INTEROFFICE
MEMORANDUM
RESEARCH
TRIANGLE
INSTITUTE
December
1,
2003
To:
Project
Files
From:
Kristin
Parrish
Subject:
Web
Search
for
Information
on
Potential
Emissions
from
Miscellaneous
Coating
Operations
To
determine
hazardous
air
pollutant
(
HAP)
content
of
miscellaneous
coatings
applied
to
plywood
and
composite
wood
products
(
PCWP),
some
of
the
more
comprehensive
permits
in
the
project
files
were
reviewed
and
a
Web
search
was
performed.
Miscellaneous
coatings
include:
edge
seals,
moisture
sealants,
anti­
skid
coatings,
company
logos,
trademark
or
grade
stamps,
nail
lines,
synthetic
patches,
wood
patches,
wood
putty,
concrete
forming
oils,
glues
for
veneer
composing,
shelving
edge
fillers,
and
OSB
primers.
Attachment
1
summarizes
the
information
obtained
from
permits
on
miscellaneous
coating
HAP
content.

The
Panel
World
2003
Directory/
Buyers'
Guide
was
reviewed
to
identify
companies
that
produce
miscellaneous
coatings
for
the
PCWP
industry.
Once
those
companies
were
identified,
the
websites
for
these
companies
were
searched
for
online
material
safety
data
sheets
(
MSDS)
or
other
information
on
the
HAP
content
of
coatings.
Attachment
2
contains
summaries
of
information
and
various
MSDS
printed
from
coating
supplier
websites.

C:\
dmautop\
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28573­
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Attachment
1
Summary
of
Information
Obtained
from
Permits
on
HAP
Content
of
Miscellaneous
Coating
Operations
Louisiana­
Pacific
OSB,
Roxboro,
NC
(
Potential
emissions
in
parentheses)

C­
1:
Edge
Seal
and
Stencil
Paint:
VOC:
1.58
(
2.76)
lb/
hr,
6.91
(
6.91)
ton/
yr
Maximum
design
capacity
is
15
gal/
hr
(
103,535
gal/
yr)
of
orange
edge
seal
from
12
guns,
5.2
gal/
hr
(
7576
gal/
yr)
of
black
stencil
paint
from
3
guns
­
both
made
by
Associated
Chemists,
Inc.
Emissions
from
this
source
are
vented
to
the
press
room
which
vents
to
the
RTOs.
Several
coatings
could
potentially
be
used
for
the
orange
edge
seal
and
black
stencil
paint
­
combinations
in
permit
represents
formulation
with
greatest
emissions
VOC
components
in
edge
seal
are
ethanol
and
glycol
ether
EB;
seal
is
41%
solids
by
weight;
density:
8­
8.4
lb/
gal;
volatile
density:
0.12
lb/
gal
­
water
based
paint,
no
hazardous
ingredients
VOC
component
in
stencil
paint
are
amino
alcohols,
paint
is
5.2%
solids
by
weight;
density:
7.7­
8.8
lb/
gal;
volatile
density:
0.19
lb/
gal
­
water
based
paint,
no
hazardous
ingredients
Insignificant
Sources:
BSI­
1:
Black
Stamp
Ink:
VOC:
0.01187
(
0.08)
lb/
hr,
0.052
(
0.052)
ton/
yr
Associated
Chemists,
Inc.
­
Mineral
Oil
(
70%)
only
hazardous
ingredient
listed
in
MSDS
­
oil­
based
paint,
MSDS
number
PF2012­
43
Other
Insignificant
Activities
that
L­
P
is
not
required
to
list
(
and
why):
Nail
Line
Marking
(
No
emissions
of
any
regulated
pollutant)
Red
and
black
nail
line
ink
made
by
Associated
Chemists,
Inc.
Red
Nail
Line
Ink
(
water­
based
paint,
PF2303­
62)
has
morpholine
(
1­
5%),
pigment
red
22
(
1­
5%),
and
propylene
glycol
n­
butyl
ether
(
2­
propanol­
1­
butoxy)
(
1­
5%)
Black
Nail
Line
Ink
(
water­
based
paint,
PF2302­
62)
has
morpholine
(
1­
5%)
and
propylene
glycol
n­
butyl
ether
(
2­
propanol­
1­
butoxy)
(
1­
5%)
White
Stencil
Painting
(
No
emissions
of
any
regulated
pollutant)
­
no
hazardous
ingredients
listed
for
High
Hide
White
Stencil
Paint
(
water­
based
paint,
PF­
5011­
88)
­
Associated
Chemists,
Inc.
Product
and
Waste
Labeling
(
Spray
cans
have
no
applicable
requirements)
Georgia­
Pacific
OSB,
Brookneal,
VA
Point
Source:
Paint
Booth
Edge
seal
coating
applied
in
paint
booth
­
Only
PM
&
PM10
emissions
are
calculated
Max.
Process
Operation:
8460
hr/
yr
Actual
Throughput:
101,933
gal/
yr
Max.
Throughput:
15
gal/
hr,
126,900
gal/
yr
Density:
8.97
lb/
gal;
20%
solids
65%
of
paint
sprayed
actually
reaches
boards,
rest
is
entrained
in
exhaust
air
&
emitted
to
atm.

