MEMORANDUM 

DATE:	May 1, 2023
	
FROM:	Donna Lee Jones, U.S. Environmental Protection Agency; Gabrielle Raymond, RTI International

TO:		Coke Ovens Residual Risk and Technology Review (RTR) Project File

SUBJECT:	HAP Emissions from Coke Oven Facilities
--------------------------------------------------------------------------------

1.0	INTRODUCTION 

      This memorandum presents the hazardous air pollutant (HAP) emissions and related information for the 14 coke oven facilities in the United States (U.S.) as part of the residual risk modeling for the Residual Risk and Technology Review (RTR) of the National Emission Standards for Hazardous Air Pollutants (NESHAP) for Coke Ovens: Pushing, Quenching, and Battery Stacks (PQBS) (40 CFR, part 63, subpart CCCCC), as required under section 112 of the Clean Air Act (CAA), section 112(f)(2) and (d)(6); and the technology review of the NESHAP for Coke Oven Batteries (40 CFR, part 63, subpart L), as required under CAA section 112(d)(6). In accordance with section 112(d)(2) and (3) of the Clean Air Act (CAA), the U.S. Environmental Protection Agency (EPA) promulgated a NESHAP for coke oven facility sources under the PQBS NESHAP on April 14, 2003 (68 FR 18008). The 2003 Coke PQBS NESHAP established maximum achievable control technology (MACT) standards for pushing, quenching, and battery stacks. Under section 112(f)(2) of the CAA, the EPA is required to perform a residual risk analysis of MACT standards within eight years of promulgation, unless otherwise required by the CAA.[1] In addition, the EPA is required to perform a technology review of MACT standards every eight years under section 112(d)(6) of the CAA. The Coke PQBS NESHAP RTR was due in 2011. The MACT for the Coke Oven Batteries NESHAP was promulgated on October 27, 1993 (58 FR 57898) and set standards for leaks from oven doors, lids, and offtake, and for charging. The RTR for Coke Ovens Batteries (MACT-track facilities) was promulgated on April 15, 2005 (72 FR 19992). The technology review of the facilities under the Coke Oven Batteries NESHAP was due in 2013. The risk review for the Coke Ovens Batteries LAER track facilities (9 of the 14 coke facilities) was due in 2020. 
      
The purpose of this memorandum is to provide the emissions and operating information for coke oven facilities as part of the RTR. Details of the data and emission estimating procedures are provided in the memorandum titled "Coke Ovens Risk and Technology Review: Data Summary" (hereafter called the Data Memorandum), located in the dockets for these rules (Docket ID No.'s EPA-HQ-OAR-2002-0085 (Coke PQBS NESHAP); and Docket ID No.'s EPA-HQ-OAR-2003-0051 (Coke Oven Batteries NESHAP)). Section 2 provides background for the current regulatory effort. Section 3 contains the estimated HAP emissions in terms of tons per year (tpy) and pounds per ton (lb/ton). Section 4 contains the estimated EPA Method 303 coke oven emissions (COE) from battery leaks. Section 5 contains a summary of opacity data. Section 6 lists the references used. Abbreviations can be found in Appendix A. Additional industry information can be found in Appendices B through D. The contents of this memorandum and appendices are listed below along with a list of tables.
      
      
      
                                   CONTENTS
1.0	INTRODUCTION	1
CONTENTS	2
LIST OF TABLES	3
2.0	BACKGROUND	4
2.1	Coke Production Process	4
2.2	Data Obtained for the Coke Ovens RTR	4
3.0	FACILITY EMISSIONS AND OPERATION	5
4.0	EPA METHOD 303 DATA	32
5.0	OPACITY DATA	37
6.0	REFERENCES	38
APPENDIX A	1
Abbreviations	1
APPENDIX B	1
Process Units, Annual Production, and Door Leak COE with Original Equation	1
APPENDIX C	7
Facility and Industry-wide Process and Total Emissions	7
Including Door Leak COE with Original Equation	7
APPENDIX D	1
Door Leak Emissions with Original and Alternate Equation	1

                                       
                                LIST OF TABLES
	
Table 1. Coke Facilities, Companies, Locations, Facility Type, and CAA 114 Request Status	8
Table 2. Coke Oven Total Facility Emissions Used in Risk Modeling with Alternate Door Leak Equation(TPY)	9
Table 3. Total HAP Emissions (lb/ton) for Coke Oven Facilities Used in Risk Modeling by Source Category and Facility[1]	10
Table 30. Opacity Data for Pushing and Battery Combustion Stacks from CAA 114	38
Table 4. Total Facility Coke Oven Actual Emissions by Process with Alternate Door Leak Equation (TPY)	11
Table 5. Total PQBS Metal HAP Emissions by Facility and Process (TPY)	12
Table 6. Noncategory HAP Emissions by Facility and HAP with Default Industry Averages for By-Product Plants	13
Table 7. Noncategory HAP Emissions by Facility and HAP	14
Table 8. HAP Emissions by PQBS Process (TPY)  -  ABC-Tarrant-AL	16
Table 9. HAP Emissions by PQBS Process (TPY)  -  ACCKS-Follansbee-WV	17
Table 10. HAP Emissions by PQBS Process (TPY)  -  CC-Middletown-OH	18
Table 11. HAP Emissions by PQBS Process (TPY)  -  CC-BurnsHarbor-IN	19
Table 12. HAP Emissions by PQBS Process (TPY)  -  CC-Monessen-PA	20
Table 13. HAP Emissions by PQBS Process (TPY)  -  CC-Warren-OH	21
Table 14. HAP Emissions by PQBS Process (TPY)  -  BLU-Birmingham-AL	22
Table 15. HAP Emissions by PQBS Process (TPY)  -  EES-RiverRouge-MI	23
Table 16. HAP Emissions by PQBS Process (TPY)  -  USS-Clairton-PA	24
Table 17. HAP Emissions by PQBS Process (TPY)  -  SC-EastChicago-IN	25
Table 18. HAP Emissions by PQBS Process (TPY)  -  SC-FranklinFurnace-OH	26
Table 19. HAP Emissions by PQBS Process (TPY)  -  SC-GraniteCity-IL	27
Table 20. HAP Emissions by PQBS Process (TPY)  -  SC-Middletown-OH	28
Table 21. HAP Emissions by PQBS Process (TPY)  -  SC-Vansant-VA	29
Table 22. HAP Emissions By Facility from HNR HRSG Bypass and Waste Heat Stacks - All HNR Facilities	30
Table 23. Facility PM Emissions by PQBS Process (TPY)	31
Table 24. Coke Facility Units Providing Test Data for the Coke PQBS RTR	32
Table 25. Pollutant Control Methods by Coke Processes	33
Table 26 Summary of ByP Facility 2022 Method 303 Performance and COE Emissions Data for the Coke Oven Batteries NESHAP	34
Table 27. Estimated Allowable Emissions Before and After Proposed Changes to the Coke Oven 
Batteries NESHAP Limits	35
Table 27. Estimated Allowable Emissions Before and After Proposed Changes to the Limits	35
Table 28. Allowable-to-Actual (CAA 114) Ratios for ByP Door Leaks in the Coke Oven Batteries NESHAP  -  Alternative Equation	36
Table 29. Actual COE (TPY) from Leaks and Charging Compared to Allowable	37
Table 29. Actual COE (TPY) from Leaks and Charging Compared to Allowable Limits in the Coke Oven Batteries NESHAP	37
Table A-1. Facility Name Abbreviations.	1
Table A-2. Other Abbreviations	2
Table A-3. Individual HAP within HAP Groups	3
Table B-1. Number of PQBS Emission Units by Facility	2
Table B-3. Coke Oven Batteries (Noncategory) Unit Counts by Oven and Battery	4
Table B-4. Annual Coke Production Values by Battery for the Coke Oven Facilities	5
Table C-1. Coke Oven Facility Emissions, Including Door Leak COE with Original Equation (TPY)	8
Table C-2. Coke Oven Total Facility Emissions by Process, Including Door Leak COE with Original Equation (TPY)	9
Table D-1. Comparison of 2022 Door Leak COE Estimates (TPY)	2
Table D-2. Facility Test and Emission Data for Door Leaks by Battery and Facility  -  Alternative Equation	3



