneberry subgroup 13A at 6.0 ppm; wild raspberry at 6.0 ppm; 
edible podded legume vegetable, subgroup 6A at 4.0 ppm; succulent 
shelled pea and bean, subgroup 6B at 0.3 ppm; and succulent shelled 
soybean at 0.3 ppm. As D3598, a significant metabolite, was found to 
interconvert readily to/from bifenazate, the analytical method is 
designed to convert all residues of D3598 to the parent compound 
(bifenazate) for analysis. The method utilizes reversed phase high 
performance liquid chromatography (HPLC) to separate the bifenazate 
from matrix derived interferences, and oxidative coulometric 
electrochemical detection for the identification and quantification of 
this analyte. Using this method, the LOQ was 0.05 ppm. The LOD for this 
method, which varies with matrix, is 0.005 ppm. The analytical method 
for bifenazate and its major metabolite D3598 in animal samples used 
the same principles as the plant method with minor modifications. 
However, in animal samples, a separate aliquot of the extract was used 
to determine residues of A1530 and its sulfate (combined) in milk and 
meat samples (these metabolites appeared to be significant in goat 
metabolism studies). The extract was subjected to acid hydrolysis to 
convert the sulfate conjugate to A1530 before it was quantified by HPLC 
using fluorescence or oxidative coulometric electrochemical detectors 
(OCED). Contact: Sidney Jackson, telephone number: (703) 305-7610; e-
mail address: jackson.sidney@epa.gov.
    8. PP 7E7187. (Docket ID number EPA-HQ-OPP-2007-0303). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the fungicide fenhexamid, (N-2,3-dichloro-4-
hydroxyphenyl)-1-methyl cyclohexene carboxamide) in or on food 
commodity asparagus at 0.02 ppm. An adequate method for purposes of 
enforcement of the proposed fenhexamid tolerance in plant commodities 
is available. Contact: Sidney Jackson, telephone number: (703) 305-
7610; e-mail address: jackson.sidney@epa.gov.
    9. PP 6E7151. (Docket ID number EPA-HQ-OPP-2007-0308). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the herbicide, flumioxazin, (2-[7-fluoro-3,4-
dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-
tetrahydro-1H-isoindole-1,3(2H)-dione) in or on food commodities: 
Bushberry, subgroup 13B at 0.02 ppm; asparagus, aronia berry, buffalo 
currant, Chilean guava, European barberry, highbush cranberry, 
honeysuckle, jostaberry, Juneberry, lingonberry, Native currant, salal, 
sea buckthorn, and okra at 0.02 ppm; melon, subgroup 9A at 0.02 ppm; 
dry beans at 0.10 ppm; vegetable, fruiting, crop group 8 at 0.02 ppm; 
and nut, tree, crop group 14 at 0.02 ppm. Practical analytical methods 
for detecting and

[[Page 35241]]

measuring levels of flumioxazin have been developed and validated in/on 
all appropriate agricultural commodities and respective processing 
fractions. The LOQ of flumioxazin in the methods is 0.02 ppm which will 
allow monitoring of food with residues at the levels proposed for the 
tolerances. Contact: Sidney Jackson, telephone number: (703) 305-7610; 
e-mail address: jackson.sidney@epa.gov.
    10. PP 6E7150. (Docket ID number EPA-HQ-OPP-2007-0309). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the insecticide etoxazole, (2-(2,6-
difluorophenyl)-4-[4-(1,1-dimethylethyl)-2-ethoxyphenyl]-4,5-
dihydrooxazole) in or on food commodities: hop, dried cones at 7.0 ppm; 
melon, subgroup 9A at 0.15 ppm; and cherry at 0.70 ppm. Practical 
analytical methods for detecting and measuring levels of etoxazole have 
been developed and validated in/on all appropriate agricultural 
commodities and respective processing fractions. The LOQ of etoxazole 
in the methods is 0.02 ppm which will allow monitoring of food with 
residues at the levels proposed for the tolerances. Contact: Sidney 
Jackson, telephone number: (703) 305-7610; e-mail address: 
jackson.sidney@epa.gov.