Associated
Chemists,
Inc.
Blue
Ultraseal
(
PFX96B21P)
Water­
based
paint
No
Hazardous
ingredients
Associated
Chemists,
Inc.
High
Hide
White
Stencil
Paint
(
PFX94M02C)
Water­
based
paint
No
Hazardous
ingredients
Attachment
2
Summary
of
Information
Obtained
from
Coating
Supplier
Websites
on
HAP
Content
of
Miscellaneous
Coating
Operations
and
MSDS
Associated
Chemists,
Inc.
­
Performance
Solutions
for
the
Wood
Products
Industry
http://
www.
achemists.
com/
"
Founded
in
1929
as
a
small
manufacturer
of
insecticides,
ACI
has
grown
into
an
international
supplier
of
coatings
and
formulated
chemicals
for
specialized
industrial
markets."
Was
a
subsidiary
of
L­
P
until
December
1999
Products
include
Sealers,
Primers,
Forced
Cure
Coatings,
Engineered
Wood
Coatings,
&
Marking
Inks
Have
an
MSDS
"
search
engine"
Other
products
not
listed
in
trip
reports
or
permits
(
no
evidence
these
are
actually
used):
Black
Stamp
Ink
(
Solvent­
based
ink,
PF2012­
45)
has
dimethyl
glutarate
(
15­
40%),
polychlorinated
alkanes
(
10­
30%),
dimethyl
adipate
(
3­
7%),
dimethyl
succinate
(
3­
7%),
analine
(<
0.5%)
Black
Stamp
Ink
(
Water­
based
paint,
PFX96K98B)
has
Dowanol
DpnB
(
1­
5%)
Red
Nail
Line
Ink
Conc.
(
water­
based
paint,
PFX01K96H
and
PFX02F41A)
has
dipropylene
glycol
methyl
ether
(
1­
5%)
Black
Nail
Line
Ink
Conc.
(
water­
based
paint,
PFX02F40A
and
PFX03C12A)
has
dipropylene
glycol
methyl
ether
(
1­
5%)
Black
Nail
Line
Ink
Conc.
(
water­
based
paint,
PFX00A13B)
has
1­
methoxy
propanol
(
1­
5%)
and
triethanolamine
(
0.5­
1.5%)
(
chemicals
on
HAP
list
in
red)

Fentak
http://
www.
fentak.
net/
Coatings
(
plywood
&
PB),
Dye
(
PB
&
PSF),
Putty
(
plywood
­
datasheets
available)
For
many
products,
no
details
given
­
just
says
"
datasheet
unavailable,
please
call"
For
the
ones
that
do
have
datasheets,
the
information
is
limited
to
color,
viscosity,
storage
information,
percent
solids,
weight
­
no
ingredients
Fentak
PY201,
PY203:
two
part
putties
that
cure
at
room
temperature.
Part
A
(
liquid
resin)
­
50%
solid;
Part
B
(
powder
hardener)
­
100%
solid
Laurence­
David
Inc.
http://
www.
ldavid.
com/
Manufacture
Synthetic
Fillers;
Paints;
Crayons;
Release
Agents;
Inks
­
no
MSDS
or
details
about
individual
products
other
than
their
intended
use.