2.0	BACKGROUND

2.1	Coke Production Process
In the coke production process, coal is heated in ovens in the absence of air to temperatures approaching 2,000°F (1,100[o]C), which drives off most of the volatile organic constituents of the coal, as gases and vapor, to form coke, which consists almost entirely of carbon. Coal is charged into the top or end of the oven, depending on the process, and the finished coke is pushed out using doors on both ends of the ovens. The hot coke product is cooled in quench towers that use water spray to cool hot coke in rail cars that drive into the bottoms of quench towers. The coke product is used either in blast furnaces in the integrated iron and steel industry (II&S) or at iron and steel foundries that produce iron molds for shaping molten metal. Coke oven temperatures are slightly higher to produce blast furnace coke than foundry coke. Coking lasts for 15 to 18 hours to produce blast furnace coke and 25 to 30 hours to produce foundry coke. 
The coke ovens are arranged in a series of adjacent ovens called batteries, where one battery may have up to 100 ovens and multiple batteries may be used by one facility. For the 14 coke facilities in the Coke Oven Risk Modeling Database, the number of batteries per facility ranged from 1 to 10, and the total number of ovens at the facility ranged from 56 to 708, with median values of 3 batteries per facility and 126 ovens total at the facility. Ovens at byproduct (ByP) coke facilities are tall and narrow (approximately 20 ft/6 m by 1.3 ft/0.4 m); whereas, at heat and nonrecovery recovery (HNR) facilities, the ovens are short and wide (approximately 7.8 ft/2.4 m by 12 ft/3.6 m). Byproduct coke ovens are operated at positive pressure, whereas HNR ovens operate under negative pressure. The organic gases and vapors that evolve from the ovens are removed through an exhaust system: for ByP plants, gases are sent to a chemical recovery plant (regulated under the 40 CFR part 61, subpart L NESHAP) that recovers chemicals and other products for sale and also cleans the coke oven gas. For nonrecovery (NR) plants (i.e., no chemical recovery) with heat recovery, the oven gases are sent to a heat recovery steam generator (HRSG) that produces power for sale and also to units that perform gas cleaning for sulfur and PM; for NR plants without heat recovery, oven exhaust gases are released to the surrounding air through waste heat stacks. 
2.2	Data Obtained for the Coke Ovens RTR
The primary source of data for the Coke RTR was the responses to two CAA section CAA 114 information requests (CAA 114 request) sent to selected facilities in the coke industry in April 2016 and June 2022 that included a questionnaire and a source test request (EPA, 2023). The EPA sent the CAA 114 requests under the authority of section CAA 114 of the CAA (42 U.S.C. 7414) to acquire the necessary data for the RTR for Coke PQBS NESHAP and the technology review for Coke Oven Batteries NESHAP. The questionnaire portion of the coke ovens CAA 114 requests included questions pertaining to inventory, process, and control devices for the emission units at the coke facilities. The source test request portion of the CAA 114 requests described the source tests, the test methods to be used, the pollutants to test, and other details concerning the requested testing. Copies of the CAA 114 requests and responses received by the EPA are included in dockets for both coke ovens rules (Docket ID No.'s EPA-HQ-OAR-2002-0085 (Coke PQBS NESHAP); and Docket ID No.'s EPA-HQ-OAR-2003-0051 (Coke Oven Batteries)).
The questionnaire portion of the 2016 CAA 114 request was sent to nine Coke companies that included 11 coke facilities operating in 2016: Mountain State Carbon, LLC (later purchased by AK Steel); AK Steel Corporation (that owned two coke facilities in 2016 and owned three coke facilities by 2019); ArcelorMittal Burns Harbor LLC; ArcelorMittal Monessen LLC; ArcelorMittal Warren LLC; Erie Coke Corporation; DTE Energy Services, Inc.; Sun Coke Energy, Inc. (which owns five coke facilities, of which three responded to the ICR) and U.S. Steel. The test request portion of the 2016 CAA 114 request was sent to seven of the 11 coke facilities operating at that time. Four coke facilities that did not receive the ICR that were operating in 2016 were: ABC Coke; Bluestone Coke; and two Sun Coke facilities, Indiana Harbor Coke and Jewell Coke and Coal. The questionnaire portion of the 2022 CAA 114 request was sent to six companies that included eight facilities operating in 2022 at six coke companies: ABC Coke; Cleveland-Cliffs (3 facilities); DTE Energy Services; Sun Coke Energy (2 facilities), U.S. Steel, and Cokenergy. The test request portion of the 2022 CAA 114 request also was sent to eight facilities. For details of the data obtained for the Coke RTR, see the Data Memorandum.
Table 1 lists the coke facilities and companies that were operating in 2016 and which facilities received the 2016 and 2022 CAA 114 requests; the type of coke produced; whether the facilities submitted data and/or performed source testing; and the estimated annual coke production per facility. In 2020, Cleveland-Cliffs, Inc., acquired AK Steel's cokemaking facilities in Follansbee, WV (Mountain State Carbon) and Middletown, OH, and ArcelorMittal USA LLC cokemaking facilities in Burns Harbor, IN; Monessen, PA; and Warren, OH. Appendix A lists the short names used for the coke facilities along with their full names and current ownership (Table A-1). Appendix A also includes other abbreviations used in this memorandum (Table A-2) and the individual HAP included in the HAP chemical groups (Table A-3).
3.0	FACILITY EMISSIONS AND OPERATION
Information submitted for the CAA 114 request was used to estimate emissions from coke facilities from the emission units and processes. Details of the procedures used to develop the emission estimates from the CAA 114 request data are describe in the Data Memorandum.[2] The coke facility emissions obtained from the test reports were analyzed and then reported in a few formats for use in regulatory development, as follows: 
Table 2 summarizes the HAP emissions (in tpy) used in risk modeling for the PQBS NESHAP (and refered to here as "source category emissions") and also for "noncategory" emissions in the risk analysis, which included the Coke Oven Batteries NESHAP sources, as well as other noncategory sources, with overal total HAP emissions by facility.
Table 3 presents the same data as Table 2 in units of lb/ton, using the average production shown in Table 1.
Table 4 shows the total HAP emissions in tpy used in the risk modeling for the PQBS NESHAP, by process, facility, and source category (PQBS NESHAP and noncategory), with door leak emissions under the Coke Oven Batteries NESHAP calculated using the alternative equation. See Appendix C for the same table using the original door leak emission equation. 
    Table 5 presents the metal HAP emissions for PQBS NESHAP sources used in risk modeling for coke oven facilities, by facility and process in tpy.
    Table 6 shows the noncategory ByP chemical plants HAP emissions by facility and HAP, with default industry averages used to estimate emissions for facilities without industry data.
Table 7 shows the noncategory HAP emissions by facility including: Coke Oven Batteries NESHAP sources (charging, doors, lids, offtakes), ByP chemical plant, boiler stacks, flares, other miscellaneous sources, and co-located II&S emissions.
    Tables 8 through 21 show the individual facility HAP emissions used in risk modeling by PQBS NESHAP process (in tpy) for each of the 14 coke ovens facilities. 
    Table 22 shows the HAP emissions by facility from HNR HRSG bypass and waste heat stacks for all HNR facilities. 
   
      Although the focus of the current rulemaling effort was on HAP emissions, particulate matter (PM) emissions were also determined in the course of collecting HAP emission data and in some cases used to apply HAP test data to facilities that did not test. The PM emissions for PQBS NESHAP sources are shown in Table 23, by process and facility, in tpy. 
      
      The 2016 test portion of the CAA 114 request was performed by 7 coke facilities: 5 ByP facilities and 2 HNR facilities. The 2022 test portion of the CAA 114 request was performed by 8 coke facilities: 6 ByP and 2 HNR facilities. These facilities and the processes that were tested are shown in Table 24, by process. The coke processes are controlled by various control technologies. Table 25 shows the pollutant control methods used in coke processes by coke oven facilities for both PM and volatile organic compound (VOC) control as well as the work practice controls. Table 26 summarizes the EPA Method 303 Charging, Door, Lids, and Offtakes data and the Coke Oven Batteries NESHAP limits. Table 27 summarizes the allowable-to-actual ratios for ByP door leaks using the alternative door leak equation to calculate emissions. Table 28 summarizes the average opacity observations for pushing, battery combustion, boiler, HRSG Main, HRSG bypass/waste heat, and HNR charging stacks and quench towers.

                                       