    11. PP 6E7097. (Docket ID number EPA-HQ-OPP-2007-0311). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the fungicide tebuconazole, (alpha-[2-(4-
chlorophenyl)-ethyl]-alpha-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-
ethanol) in or on food commodities: Vegetable, bulb, group 3 at 1.3 
ppm; Brassica, leafy greens, subgroup 5B at 2.5 ppm; beet, garden, 
roots at 0.7 ppm; and beet, garden, leaves at 5.0 ppm. An enforcement 
method for plant commodities has been validated on various commodities. 
It has undergone successful EPA validation and has been submitted for 
inclusion in the Pesticide Analytical Manual, Volume II (PAM II). The 
animal method has also been approved as an adequate enforcement method. 
Contact: Sidney Jackson, telephone number: (703) 305-7610; e-mail 
address: jackson.sidney@epa.gov.
    12. PP 7E7183. (Docket ID number EPA-HQ-OPP-2007-0312). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the fungicide triflumizole, (1-(1-((4-chloro-
2-(trifluoromethyl) phenyl)imino)-2-propoxyethyl)-1H-imidazole), and 
its metabolites containing the 4-chloro-2-trifluoromethylaniline 
moiety, calculated as the parent compound in or on food commodity leafy 
Brassica (subgroup 5B) at 20.0 ppm. The analytical method is suitable 
for analyzing crops for residues of triflumizole and its aniline 
containing metabolites at the proposed tolerance levels. The analytical 
method has been independently validated. Residue levels of triflumizole 
are converted to FA-1-1 by acidic and alkaline reflux, followed by 
distillation. Residues are then extracted and subjected to solid phase 
extraction (SPE) purification. Detection and quantitation are conducted 
by a GC equipped with nitrogen phosphorus detector, electron capture 
detector or mass spectrometry detection. The LOQ of the method has been 
determined at 0.05 ppm for the combined residues of triflumizole and 
FA-1-1 in mustard greens. The enforcement methodology has been 
submitted to the Food and Drug Administration (FDA) for publication in 
the PAM II. Contact: Sidney Jackson, telephone number: (703) 305-7610; 
e-mail address: jackson.sidney@epa.gov.
    13. PP 6E7081. (Docket ID number EPA-HQ-OPP-2007-0338). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for combined residues of the insecticide flonicamid [N-
(cyanomethyl)-4-(trifluoromethyl)-3-pyridinecarboxamide] and its 
metabolites TFNA [4-trifluoromethylnicotinic acid], TFNA-AM [4-
trifluoromethylnicotinamide], TFNG [N-(4-
trifluoromethylnicotinoyl)glycine] in or on food commodities: 
Vegetables, root, except sugarbeet, (subgroup 1B) at 0.45 ppm; radish, 
tops at 16.0 ppm; vegetables, tuberous and corm, (subgroup 1C) at 0.2 
ppm; Brassica, leafy greens (subgroup 5B) at 16.0 ppm; turnip greens at 
16.0 ppm; hop at 7.0 ppm; and okra at 0.4 ppm. Analytical methodology 
has been developed to determine the residues of flonicamid and its 
three major metabolites (TFNA, TFNG, and TFNA-AM) in various crops. The 
residue analytical method for the majority of crops includes an initial 
extraction with acetonitrile/deionized water (ACN/DI), followed by a 
liquid/liquid partition with ethyl acetate. The residue method for 
wheat straw is similar, except that a C18 solid phase extraction (SPE) 
is added prior to the liquid/liquid partition. The final sample 
solution is quantitated using LC equipped with a reverse phase column 
and a triple quadruple mass spectrometer (MS/MS). Contact: Sidney 
Jackson, telephone number: (703) 305-7610; jackson.sidney@epa.gov.
    14. PP 7E7172. (Docket ID number EPA-HQ-OPP-2007-0339). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the fungicide fluopicolide, (2,6-dichloro-N-
[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]methyl] benzamide) in or on 
food commodities: Vegetable, root and tuber, group 1 at 0.2 ppm; 
vegetable, leaves of root and tuber, group 2 at 12.0 ppm; vegetable, 
bulb, group 3 at 5.0 ppm; chive, fresh leaves at 5.0 ppm; chive, 
Chinese, fresh leaves at 5.0 ppm; daylily, bulb at 5.0 ppm; elegans 
hosta at 5.0 ppm; fritillaria, bulb at 5.0 ppm; fritillaria, leaves at 
5.0 ppm; garlic, serpent, bulb at 5.0 ppm; kurrat at 5.0 ppm; lady's 
leek at 5.0 ppm; leek, wild at 5.0 ppm; lily, bulb at 5.0 ppm; onion, 
Beltsville bunching at 5.0 ppm; onion, Chinese, bulb at 5.0 ppm; onion, 
fresh at 5.0 ppm; onion, macrostem at 5.0 ppm; onion, pearl at 5.0 ppm; 
onion, potato, bulb at 5.0 ppm; onion, tree, tops at 5.0 ppm; shallot, 
bulb at 5.0 ppm; shallot, fresh leaves at 5.0 ppm; and Brassica, head 
and stem, subgroup 5A at 5.0 ppm. A practical analytical method 
utilizing LC and MSD is available and has been validated for detecting 
and measuring levels of fluopicolide in and on crops. The validated LOQ 
is 0.01 ppm. Contact: Sidney Jackson, telephone number: (703) 305-7610; 
e-mail address: jackson.sidney@epa.gov.
    15. PP 7F7190. (Docket ID number EPA-HQ-OPP-2007-0366). Nichino 
America, Inc., 4550 New Linden Hill Road, Suite 501, Wilmington, DE 
19808, proposes to establish a tolerance for residues of the herbicide, 
pyraflufen-ethyl (ethyl 2-chloro-5-(4-chloro-5-difluoromethoxy-(1-
methyl-1H-pyrazol-3-yl)-4-fluorophenoxyacetate) and its acid 
metabolite, E-1 (2-chloro-5-(4-chloro-5-difluoromethoxy-(1-methyl-1H-
pyrazol-3-yl)-4-fluorophenoxyacetic acid), expressed in terms of the 
parent in or on food commodities: Soybeans, forage at 0.05 ppm; 
soybeans, hay at 0.1 ppm; grass, forage, crop group 17 at 1.0 ppm; and 
grass, hay, crop group 17 at 1.2 ppm. Aqueous organic solvent 
extraction, column clean up, and quantitation by GC is used to measure 
and evaluate the chemical residues. Contact: Joanne I. Miller, 
telephone number: (703) 305-6224; e-mail address: 
miller.joanne@epa.gov.