National
Casein
http://
www.
nationalcasein.
com
Make
chemicals
for
edge
bonding,
film
/
paper
overlay
/
decorative
film
&
foil
laminating,
and
adhesives
for
finger­
joining,
plywood,
veneer,
etc.
Have
a
list
of
products
for
each
application,
no
MSDS
online
R&
D
Coatings
Inc.
http://
www.
rdcoatings.
com/
Manufacture
"
radiation
curable
finishes
for
wood,
plastic,
and
metal
substrates"
including
finishes
for
hardwood
floors
and
"
specializes
in
the
development,
marketing
and
manufacture
of
UV
(
Ultraviolet)
and
EB
(
Electron
Beam)
curable
finishes."
Wood
substrates
include:
hardwoods,
MDF,
PB,
veneered
plywood,
and
others.
Products
for
wood
substrates
include
fillers,
sealers,
clear
topcoats,
and
opaque
coatings
(
most
UV
or
EB)
­
no
MSDS
or
other
product
details.
Website
notes
that
most
UV
"
products
contain
little
or
no
solvent
(
VOCs)
and
therefore
meet
all
current
and
proposed
emission
requirements,
even
in
the
state
of
California."

Talladega
Machinery
and
Supply
Company
http://
www.
tmsco.
com/
Make
lumber
crayons,
lumber
wax
end
seals
and
paints
­
mostly
deal
in
machinery
and
replacement
parts
U­
C
Coatings
Corporation
https://
www.
uccoatings.
com/
Many
products
water­
based,
some
information
such
as
density
and
storage
is
given,
no
ingredients
listed
End
coatings
for
logs
&
lumber
(
end
sealer,
end
paint
for
dried
lumber,
wax­
based
end
paint
for
dried
lumber,
sample
sealer)
Coatings
for
wood
products
production
(
boothcoating/
glue
release,
hot
press
release,
dried
wood
parts
sealer,
edge
sealer
for
dried
dimension
stock
and
panels)

Willamette
Valley
Co.
http://
www.
wilvaco.
com/
Paints
&
Primers;
Composite
Board,
LVL,
&
Log
Sealers;
Water­
Repellants;
Edge
Seal
and
Stencil
Paints;
Putty,
Epoxy,
&
Synthetic
Patching;
Inks
Product
descriptions
include
percent
solids,
density,
viscosity,
pH,
storage
information
­
no
ingredients
No
MSDS
online,
some
products
say
"
you
must
read
and
become
familiar
with
available
information
concerning
its
hazards,
proper
use,
and
handling.
If
you
do
not
have
access
to
a
MSDS,
please
contact
your
local
representative
for
a
copy,"
others
say
"
no
unusual
health
hazards
associated
with
this
product."
Tannin
Stain
Blockers
(
Primers)
­
Solids:
38
(
2.0
%
by
weight)
Various
epoxies
­
Solids:
100%
Water
based
putties
­
Solids:
High
Solids
Resin­
based
putty
­
Solids:
63%
+/­
1%
Resin­
based
edge
seal
paint
­
Solids:
15%
(
by
weight)
Edge
seal
waterborne
paint
with
a
paraffin
base
(
saw
mills)
­
Solids:
16%
by
weight
Stencil
paint/
primer
­
Solids:
>
64%
by
weight
Red
disappearing
ink
­
Solids:
N/
A
Veneer
Stripping
Ink
­
Solids:
N/
A
WVCO
Synthetic
Patch
PRODUCT
DESCRIPTION
Willamette
Valley
Company's
U­
100
Synthetic
Patch
compound
is
a
two­
component
urethane
system
that
has
evolved
through
the
years
of
formulating
and
testing
in
the
wood
products
industry.
During
the
last
10
years
U­
100
has
found
extensive
uses
in
up­
grading
plywood
panels,
filling
laminated
beams,
moldings,
door
blanks
and
medium
density
overlay
plywood.

PHYSICAL
CHARACTERISTICS
Colors:
Available
in
most
colors
Wt/
Gal:
Part"
A"=
12.6lbs/
gal
Part"
B"=
10.3lbs/
gal
Viscosity:
2800
cps
±
100cps
Mix
ratios:
2
½
:
1
to
6:
1
Shelf
Life:
3
months
(
mixing
may
be
required
after
prolonged
storage)
Set
Time:
Formulated
from
25
seconds
to
70
seconds
(
70
mils
at
77

F.)