Table 1. Coke Facilities, Companies, Locations, Facility Type, and CAA 114 Request Status 
                                 Facility Name
                                 Company Name
                            [Previous Company Name]
                                  Facility ID
                            [Previous Facility ID]
                                     City
                                     State
                         Type of Coke and Facility[1]
                      2016 CAA 114 Request Submissions[2]
                      2022 CAA 114 Request Submissions[2]
                        Typical Annual Coke Production
                                   (tons)[3]
ABC Coke
Drummond Company
ABC-Tarrant-AL
Tarrant
                                      AL
                                    Foundry
                                      No
                                    Yes (T)
                                    525,685
Bluestone Coke
Bluestone
BLU-Birmingham-AL
Birmingham
                                      AL
                                    Foundry
                                      No
                                      No
                                    348,713
Cleveland-Cliffs Follansbee Works
Cleveland-Cliffs [Mountain State Carbon, LLC]
CC-Follansbee-WV 
[AKS-Follansbee-WV]
Follansbee
                                      WV
                                    BF, ByP
                                      Yes
                                      No
                                    561,862
Cleveland-Cliffs Middletown Works
Cleveland-Cliffs 
[AK Steel Corporation]
CC-Middletown-OH 
[AKS-Middletown-OH]
Middletown
                                      OH
                                    BF, ByP
                                    Yes (T)
                                      No
                                    401,752
Cleveland-Cliffs Burns Harbor
Cleveland-Cliffs [ArcelorMittal Burns Harbor LLC]
CC-BurnsHarbor-IN 
[AM-BurnsHarbor-IN]
Burns Harbor
                                      IN
                                    BF, ByP
                                    Yes (T)
                                    Yes (T)
                                   1,888,153
Cleveland-Cliffs Monessen
Cleveland-Cliffs [ArcelorMittal Monessen LLC]
CC-Monessen-PA 
[AM-Monessen-PA]
Monessen
                                      PA
                                    BF, ByP
                                    Yes (T)
                                    Yes (T)
                                    336,022
Cleveland-Cliffs Warren
Cleveland-Cliffs [ArcelorMittal Warren LLC]
CC-Warren-OH 
[AM-Warren-OH]
Warren
                                      OH
                                    BF, ByP
                                      Yes
                                    Yes (T)
                                    359,281
EES Coke Battery
DTE Energy Services, Inc.
EES-RiverRouge-MI
River Rouge
                                      MI
                                    BF, ByP
                                      Yes
                                    Yes (T)
                                    981,765
Erie Coke Corporation[4]
Erie Coke Corporation
EC-Erie-PA
Erie
                                      PA
                                    Foundry
                                    Yes (T)
                                      No
                                    122,387
Indiana Harbor Coke
SunCoke Energy, Inc.
SC-EastChicago-IN
East Chicago
                                      IN
                                    BF, HNR
                                      No
                                      No
                                   1,300,000
Haverhill Coke
SunCoke Energy, Inc.
SC-FranklinFurnace-OH
Franklin Furnace
                                      OH
                                    BF, HNR
                                      Yes
                                    Yes (T)
                                    683,313
Gateway Energy and Coke
SunCoke Energy, Inc.
SC-GraniteCity-IL
Granite City
                                      IL
                                    BF, HNR
                                    Yes (T)
                                      No
                                    428,412
Middletown Coke Company
SunCoke Energy, Inc.
SC-Middletown-OH
Middletown
                                      OH
                                    BF, HNR
                                    Yes (T)
                                      No
                                    357,010
Jewell Coke and Coal
SunCoke Energy, Inc.
SC-Vansant-VA
Vansant
                                      VA
                                    BF, HNR
                                      No
                                    Yes (T)
                                    710,000
US Steel-Clairton
U.S. Steel
USS-Clairton-PA
Clairton
                                      PA
                                    BF, ByP
                                    Yes (T)
                                    Yes (T)
                                   3,776,244
Cokenergy[5]
Coke Energy
CC-EastChicago-IN
East Chicago
                                      IN
                                    BF, HNR
                                      No
                                    Yes (T)
                                   1,300,000
1 BF = blast furnace. ByP = ByP. HNR = heat and/or nonrecovery. 
2 T = Facility also performed testing as part of CAA 114 request.
[3] Typical production as estimated by one or more of the following: (1) facilities in their CAA 114 request responses: (2) industry during the CAA 114 request review process; (3) 1998 coke production values from the NESHAP for Coke Ovens: Pushing, Quenching, and Battery Stacks  -  Background Information for Proposed Standards (EPA, 2001a); or (4) 55 percent capacity utilization of coke production design capacity from CAA 114 request responses for facilities that did not provide actual coke production values. See the Data Summary[2] for more details.
[4] The Erie Coke facility closed in 2019; however, the data were used in the Coke Emissions Database to estimate emission for other coke foundry facilities. 
[5] Cokenergy operates a combined heat and power system that uses the waste heat in the flue gas from Indiana Harbor Coke Company's (IHCC) metallurgical coke facility to produce steam and electricity for the Cleveland-Cliffs Indiana Harbor integrated steel mill. Cokenergy owns and operates the 16 HRSG to recover heat from the flue gas to allow for environmental treatment by the flue gas desulfurization system.
Table 2. Coke Oven Total Facility Emissions Used in Risk Modeling, with Alternate Door Leak Equation (TPY)
                          Facility Name-City-State[1]
                              Facility Type2 and 
                                  Coke Type 
                              Coke Capacity (TPY)
                       HAP Emissions (TPY) - Actuals[3]



                           Source Category CCCCC[4]
                               NonCategory[5,6]
                               Total Facility[7]
ABC-Tarrant-AL
ByP-foundry coke
                                    699,967
                                      9.3
                                      13
                                      22
CC-Follansbee-WV
ByP-blast furnace coke
                                   1,346,000
                                      11
                                      7.3
                                      19
CC-Middletown-OH
ByP-blast furnace coke
                                    456,000
                                      20
                                      10
                                      29
CC-BurnsHarbor-IN
ByP-blast furnace coke
                                   1,900,000
                                      26
                                      88
                                      114
CC-Monessen-PA
ByP-blast furnace coke
                                    372,581
                                      2.5
                                      4.4
                                      6.9
CC-Warren-OH
ByP-blast furnace coke
                                    549,000
                                      7.2
                                      7.2
                                      14
BLU-Birmingham-AL
ByP-foundry coke
                                    596,775
                                      6.3
                                      10
                                      16
EES-RiverRouge-MI
ByP-blast furnace coke
                                   1,050,000
                                      20
                                      4.4
                                      24
USS-Clairton-PA
ByP-blast furnace coke
                                   6,422,997
                                      37
                                      28
                                      65
SC-EastChicago-IN
HNR-blast furnace coke
                                   1,300,000
                                      524
                                    0.0067
                                      524
SC-FranklinFurnace-OH
HNR-blast furnace coke
                                   1,100,000
                                      389
                                     0.66
                                      389
SC-GraniteCity-IL
HNR-blast furnace coke
                                    650,000
                                      202
                                     0.36
                                      202
SC-Middletown-OH
HNR-blast furnace coke
                                    550,000
                                      49
                                    0.0028
                                      49
SC-Vansant-VA
HNR-blast furnace coke
                                    745,000
                                      965
                                      11
                                      976
Total
 
 
                                     2,267
                                      183
                                     2,451
[1] CC = Cleveland Cliffs. BLU = Bluestone. SC = SunCoke. USS = U.S. Steel.
[2] ByP = ByP; HNR = heat and/or nonrecovery.	
[3] HAP emissions have been adjusted for nondetected values.
[4] Includes Coke PQBS NESHAP source category emissions from ByP pushing, ByP combustion (battery) stack, HNR operations (HNR pushing, HRSG main stack, HRSG bypass/waste heat stack), quench towers and fugitive pushing
[5] Includes noncategory emissions from Coke Oven Batteries NESHAP sources (charging, Doors (using alternate equation), lids, offtakes) boilers, flares, 40 CFR part 61, subpart L NESHAP ByP chemical plant, co-located II&S facilities, and other operations. 
[6] Co-located II&S (noncategory) emissions: CC-Middletown-OH = 1.4 TPY; CC-BurnsHarbor-IN = 78 TPY (with sinter plant)
[7] 931 tpy emissions from HCl (out of 976 total HAP for the facility) are from 16 HRSG bypass/waste heat stacks at SC-Vansant-VA, a HNR facility. The footprint of the SC-Vansant-VA facility, among other factors, does not allow for HRSGs. As such, all combusted flue gases are ducted continuously (8,760 hr/yr) to the HRSG bypass/waste heat stacks. Other HNR SunCoke facilities route combusted flue gas to HRSGs and then to a spray dryer absorber (SDA) and baghouse for SO2 and PM control. The SDA also controls HCl.

Table 3. Total HAP Emissions (lb/ton) for Coke Oven Facilities Used in Risk Modeling by Source Category and Facility[1]
                                   Facility
                            HAP Emissions (lb/ton)

                                  PQBS NESHAP
                              Source Category[2]
                                Noncategory[3]
                                Total Facility
ABC-Tarrant-AL
                                     0.035
                                     0.049
                                     0.084
CC-Follansbee-WV
                                     0.039
                                     0.026
                                     0.068
CC-Middletown-OH
                                     0.10
                                     0.050
                                     0.14
CC-BurnsHarbor-IN
                                     0.028
                                     0.093
                                     0.12
CC-Monessen-PA
                                     0.015
                                     0.026
                                     0.041
CC-Warren-OH
                                     0.040
                                     0.040
                                     0.078
BLU-Birmingham-AL
                                     0.036
                                     0.057
                                     0.092
EES-RiverRouge-MI
                                     0.041
                                    0.0090
                                     0.049
USS-Clairton-PA
                                     0.020
                                     0.015
                                     0.034
Subtotal ByP
                                     0.35
                                     0.37
                                     0.71
SC-EastChicago-IN
                                     0.81
                                   0.000010
                                     0.81
SC-FranklinFurnace-OH
                                      1.1
                                    0.0019
                                      1.1
SC-GraniteCity-IL
                                     0.94
                                    0.0017
                                     0.94
SC-Middletown-OH
                                     0.27
                                   0.000016
                                     0.27
SC-Vansant-VA
                                      2.7
                                     0.031
                                      2.7
Subtotal  -  HNR
                                      5.9
                                     0.035
                                      5.9
[1] lb/ton = pound HAP emitted per ton coke produced. HNR = heat and nonrecovery. HAP emissions have been adjusted for nondetected values by using half of the MDL, as per EPA risk assessment protocol.
[2] Source category emission points include, as applicable: pushing (controlled), fugitive pushing, ByP battery (combustion) stack, HRSG main stacks, HRSG bypass/waste heat stacks, quench towers.
[3] Noncategory emissions points include, as applicable: Coke Oven Batteries NESHAP sources (charging, doors, lids, offtakes); boiler stacks; flares; ByP chemical recovery plant; co-located II&S; and other miscellaneous noncategory sources.