    16. PP 7F7169. (Docket ID number EPA-HQ-OPP-2007-0377). BASF 
Corporation, P.O. Box 13528, Research

[[Page 35242]]

Triangle Park, NC 27709, proposes to establish a tolerance for residues 
of the fungicide Boscalid (BAS 510F), [3-pyridinecarboxamide, 2-chloro-
N-(4'-chloro(1,1'-biphenyl)-2-yl] in or on food commodities: Cotton, 
undelinted seed at 1.0 ppm and cotton, gin byproducts at 55.0 ppm. In 
plants, the parent residue is extracted using an aqueous organic 
solvent mixture followed by liquid/liquid partitioning and a column 
clean up. Quantitation is by GC using MS. In livestock, the residues 
are extracted with methanol. The extract is treated with enzymes in 
order to release the conjugated glucuronic acid metabolite. The 
residues are then isolated by liquid/liquid partition followed by 
column chromatography. The hydroxylated metabolite is acetylated 
followed by a column clean up. The parent and acetylated metabolite are 
quantitated by GC with ECD. Contact: Bryant Crowe, telephone number: 
(703) 305-0025; e-mail address: crowe.bryant@epa.gov.
    17. PP 7E7204. (Docket ID number EPA-HQ-OPP-2007-0398). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to establish a 
tolerance for residues of the insecticide/miticide spirodiclofen,(3-
(2,4-dichlorophenyl)-2-oxo-1-oxaspiro[4,5]dec-3-en-4-yl ester 2,2-
dimethylbutanoate in or on food commodity hops, cones, dried at 30.0 
ppm. Adequate analytical methodology using LC/MS/MS detection is 
available for enforcement purposes. Contact: Susan Stanton, telephone 
number: (703) 305-5218; e-mail address: stanton.susan@epa.gov.