APPLICATION
We
recommend
using
Willamette
Valley
Company's
metering
Equipment
which
has
been
specifically
engineered
for
controlling
U­
100'
s
mix
ratio,
temperature,
viscosity,
and
set
time.
Also
available
is
Willamette's
full
service
warranty.
Under
proper
surface
preparation
and
mixing
conditions,
U­
100
is
fully
approved
by
the
American
Plywood
Association
for
routed
defects
up
to
2
¼
"
x
6".
Check
with
your
Willamette
Valley
Company
representative
for
directions
and
recommendations
for
use.

CAUTION
This
product
is
supplied
to
the
customer
in
a
ready­
to­
use
form
requiring
proper
mixing
and
dispensing.
Care
should
be
taken
that
the
product
does
not
become
contaminated
with
foreign
matter.
Refer
to
specific
"
A"
and
"
B"
Material
Safety
Data
Sheets.

Performance
of
Most
Common
Polyurethane
Patch
Formulas
PATCH
FORULA
Ratio
Shrinkage
Mileage
Separation
Wood
Adhesion
MDO/
HDO
Hardwood
Veneer
XU­
100
(
Mod.)
6:
1
Good
Excellent
Excellent
Excellent
 
 
U­
100
EM
6:
1
Fair
Excellent
Good
Excellent
 
 
U­
100
EM
Hot
Panel
6:
1
Fair
Excellent
Good
Excellent
 
 
U­
100
6:
1
Fair
Good
Excellent
Excellent
 
 
U­
1100
10:
1
Poor
Fair
Excellent
Fair
 
 
U­
1200
12:
1
Poor
Poor
Excellent
Fair
 
 
U­
100
M.
B.
6:
1
Good
Poor
Fair
Excellent
 
 
U­
100
M.
B.
N.
S.
6:
1
Good
Poor
Fair
Excellent
 
 
U­
100
M.
B.
#
5
6:
1
Good
Poor
Fair
Excellent
 
 
U­
100
BL2
6:
1
Excellent
Poor
Poor
Good
Excellent
 
U­
100
BL3
6:
1
Excellent
Poor
Poor
Good
Good
 
U­
100
O.
S.
6:
1
Good
Poor
Poor
Good
Good
 
U­
100
Knot
3:
1
Excellent
Good
Excellent
Excellent
 
 
CU­
100
3:
1
Excellent
Excellent
Excellent
Excellent
Fair
Excellent
Polyurethane
Mixing
Instructions
Equipment
needed
"
A"
and
"
B"
components
Accurate
measuring
devices
Stiff
bladed
mixing
stick
(
tongue
depressor,
paint
mixing
stick,...)
Vessel
large
enough
for
mixing
the
desired
volume
without
overflow
All
instruments
should
be
clean
and
completely
dry.

Mixing
Instructions
1.
Measure
the
appropriate
volume
of
the
resin
component
as
dictated
by
the
ratio
of
the
product
(
i.
e.
60
ml
of
resin
for
a
6:
1
product,
100
ml
of
resin
for
a
10:
1
product).

2.
Measure
the
appropriate
volume
of
the
isocyanate
component
as
dictated
by
the
ratio
of
the
product
(
i.
e.
10
ml
of
iso
to
be
used
with
the
60
ml
of
resin
for
a
6:
1
product,
or
10
ml
of
iso
to
be
used
with
100
ml
of
resin
for
a
10:
1
product).

3.
With
a
mixing
device
on
hand,
put
resin
component
into
mixing
vessel
and
add
isocyanate.

4.
Mix
rapidly
­
be
sure
to
scrape
sides
and
bottom
in
a
rapid
fashion:
A
system
for
mixing:
a.
Mix
the
main
body
of
the
material
with
10
passes
around
the
mixing
vessel.
b.
Scrape
the
sides
10
times
while
rotating
the
mixing
vessel.
c.
Scrape
the
bottom
10
times
while
rotating
the
mixing
vessel.
d.
Mix
the
main
body
of
the
material
with
10
passes
around
the
mixing
vessel.

5.
Pour
the
material
from
the
mixing
vessel
onto
the
substrate
making
sure
all
of
the
corners
of
the
substrate
are
filled.