Table 4. Total Coke Oven Facility Actual Emissions by Process with Alternate Door Leak Equation (TPY)
                                  Process ID
                      HAP Emissions (TPY)  -  Actuals[1]
                                       
                                ABC-Tarrant-AL
                               CC-Follansbee-WV
                               CC-Middletown-OH
                               CC-BurnsHarbor-IN
                                CC-Monessen-PA
                                 CC-Warren-OH
                               BLU-Birmingham-AL
                               EES-RiverRouge-MI
                               SC-EastChicago-IN
                             SC-FranklinFurnace-OH
                               SC-GraniteCity-IL
                               SC-Middletown-OH
                                 SC-Vansant-VA
                                USS-Clairton-PA
                            Process ID Total (TPY)
ByP Pushing (CD)
                                      3.7
                                     0.62
                                     0.13
                                      3.3
                                     0.44
                                     0.40
                                      2.4
                                      1.1
                                      --
                                      --
                                      --
                                      --
                                      --
                                      4.2
                                      16
ByP Battery (Combustion) Stack
                                      5.1
                                      10
                                      20
                                      22
                                      1.8
                                      6.6
                                      3.4
                                      18
                                      --
                                      --
                                      --
                                      --
                                      --
                                      31
                                      117
HRSG Main Stacks[2]
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      242
                                      353
                                      177
                                      24
                                      --
                                       
                                      796
HRSG Bypass/waste heat Stacks
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      280
                                      34
                                      24
                                      24
                                      964
                                      --
                                     1,326
HNR Pushing (CD)
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      1.2
                                     0.61
                                     0.39
                                     0.31
                                     0.48
                                      --
                                      3.0
Quench Tower
                                     0.29
                                     0.31
                                     0.22
                                      1.0
                                     0.19
                                     0.20
                                     0.19
                                     0.55
                                     0.72
                                     0.38
                                     0.24
                                     0.20
                                     0.39
                                      2.1
                                      7.0
Fugitive Pushing
                                     0.19
                                     0.045
                                     0.019
                                     0.13
                                     0.014
                                     0.031
                                     0.27
                                     0.087
                                     0.068
                                     0.036
                                     0.022
                                     0.019
                                     0.037
                                     0.019
                                      1.0
ByP Charging
                                     0.070
                                     0.068
                                     0.089
                                     0.29
                                     0.056
                                     0.074
                                     0.056
                                     0.035
                                      --
                                      --
                                      --
                                      --
                                      --
                                     0.29
                                      1.0
HNR Charging (CD)
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                    0.0067
                                    0.0053
                                    0.0033
                                    0.0028
                                    0.0032
                                       0
                                     0.021
Doors-Coke-Side
Alternate Equation
                                     0.52
                                     0.36
                                     0.35
                                     0.81
                                     0.016
                                     0.27
                                     0.44
                                     0.026
                                      --
                                      --
                                      --
                                      --
                                      --
                                     0.86
                                      3.6
Doors-Push-Side
Alternate Equation
                                     0.52
                                     0.36
                                     0.35
                                     0.81
                                     0.016
                                     0.27
                                     0.44
                                     0.026
                                      --
                                      --
                                      --
                                      --
                                      --
                                     0.86
                                      3.6
Lids[3]
                                    0.0032
                                    0.00095
                                    0.00040
                                     0.019
                                       0
                                    0.0070
                                     0.016
                                    0.0015
                                      --
                                      --
                                      --
                                      --
                                      --
                                    0.0057
                                     0.054
Offtakes
                                    0.00020
                                     0.049
                                    0.00069
                                     0.019
                                    0.00084
                                     0.072
                                     0.028
                                    0.0038
                                      --
                                      --
                                      --
                                      --
                                      --
                                     0.19
                                     0.37
ByP Boiler Stacks[4]
                                      7.0
                                     0.57
                                     0.18
                                      1.8
                                     0.23
                                     0.47
                                      5.8
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      1.8
                                      18
Flare[5]
                                      1.7
                                      1.3
                                      1.5
                                      1.5
                                      2.3
                                      1.5
                                      1.0
                                      1.5
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      12
ByP Chemical Plant
                                      3.1
                                      4.6
                                      2.0
                                      4.1
                                      1.8
                                      4.4
                                      2.1
                                      2.8
                                      --
                                      --
                                      --
                                      --
                                      --
                                      23
                                      48
Co-located II&S[6]
                                      --
                                      --
                                      1.4
                                      78
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      80
Other
                                       0
                                    0.00036
                                      3.7
                                     0.47
                                       0
                                     0.080
                                       0
                                       0
                                   0.0000075
                                     0.65
                                     0.36
                                       0
                                      11
                                     0.17
                                      16
Facility Total (TPY)
                                      22
                                      19
                                      29
                                    CAA 114
                                      6.9
                                      14
                                      16
                                      24
                                      302
                                      74
                                      45
                                      44
                                      976
                                      65
                                     1,751
[1] HAP emissions have been adjusted for nondetected values by using half of the MDL.
[2] No HRSG main stacks at SC-Vansant-VA.
[3] For Lids: ABC-Tarrant-AL and CC-Monessen-PA all batteries had no actual COG emissions.
[4] No boiler at EES-RiverRouge-MI.
[5] Flare: none at USS-Clairton-PA.
[6] Co-located II&S at CC-Middletown-OH and CC-BurnsHarbor-IN.
 Table 5. Total PQBS NESHAP Metal HAP Emissions by Facility and Process (TPY)
                              Facility-City-State
                                 Facility Type
                     PQBS NESHAP Metal HAP Emissions (TPY
                                       
                                       
                                 Pushing (CD)
                               Fugitive Pushing
                               BP Battery Stack
                               HRSG Main Stacks
                                 HRSG Bypass/
                               Waste Heat Stacks
                                 Quench Tower
                                Facility Total 
                                     (TPY)
ABC-Tarrant-AL
ByP
                                    1.4E-02
                                    2.2E-03
                                    1.2E-01
                                      NA
                                      NA
                                    2.5E-02
                                     0.16
CC-Follansbee-WV

                                    4.6E-03
                                    2.8E-03
                                    1.2E-01
                                       
                                       
                                    2.7E-02
                                     0.16
CC-Middletown-OH

                                    1.6E-03
                                    1.2E-03
                                    8.0E-02
                                       
                                       
                                    1.9E-02
                                     0.10
CC-BurnsHarbor-IN

                                    6.0E-03
                                    8.0E-03
                                    1.1E+00
                                       
                                       
                                    9.1E-02
                                      1.2
CC-Monessen-PA

                                    5.8E-03
                                    8.7E-04
                                    1.4E-02
                                       
                                       
                                    1.6E-02
                                     0.036
CC-Warren-OH

                                    2.9E-03
                                    1.9E-03
                                    7.7E-02
                                       
                                       
                                    1.7E-02
                                     0.10
BLU-Birmingham-AL

                                    9.5E-03
                                    2.9E-03
                                    7.7E-02
                                       
                                       
                                    1.7E-02
                                     0.11
EES-RiverRouge-MI

                                    8.0E-03
                                    5.5E-03
                                    2.1E-01
                                       
                                       
                                    4.7E-02
                                     0.27
USS-Clairton-PA

                                    3.1E-02
                                    1.2E-03
                                    1.3E-01
                                       
                                       
                                    1.8E-01
                                     0.34
SC-EastChicago-IN
HNR
                                    4.5E-02
                                    7.2E-03
                                      NA
                                    1.4E-01
                                    1.2E+00
                                    6.3E-02
                                      1.5
SC-FranklinFurnace-OH

                                    2.3E-02
                                    3.8E-03
                                       
                                    2.8E-01
                                    1.2E-01
                                    3.3E-02
                                     0.46
SC-GraniteCity-IL

                                    2.1E-02
                                    2.4E-03
                                       
                                    1.4E-01
                                    1.3E-01
                                    2.1E-02
                                     0.31
SC-Middletown-OH

                                    6.6E-03
                                    2.0E-03
                                       
                                    1.2E-01
                                    1.0E-01
                                    1.7E-02
                                     0.25
SC-Vansant-VA

                                    1.8E-02
                                    3.9E-03
                                       
                                      NA
                                    4.1E+00
                                    3.4E-02
                                      4.2
Total HAP for Process (tpy)
                                     0.19
                                     0.046
                                      1.9
                                     0.68
                                      5.7
                                     0.61
                                      9.1




Table 6. HAP Emissions by Facility and HAP with Default Industry Averages for ByP Chemical Plants 
                                      HAP
                       Industry Average (Default) (TPY)
           By Product Noncategory Chemical Plant HAP Emissions (TPY)