Amendment to Existing Tolerances

    1. PP 5F6904. (Docket ID number EPA-HQ-OPP-2005-0157). ABERCO, 
Inc., 9430 Lanham-Severn Road, Seabrook, MD 20706, proposes to amend 
the tolerances in 40 CFR 180.491 by deleting sections (a)(2) and (a)(4) 
for residues of the fungicide propylene oxide in or on the food 
commodities. These directions are described on the label and are no 
longer required in the tolerance expression. Contact: Tony Kish, 
telephone number: (703) 308-9943; e-mail address: kish.tony@epa.gov.
    2. PP 6F7161. (Docket ID number EPA-HQ-OPP-2007-0029). Bayer 
CropScience, 2 T.W. Alexander Dr., Research Triangle Park, NC 27709, 
proposes to amend the tolerances in 40 CFR 180.473(a) to eliminate the 
reference to transgenic crops tolerant to glufosinate ammonium in 
section 180.473(a)(2) such that the crop tolerances listed under 
section 180.473(a) General support uses in all of the crops listed to 
include both conventional and transgenic crops and to delete sections 
180.473 (a)(1) and 180.473 (a)(2). This notice clarifies the initial 
notice of filing published in the Federal Register of February 28, 2007 
(72 FR 9000; FRL-8115-5). The tolerances for glufosinate-ammonium and 
its metabolites listed for the commodities under both subsections (1) 
and (2) are proposed to be placed in paragraph 180.473(a) General to 
read as follows: Tolerances are established for residues of 
glufosinate-ammonium (butanoic acid, 2-amino-4-
(hydroxymethylphosphinyl)-monoammonium salt) and its metabolites 
expressed as butanoic acid, 2-amino-4-(hydroxymethylphosphinyl)-, 
monoammonium salt, 2-acetamido-4-methylphosphinico-butanoic acid and 3-
methylphosphinico-propionic acid expressed as glufosinate free acid 
equivalents in or on the raw agricultural commodities: Almond, hulls at 
0.50 ppm; apple at 0.05 ppm; aspirated grain fractions at 25.0 ppm; 
banana at 0.30 ppm; banana, pulp at 0.20 ppm; beet, sugar, molasses at 
5.0 ppm; beet, sugar, roots at 0.9 ppm; beet, sugar, tops (leaves) at 
1.5 ppm; bushberry subgroup 13B at 0.15 ppm; canola, meal at 1.1 ppm; 
canola, seed at 0.4 at ppm; cattle, fat at 0.40 ppm; cattle, meat at 
0.15 ppm; cattle, meat byproducts at 6.0 ppm; corn, field forage at 4.0 
ppm; corn, field, grain at 0.2 ppm; corn, field, stover at 6.0 ppm; 
cotton, gin byproducts at 15 ppm; cotton, undelinted seed at 4.0 ppm; 
egg at 0.15 ppm; goat, fat at 0.40 ppm; goat, meat at 0.15 ppm; goat, 
meat byproducts at 6.0 ppm; grape at 0.05 ppm; hog, fat at 0.40 ppm; 
hog, meat at 0 .15; hog, meat byproducts at 6.0 ppm; horse, fat at 0.40 
ppm; horse, meat at 0.15 ppm; horse, meat byproducts at 6.0 ppm; 
Juneberry 0.10 ppm; lingonberry at 0.10 ppm; milk at 0.15 ppm; nut, 
tree, group 14 at 0.10 ppm; potato at 0.80 ppm; potato, chips at 1.60 
ppm; potato granules and flakes 2.00 ppm; poultry, fat 0.15 ppm; 
poultry, meat at 0.15 ppm; poultry, meat byproducts 0.60 ppm; rice, 
grain at 1.0 ppm; rice, hull at 2.0 ppm; rice, straw at 2.0 ppm; salal 
at 0.10 ppm; sheep, fat at 0.40 ppm; sheep, meat at 0.15 ppm; sheep, 
meat byproducts at 6.0 ppm; soybean at 2.0 ppm and soybean, hulls at 
5.0 ppm. An analytical method was developed to measure the glufosinate-
ammonium and its metabolites in raw agricultural commodities by GC. 
Contact: Joanne I. Miller, telephone number: (703) 305-6224; e-mail 
address: miller.joanne@epa.gov.
    3. PP 6E7151. (Docket ID number EPA-HQ-OPP-2007-0308). 
Interregional Research Project Number 4 (IR-4), 500 College Road East, 
Suite 201 W, Princeton, NJ 08540-6635, proposes to amend the tolerances 
in 40 CFR 180.568 for residues of the herbicide, flumioxazin, 2-[7-
fluoro-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazin-6-yl]-
4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione in or on the food 
commodity almond, nutmeats be deleted upon establishment of the crop 
group tolerance for nut, tree, Crop Group 14. Contact: Sidney Jackson, 
telephone number: (703) 305-7610; e-mail address: 
jackson.sidney@epa.gov.


List of Subjects

    Environmental protection, Agricultural commodities, Feed additives, 
Food additives, Pesticides and pests, Reporting and recordkeeping 
requirements.


    Dated: June 13, 2007.
Donald R. Stubbs,
Acting Director, Registration Division, Office of Pesticide Programs.
[FR Doc. E7-12036 Filed 6-26-07; 8:45 am]

BILLING CODE 6560-50-S