                                ABC-Tarrant-AL
                               CC-Follansbee-WV
                               CC-Middletown-OH
                               CC-BurnsHarbor-IN
                                CC-Monessen-PA
                                 CC-Warren-OH
                               BLU-Birmingham-AL
                               EES-RiverRouge-MI
                                USS-Clairton-PA
Anthracene
                                   5.19E-03
                                   2.00E-04
                                   2.29E-02
                                   6.00E-03
                                  5.19E-03[1]
                                  5.19E-03[1]
                                   4.96E-03
                                   1.30E-03
                                   7.79E-09
                                   1.00E-03
Benzene
                                   1.04E+00
                                   1.30E+00
                                   1.25E+00
                                   9.55E-01
                                   1.67E-01
                                   7.90E-01
                                   2.44E+00
                                   3.76E-01
                                   7.22E-01
                                   1.34E+00
Benzo[a]Pyrene
                                   4.93E-04
                                  4.93E-04[1]
                                   6.07E-05
                                  4.93E-04[1]
                                  4.93E-04[1]
                                  4.93E-04[1]
                                   1.71E-05
                                  4.93E-04[1]
                                  4.93E-04[1]
                                   1.40E-03
Biphenyl
                                   3.40E-03
                                  3.40E-03[1]
                                  3.40E-03[1]
                                  3.40E-03[1]
                                   6.60E-03
                                  3.40E-03[1]
                                  3.40E-03[1]
                                  3.40E-03[1]
                                  3.40E-03[1]
                                   2.00E-04
Cresol/Cresylic Acid[2] 
                                   3.85E-02
                                   4.00E-03
                                   6.57E-02
                                   3.21E-02
                                  3.85E-02[1]
                                  3.85E-02[1]
                                  3.85E-02[1]
                                   9.05E-02
                                  3.85E-02[1]
                                   2.00E-04
Cyanide
                                   7.73E-01
                                   4.21E-01
                                   2.02E-01
                                   1.10E-01
                                   9.36E-01
                                   1.74E-01
                                   2.45E-01
                                   1.85E-01
                                   4.12E-01
                                   4.27E+00
Dibenzofuran
                                   4.20E-03
                                   1.60E-03
                                   5.66E-03
                                   2.76E-03
                                   1.97E-02
                                   2.10E-04
                                  4.20E-03[1]
                                   3.00E-04
                                   2.16E-03
                                   1.20E-03
Ethyl Benzene
                                   5.88E-03
                                   3.00E-04
                                  5.88E-03[1]
                                  5.88E-03[1]
                                   6.60E-03
                                  5.88E-03[1]
                                  5.88E-03[1]
                                   2.30E-03
                                  5.88E-03[1]
                                   1.43E-02
Hydrochloric Acid
                                   1.77E+00
                                   8.63E-01
                                   5.95E-01
                                   3.24E-01
                                   2.73E+00
                                   5.12E-01
                                   7.23E-01
                                   5.33E-01
                                   1.21E+00
                                   8.43E+00
Naphthalene
                                   3.66E-01
                                   2.50E-01
                                   1.75E+00
                                   2.18E-01
                                   1.32E-01
                                   2.04E-01
                                   4.32E-01
                                   1.36E-01
                                   1.36E-01
                                   4.02E-02
PAH, total[3]
                                   3.46E-02
                                   7.10E-03
                                   1.54E-01
                                   3.66E-02
                                  3.46E-02[1]
                                   5.44E-03
                                   4.50E-02
                                   9.80E-03
                                   9.53E-03
                                   8.80E-03
Phenol
                                   1.11E+00
                                   8.25E-02
                                   1.44E-01
                                   3.53E-02
                                   3.82E-02
                                   1.63E-02
                                   2.58E-02
                                   6.05E-01
                                   1.32E-01
                                   8.87E+00
Quinoline
                                   2.36E-03
                                  2.36E-03[1]
                                  2.36E-03[1]
                                  2.36E-03[1]
                                   6.50E-03
                                   5.20E-04
                                  2.36E-03[1]
                                  2.36E-03[1]
                                   7.48E-05
                                  2.36E-03[1]
Styrene
                                   1.84E-02
                                   1.13E-02
                                   7.91E-02
                                   3.86E-02
                                   1.52E-02
                                   2.70E-04
                                   3.13E-03
                                   7.00E-03
                                   8.25E-03
                                   2.60E-03
Toluene
                                   1.61E-01
                                   1.63E-01
                                   2.57E-01
                                   1.70E-01
                                   8.50E-03
                                   6.43E-03
                                   3.41E-01
                                   8.47E-02
                                   7.32E-02
                                   3.43E-01
Xylenes[2] 
                                   4.73E-02
                                   2.88E-02
                                   1.05E-01
                                   4.39E-02
                                   6.00E-03
                                   5.20E-04
                                   1.05E-01
                                   1.77E-02
                                   1.09E-02
                                   1.08E-01
[1] Indicates default values developed from the average of facility-level industry data (shown in the first data column).
[2] Includes mixed isomers.
[3] Although naphthalene is also a PAH, naphthalene is listed separately here because it is a separately CAA-listed HAP.

                                       
                                       
                                       
                                       
                                       
                                       
                                       
                                       

            Table 7. Noncategory HAP Emissions by Facility and HAP 
                                      HAP
                                ABC-Tarrant-AL
                               AKS-Follansbee-WV
                               AKS-Middletown-OH
                               AM-BurnsHarbor-IN
                                AM-Monessen-PA
                                 AM-Warren-OH
                               BLU-Birmingham-AL
                               EES-RiverRouge-MI
                               SC-EastChicago-IN
                             SC-FranklinFurnace-OH
                               SC-GraniteCity-IL
                               SC-Middletown-OH
                                 SC-Vansant-VA
                                USS-Clairton-PA
Acid Gases 
(HCl, HF)
                                    4.0E+00
                                    8.4E-01
                                    3.3E+00
                                    8.3E+00
                                    6.3E-01
                                    9.6E-01
                                    3.1E+00
                                    1.2E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    3.2E+00
                                    9.3E+00
Dioxin/furans
                                    3.5E-08
                                    7.1E-09
                                    2.6E-09
                                    1.9E-05
                                    3.3E-09
                                    6.8E-09
                                    2.9E-08
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    2.7E-08
Formaldehyde
                                    0.0E+00
                                    3.1E-03
                                    4.5E-01
                                    4.6E-01
                                    0.0E+00
                                    3.1E-03
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    2.5E-02
                                    0.0E+00
                                    0.0E+00
                                    1.7E-04
                                    0.0E+00
Antimony
                                    3.4E-04
                                    9.5E-05
                                    3.0E-03
                                    1.3E-02
                                    4.4E-05
                                    9.1E-05
                                    2.8E-04
                                    0.0E+00
                                    2.5E-04
                                    2.0E-04
                                    1.2E-04
                                    1.0E-04
                                    1.2E-04
                                    3.6E-04
Arsenic
                                    2.1E-02
                                    5.4E-04
                                    1.8E-02
                                    2.3E-02
                                    2.5E-04
                                    5.2E-04
                                    1.7E-02
                                    0.0E+00
                                    8.2E-04
                                    7.2E-04
                                    4.1E-04
                                    3.4E-04
                                    3.9E-04
                                    2.0E-03
Beryllium
                                    8.5E-05
                                    1.6E-05
                                    5.4E-04
                                    3.2E-03
                                    7.5E-06
                                    1.6E-05
                                    6.9E-05
                                    0.0E+00
                                    2.4E-05
                                    2.1E-05
                                    1.2E-05
                                    1.0E-05
                                    1.1E-05
                                    6.1E-05
Cadmium
                                    1.7E-03
                                    6.2E-05
                                    3.8E-02
                                    3.8E-01
                                    7.5E-06
                                    6.1E-05
                                    1.4E-03
                                    0.0E+00
                                    4.9E-05
                                    4.1E-04
                                    2.4E-05
                                    2.0E-05
                                    2.3E-05
                                    6.1E-05
Chromium
                                    5.6E-02
                                    1.5E-03
                                    5.7E-02
                                    7.0E-02
                                    6.7E-04
                                    1.4E-03
                                    4.6E-02
                                    0.0E+00
                                    1.2E-03
                                    1.5E-03
                                    6.2E-04
                                    5.2E-04
                                    5.9E-04
                                    5.4E-03
Cobalt
                                    2.1E-03
                                    2.7E-04
                                    3.3E-03
                                    2.5E-02
                                    1.2E-04
                                    2.5E-04
                                    1.7E-03
                                    0.0E+00
                                    9.2E-05
                                    1.0E-04
                                    4.6E-05
                                    3.8E-05
                                    4.4E-05
                                    9.8E-04
Lead
                                    1.1E-02
                                    5.7E-03
                                    5.1E-01
                                    1.1E+01
                                    5.6E-03
                                    5.7E-03
                                    1.0E-02
                                    5.5E-03
                                    8.1E-04
                                    6.4E-04
                                    3.0E-01
                                    3.3E-04
                                    1.8E-01
                                    8.5E-04
Manganese
                                    3.0E-02
                                    9.2E-04
                                    6.3E-01
                                    8.2E-01
                                    4.2E-04
                                    8.8E-04
                                    2.4E-02
                                    0.0E+00
                                    1.7E-03
                                    1.5E-03
                                    8.7E-04
                                    7.3E-04
                                    8.3E-04
                                    3.4E-03
Mercury2
                                    9.5E-04
                                    1.7E-03
                                    4.2E-02
                                    9.1E-02
                                    8.1E-04
                                    1.4E-03
                                    8.3E-04
                                    2.4E-04
                                    8.7E-05
                                    1.6E-04
                                    4.4E-05
                                    3.6E-05
                                    3.4E-03
                                    4.6E-03
Nickel
                                    1.4E-01
                                    2.5E-03
                                    4.4E-02
                                    9.5E-02
                                    1.1E-03
                                    2.4E-03
                                    1.1E-01
                                    0.0E+00
                                    1.3E-03
                                    1.8E-03
                                    6.6E-04
                                    5.5E-04
                                    6.2E-04
                                    9.1E-03
Selenium
                                    7.4E-03
                                    4.3E-04
                                    6.3E-03
                                    1.4E-01
                                    2.0E-04
                                    4.1E-04
                                    6.0E-03
                                    0.0E+00
                                    2.4E-04
                                    2.0E-04
                                    1.2E-04
                                    1.0E-04
                                    1.2E-04
                                    1.6E-03
HCN
                                    9.1E-01
                                    4.6E-01
                                    2.9E-01
                                    2.4E+00
                                    3.0E-01
                                    4.9E-01
                                    5.9E-01
                                    4.3E-01
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    5.2E+00
Naphthalene
                                    3.4E+00
                                    1.8E+00
                                    2.9E-01
                                    1.2E+00
                                    2.8E-01
                                    5.1E-01
                                    2.8E+00
                                    2.1E-01
                                    0.0E+00
                                    2.1E-04
                                    0.0E+00
                                    0.0E+00
                                    1.2E-05
                                    4.2E-02
PAH (total)
                                    5.6E-02
                                    1.8E-01
                                    4.6E-02
                                    7.4E-01
                                    1.4E-02
                                    5.6E-02
                                    5.1E-02
                                    1.0E-02
                                    0.0E+00
                                    2.4E-05
                                    0.0E+00
                                    0.0E+00
                                    3.5E-04
                                    3.5E-02
VOHAP (total)
                                    2.9E+00
                                    2.7E+00
                                    2.4E+00
                                    3.2E+01
                                    2.8E+00
                                    4.1E+00
                                    1.1E+00
                                    2.0E+00
                                    0.0E+00
                                    1.9E-03
                                    0.0E+00
                                    0.0E+00
                                    3.4E-01
                                    1.9E+00
1,3-Butadiene
                                    2.3E-01
                                    2.3E-01
                                    2.3E-01
                                    2.3E-01
                                    2.3E-01
                                    2.3E-01
                                    2.3E-01
                                    2.3E-01
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
Biphenyl
                                    3.4E-03
                                    3.4E-03
                                    3.4E-03
                                    6.6E-03
                                    3.4E-03
                                    3.4E-03
                                    3.4E-03
                                    3.4E-03
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    2.0E-04
Coke Oven Emissions
                                    1.1E+00
                                    8.3E-01
                                    7.9E-01
                                    1.9E+00
                                    8.8E-02
                                    6.9E-01
                                    9.7E-01
                                    9.3E-02
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    2.2E+00
Cresol/Cresylic Acid (Mixed Isomers)
                                    4.0E-03
                                    6.6E-02
                                    3.2E-02
                                    3.9E-02
                                    3.9E-02
                                    3.9E-02
                                    9.1E-02
                                    3.9E-02
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    2.0E-04
Dibenzofuran
                                    1.6E-03
                                    5.7E-03
                                    2.8E-03
                                    2.0E-02
                                    2.1E-04
                                    4.2E-03
                                    3.0E-04
                                    2.2E-03
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    1.2E-03
Hexane
                                    0.0E+00
                                    7.4E-02
                                    6.8E-02
                                    0.0E+00
                                    0.0E+00
                                    7.4E-02
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    6.1E-01
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
Phenol
                                    8.3E-02
                                    1.4E-01
                                    3.5E-02
                                    3.8E-02
                                    1.6E-02
                                    2.6E-02
                                    6.1E-01
                                    1.3E-01
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    8.9E+00
Quinoline
                                    2.4E-03
                                    2.4E-03
                                    2.4E-03
                                    6.5E-03
                                    5.2E-04
                                    2.4E-03
                                    2.4E-03
                                    7.5E-05
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    2.4E-03
Acetaldehyde
                                    0.0E+00
                                    0.0E+00
                                    1.3E-01
                                    0.0E+00
                                    0.0E+00
                                    9.7E-04
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    7.3E-03
                                    0.0E+00
                                    0.0E+00
                                    1.1E-04
                                    0.0E+00
Acrolein
                                    0.0E+00
                                    0.0E+00
                                    1.2E-01
                                    0.0E+00
                                    0.0E+00
                                    8.3E-04
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    6.3E-03
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
Carbonyl Sulfide
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    2.7E+01
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
Ethylene Glycol
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    3.9E-02
Glycol Ethers
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    6.8E-02
Phosphorus
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    0.0E+00
                                    6.4E-02
                                    0.0E+00
                                    7.3E+00
                                    0.0E+00
Total
                                      13
                                      7.3
                                      10
                                      88
                                      4.4
                                      7.2
                                      10
                                      4.4
                                    0.0067
                                     0.66
                                     0.36
                                    0.0028
                                      11
                                      28

    Table 8. HAP Emissions by PQBS NESHAP Process (TPY)  -  ABC-Tarrant-AL
                                     HAP/
                                HAP Group[1] 
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    3.8E-01
                                    2.0E-02
                                    2.3E+00
                                    1.1E-01
Dioxin/furans
                                    9.7E-09
                                    5.1E-10
                                    2.3E-07
                                    3.4E-08
Formaldehyde
                                    2.0E-03
                                    1.0E-04
                                    1.9E-02
                                    3.4E-03
HAP Metals (total)
                                    1.4E-02
                                    2.2E-03
                                    1.2E-01
                                    2.5E-02
                                                                       Antimony
                                    4.1E-05
                                    3.1E-04
                                    5.2E-04
                                    8.9E-04
                                                                        Arsenic
                                    5.5E-05
                                    2.0E-04
                                    7.5E-03
                                    1.8E-02
                                                                      Beryllium
                                    1.0E-05
                                    9.0E-06
                                    1.3E-04
                                    6.9E-05
                                                                        Cadmium
                                    3.3E-05
                                    9.9E-05
                                    1.9E-04
                                    5.6E-05
                                                                    Chromium[2]
                                    9.3E-04
                                    2.1E-04
                                    3.1E-02
                                    7.0E-04
                                                                         Cobalt
                                    3.0E-05
                                    3.4E-05
                                    1.9E-03
                                    1.6E-04
                                                                           Lead
                                    1.1E-04
                                    3.3E-04
                                    7.9E-03
                                    2.0E-03
                                                                      Manganese
                                    1.2E-02
                                    3.2E-04
                                    2.0E-02
                                    6.6E-04
                                                                     Mercury[3]
                                    2.7E-05
                                    2.0E-04
                                    1.3E-03
                                    3.0E-04
                                                                         Nickel
                                    9.3E-04
                                    3.6E-04
                                    4.0E-02
                                    6.6E-04
                                                                       Selenium
                                    1.8E-04
                                    7.5E-05
                                    4.7E-03
                                    1.7E-03
HCN
                                    1.2E-01
                                    6.2E-03
                                    9.9E-01
                                    4.0E-02
Naphthalene
                                    9.4E-02
                                    2.8E-03
                                    1.0E+00
                                    5.5E-03
PAH (total)
                                    7.5E-02
                                    4.1E-03
                                    2.0E-01
                                    1.4E-02
VOHAP (total)
                                    3.0E+00
                                    1.6E-01
                                    5.2E-01
                                    9.2E-02
Total HAP by Process
                                      3.7
                                     0.19
                                      5.1
                                     0.29
Total HAP
                                      9.3
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020) 

                                       
                                       
                                       

   Table 9. HAP Emissions by PQBS NESHAP Process (TPY)  -  CC-Follansbee-WV
                                     HAP/
                                HAP Group[1] 
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    3.6E-01
                                    2.1E-02
                                    7.2E+00
                                    1.2E-01
Dioxin/furans
                                    3.2E-09
                                    2.3E-10
                                    1.7E-07
                                    3.7E-08
Formaldehyde
                                    8.5E-04
                                    4.0E-05
                                    2.7E-03
                                    3.6E-03
HAP Metals (total)
                                    4.6E-03
                                    2.8E-03
                                    1.2E-01
                                    2.7E-02
                                                                       Antimony
                                    3.5E-05
                                    3.0E-05
                                    4.2E-04
                                    9.5E-04
                                                                        Arsenic
                                    3.9E-05
                                    6.2E-04
                                    4.5E-03
                                    1.9E-02
                                                                      Beryllium
                                    1.5E-05
                                    7.9E-06
                                    8.0E-05
                                    7.4E-05
                                                                        Cadmium
                                    1.9E-05
                                    1.6E-05
                                    1.4E-04
                                    6.0E-05
                                                                    Chromium[2]
                                    1.5E-03
                                    5.9E-05
                                    5.8E-02
                                    7.5E-04
                                                                         Cobalt
                                    3.2E-05
                                    2.9E-05
                                    5.3E-04
                                    1.7E-04
                                                                           Lead
                                    1.3E-04
                                    9.9E-04
                                    6.0E-03
                                    2.1E-03
                                                                      Manganese
                                    1.4E-03
                                    3.2E-04
                                    9.9E-03
                                    7.0E-04
                                                                     Mercury[3]
                                    5.4E-05
                                    4.2E-06
                                    2.2E-03
                                    3.2E-04
                                                                         Nickel
                                    1.0E-03
                                    6.1E-04
                                    3.1E-02
                                    7.0E-04
                                                                       Selenium
                                    3.5E-04
                                    1.4E-04
                                    7.5E-03
                                    1.8E-03
HCN
                                    1.5E-01
                                    9.2E-03
                                    4.1E-01
                                    4.3E-02
Naphthalene
                                    6.0E-03
                                    3.2E-04
                                    1.2E-01
                                    5.9E-03
PAH (total)
                                    4.1E-03
                                    6.4E-04
                                    4.9E-02
                                    1.5E-02
VOHAP (total)
                                    1.0E-01
                                    1.1E-02
                                    2.4E+00
                                    9.9E-02
Total HAP by Process
                                     0.62
                                     0.045
                                      10
                                     0.31
Total HAP
                                      11
1 For list of individual HAP in the HAP groups see Appendix Table A-3. HCl = hydrogen chloride; HCN = hydrogen cyanide; HF = hydrogen fluoride.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016). 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020). 
                                       
   Table 10. HAP Emissions by PQBS NESHAP Process (TPY)  -  CC-Middletown-OH
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    5.1E-02
                                    9.0E-03
                                    1.2E+01
                                    8.5E-02
Dioxin/furans
                                    7.7E-10
                                    9.7E-11
                                    4.8E-08
                                    2.6E-08
Formaldehyde
                                    1.6E-07
                                    1.7E-05
                                    2.2E-03
                                    2.6E-03
HAP Metals (total)
                                    1.6E-03
                                    1.2E-03
                                    8.0E-02
                                    1.9E-02
                                                                       Antimony
                                    1.0E-05
                                    1.3E-05
                                    6.2E-04
                                    6.8E-04
                                                                        Arsenic
                                    2.1E-05
                                    2.6E-04
                                    9.5E-03
                                    1.4E-02
                                                                      Beryllium
                                    4.2E-06
                                    3.4E-06
                                    9.6E-05
                                    5.3E-05
                                                                        Cadmium
                                    2.1E-06
                                    6.7E-06
                                    1.1E-04
                                    4.3E-05
                                                                    Chromium[2]
                                    6.4E-04
                                    2.5E-05
                                    2.0E-02
                                    5.4E-04
                                                                         Cobalt
                                    9.7E-06
                                    1.2E-05
                                    2.2E-04
                                    1.2E-04
                                                                           Lead
                                    4.5E-05
                                    4.2E-04
                                    1.2E-02
                                    1.5E-03
                                                                      Manganese
                                    3.4E-04
                                    1.4E-04
                                    9.1E-03
                                    5.0E-04
                                                                     Mercury[3]
                                    2.5E-06
                                    1.8E-06
                                    8.4E-04
                                    2.3E-04
                                                                         Nickel
                                    5.0E-04
                                    2.6E-04
                                    1.3E-02
                                    5.0E-04
                                                                       Selenium
                                    4.2E-05
                                    6.1E-05
                                    1.4E-02
                                    1.3E-03
HCN
                                    2.3E-02
                                    3.9E-03
                                    6.1E-01
                                    3.1E-02
Naphthalene
                                    1.1E-03
                                    1.3E-04
                                    2.6E-01
                                    4.2E-03
PAH (total)
                                    2.9E-04
                                    2.7E-04
                                    1.1E-01
                                    1.1E-02
VOHAP (total)
                                    5.6E-02
                                    4.4E-03
                                    6.2E+00
                                    7.1E-02
Total HAP by Process
                                     0.13
                                     0.019
                                      20
                                     0.22
Total HAP
                                      20
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020) 
                                       
                                       
  Table 11. HAP Emissions by PQBS NESHAP Process (TPY)  -  CC-BurnsHarbor-IN
                                     HAP/
                                HAP Group[1] 
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    2.3E+00
                                    6.0E-02
                                    1.5E+01
                                    4.0E-01
Dioxin/furans
                                    1.4E-08
                                    6.5E-10
                                    2.9E-07
                                    1.2E-07
Formaldehyde
                                    1.2E-03
                                    1.1E-04
                                    1.1E-02
                                    1.2E-02
HAP Metals (total)
                                    6.0E-03
                                    8.0E-03
                                    1.1E+00
                                    9.1E-02
                                                                       Antimony
                                    1.4E-04
                                    8.4E-05
                                    1.9E-03
                                    3.2E-03
                                                                        Arsenic
                                    1.3E-04
                                    1.7E-03
                                    5.6E-03
                                    6.5E-02
                                                                      Beryllium
                                    3.3E-05
                                    2.2E-05
                                    4.8E-04
                                    2.5E-04
                                                                        Cadmium
                                    1.5E-04
                                    4.4E-05
                                    4.8E-04
                                    2.0E-04
                                                                    Chromium[2]
                                    7.1E-04
                                    1.7E-04
                                    6.7E-01
                                    2.5E-03
                                                                         Cobalt
                                    4.6E-05
                                    8.1E-05
                                    4.5E-03
                                    5.6E-04
                                                                           Lead
                                    6.9E-04
                                    2.8E-03
                                    1.2E-02
                                    7.0E-03
                                                                      Manganese
                                    8.9E-04
                                    9.0E-04
                                    5.8E-02
                                    2.4E-03
                                                                     Mercury[3]
                                    7.8E-05
                                    1.2E-05
                                    1.5E-02
                                    1.1E-03
                                                                         Nickel
                                    8.8E-04
                                    1.7E-03
                                    3.4E-01
                                    2.4E-03
                                                                       Selenium
                                    2.2E-03
                                    4.0E-04
                                    7.3E-03
                                    6.1E-03
HCN
                                    7.9E-01
                                    2.6E-02
                                    2.3E+00
                                    1.4E-01
Naphthalene
                                    1.7E-02
                                    8.9E-04
                                    2.9E-01
                                    2.0E-02
PAH (total)
                                    8.6E-03
                                    1.8E-03
                                    6.1E-02
                                    5.0E-02
VOHAP (total)
                                    1.9E-01
                                    3.0E-02
                                    2.6E+00
                                    3.3E-01
Total HAP by Process
                                      3.3
                                     0.13
                                      22
                                      1.0
Total HAP
                                      26
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020) 



    Table 12. HAP Emissions by PQBS NESHAP Process (TPY)  -  CC-Monessen-PA
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    2.0E-01
                                    6.4E-03
                                    1.7E+00
                                    7.1E-02
Dioxin/furans
                                    2.6E-09
                                    6.9E-11
                                    1.0E-07
                                    2.2E-08
Formaldehyde
                                    1.3E-03
                                    1.2E-05
                                    1.1E-03
                                    2.2E-03
HAP Metals (total)
                                    5.8E-03
                                    8.7E-04
                                    1.4E-02
                                    1.6E-02
                                                                       Antimony
                                    2.9E-05
                                    9.1E-06
                                    7.4E-05
                                    5.7E-04
                                                                        Arsenic
                                    2.9E-05
                                    1.9E-04
                                    4.0E-04
                                    1.2E-02
                                                                      Beryllium
                                    1.7E-05
                                    2.4E-06
                                    1.8E-05
                                    4.4E-05
                                                                        Cadmium
                                    7.2E-06
                                    4.8E-06
                                    7.6E-05
                                    3.6E-05
                                                                    Chromium[2]
                                    2.1E-03
                                    1.8E-05
                                    2.9E-03
                                    4.5E-04
                                                                         Cobalt
                                    4.1E-05
                                    8.8E-06
                                    2.5E-04
                                    1.0E-04
                                                                           Lead
                                    6.7E-05
                                    3.0E-04
                                    1.0E-03
                                    1.2E-03
                                                                      Manganese
                                    2.0E-03
                                    9.8E-05
                                    3.9E-03
                                    4.2E-04
                                                                     Mercury[3]
                                    8.0E-05
                                    1.3E-06
                                    6.5E-04
                                    1.9E-04
                                                                         Nickel
                                    1.2E-03
                                    1.9E-04
                                    2.2E-03
                                    4.2E-04
                                                                       Selenium
                                    2.0E-04
                                    4.4E-05
                                    2.1E-03
                                    1.1E-03
HCN
                                    1.2E-01
                                    2.8E-03
                                    4.3E-02
                                    2.6E-02
Naphthalene
                                    6.9E-03
                                    9.7E-05
                                    5.5E-03
                                    3.5E-03
PAH (total)
                                    5.6E-03
                                    2.0E-04
                                    9.4E-03
                                    9.0E-03
VOHAP (total)
                                    1.0E-01
                                    3.2E-03
                                    4.7E-03
                                    5.9E-02
Total HAP by Process
                                     0.44
                                     0.014
                                      1.8
                                     0.19
Total HAP
                                      2.5
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)

                                       
                                       

     Table 13. HAP Emissions by PQBS NESHAP Process (TPY)  -  CC-Warren-OH
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    2.3E-01
                                    1.5E-02
                                    4.6E+00
                                    7.6E-02
Dioxin/furans
                                    2.0E-09
                                    1.6E-10
                                    1.1E-07
                                    2.3E-08
Formaldehyde
                                    5.4E-04
                                    2.8E-05
                                    1.7E-03
                                    2.3E-03
HAP Metals (total)
                                    2.9E-03
                                    1.9E-03
                                    7.7E-02
                                    1.7E-02
                                                                       Antimony
                                    2.2E-05
                                    2.0E-05
                                    2.7E-04
                                    6.1E-04
                                                                        Arsenic
                                    2.5E-05
                                    4.2E-04
                                    2.9E-03
                                    1.2E-02
                                                                      Beryllium
                                    9.6E-06
                                    5.4E-06
                                    5.1E-05
                                    4.7E-05
                                                                        Cadmium
                                    1.2E-05
                                    1.1E-05
                                    9.0E-05
                                    3.8E-05
                                                                    Chromium[2]
                                    9.7E-04
                                    4.0E-05
                                    3.7E-02
                                    4.8E-04
                                                                         Cobalt
                                    2.1E-05
                                    2.0E-05
                                    3.4E-04
                                    1.1E-04
                                                                           Lead
                                    8.1E-05
                                    6.8E-04
                                    3.9E-03
                                    1.3E-03
                                                                      Manganese
                                    8.8E-04
                                    2.2E-04
                                    6.4E-03
                                    4.5E-04
                                                                     Mercury[3]
                                    3.4E-05
                                    2.9E-06
                                    1.4E-03
                                    2.0E-04
                                                                         Nickel
                                    6.4E-04
                                    4.2E-04
                                    2.0E-02
                                    4.5E-04
                                                                       Selenium
                                    2.2E-04
                                    9.7E-05
                                    4.8E-03
                                    1.2E-03
HCN
                                    9.3E-02
                                    6.3E-03
                                    2.6E-01
                                    2.7E-02
Naphthalene
                                    3.8E-03
                                    2.2E-04
                                    7.9E-02
                                    3.8E-03
PAH (total)
                                    2.6E-03
                                    4.4E-04
                                    3.2E-02
                                    9.6E-03
VOHAP (total)
                                    6.5E-02
                                    7.3E-03
                                    1.6E+00
                                    6.3E-02
Total HAP by Process
                                     0.40
                                     0.031
                                      6.6
                                     0.20
Total HAP
                                      7.2
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)


  Table 14. HAP Emissions by PQBS NESHAP Process (TPY)  -  BLU-Birmingham-AL
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    2.5E-01
                                    2.8E-02
                                    1.5E+00
                                    7.3E-02
Dioxin/furans
                                    6.4E-09
                                    7.1E-10
                                    1.5E-07
                                    2.3E-08
Formaldehyde
                                    1.3E-03
                                    1.5E-04
                                    1.3E-02
                                    2.2E-03
HAP Metals (total)
                                    9.5E-03
                                    2.9E-03
                                    7.7E-02
                                    1.7E-02
                                                                       Antimony
                                    2.7E-05
                                    4.1E-04
                                    3.4E-04
                                    5.9E-04
                                                                        Arsenic
                                    3.7E-05
                                    2.7E-04
                                    5.0E-03
                                    1.2E-02
                                                                      Beryllium
                                    6.7E-06
                                    1.2E-05
                                    8.6E-05
                                    4.6E-05
                                                                        Cadmium
                                    2.2E-05
                                    1.3E-04
                                    1.3E-04
                                    3.7E-05
                                                                    Chromium[2]
                                    6.2E-04
                                    2.7E-04
                                    2.1E-02
                                    4.6E-04
                                                                         Cobalt
                                    2.0E-05
                                    4.6E-05
                                    1.3E-03
                                    1.0E-04
                                                                           Lead
                                    7.6E-05
                                    4.4E-04
                                    5.2E-03
                                    1.3E-03
                                                                      Manganese
                                    8.0E-03
                                    4.3E-04
                                    1.3E-02
                                    4.4E-04
                                                                     Mercury[3]
                                    1.8E-05
                                    2.7E-04
                                    8.7E-04
                                    2.0E-04
                                                                         Nickel
                                    6.2E-04
                                    4.8E-04
                                    2.6E-02
                                    4.4E-04
                                                                       Selenium
                                    1.2E-04
                                    9.9E-05
                                    3.1E-03
                                    1.1E-03
HCN
                                    7.8E-02
                                    8.7E-03
                                    6.6E-01
                                    2.7E-02
Naphthalene
                                    6.2E-02
                                    3.7E-03
                                    6.7E-01
                                    3.7E-03
PAH (total)
                                    5.0E-02
                                    5.5E-03
                                    1.3E-01
                                    9.3E-03
VOHAP (total)
                                    2.0E+00
                                    2.2E-01
                                    3.5E-01
                                    6.1E-02
Total HAP by Process
                                      2.4
                                     0.27
                                      3.4
                                     0.19
Total HAP
                                      6.3
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)


  Table 15. HAP Emissions by PQBS NESHAP Process (TPY)  -  EES-RiverRouge-MI
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    6.2E-01
                                    4.2E-02
                                    1.3E+01
                                    2.1E-01
Dioxin/furans
                                    5.6E-09
                                    4.5E-10
                                    2.9E-07
                                    6.4E-08
Formaldehyde
                                    1.5E-03
                                    7.8E-05
                                    4.7E-03
                                    6.3E-03
HAP Metals (total)
                                    8.0E-03
                                    5.5E-03
                                    2.1E-01
                                    4.7E-02
                                                                       Antimony
                                    6.0E-05
                                    5.7E-05
                                    7.3E-04
                                    1.7E-03
                                                                        Arsenic
                                    6.8E-05
                                    1.2E-03
                                    7.9E-03
                                    3.4E-02
                                                                      Beryllium
                                    2.6E-05
                                    1.5E-05
                                    1.4E-04
                                    1.3E-04
                                                                        Cadmium
                                    3.4E-05
                                    3.0E-05
                                    2.5E-04
                                    1.0E-04
                                                                    Chromium[2]
                                    2.7E-03
                                    1.1E-04
                                    1.0E-01
                                    1.3E-03
                                                                         Cobalt
                                    5.6E-05
                                    5.5E-05
                                    9.3E-04
                                    2.9E-04
                                                                           Lead
                                    2.2E-04
                                    1.9E-03
                                    1.1E-02
                                    3.6E-03
                                                                      Manganese
                                    2.4E-03
                                    6.2E-04
                                    1.7E-02
                                    1.2E-03
                                                                     Mercury[3]
                                    9.4E-05
                                    8.1E-06
                                    3.8E-03
                                    5.6E-04
                                                                         Nickel
                                    1.7E-03
                                    1.2E-03
                                    5.5E-02
                                    1.2E-03
                                                                       Selenium
                                    6.1E-04
                                    2.8E-04
                                    1.3E-02
                                    3.2E-03
HCN
                                    2.5E-01
                                    1.8E-02
                                    7.1E-01
                                    7.5E-02
Naphthalene
                                    1.0E-02
                                    6.1E-04
                                    2.2E-01
                                    1.0E-02
PAH (total)
                                    7.2E-03
                                    1.2E-03
                                    8.6E-02
                                    2.6E-02
VOHAP (total)
                                    1.8E-01
                                    2.1E-02
                                    4.2E+00
                                    1.7E-01
Total HAP by Process
                                      1.1
                                     0.087
                                      18
                                     0.55
Total HAP
                                      20
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)
                                       

   Table 16. HAP Emissions by PQBS NESHAP Process (TPY)  -  USS-Clairton-PA
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                               ByP Battery Stack
                                 Quench Tower
Acid Gases (HCl, HF)
                                    2.4E+00
                                    9.0E-03
                                    2.9E+01
                                    8.0E-01
Dioxin/furans
                                    2.1E-08
                                    9.7E-11
                                    2.3E-06
                                    2.5E-07
Formaldehyde
                                    5.7E-03
                                    1.7E-05
                                    1.7E-02
                                    2.4E-02
HAP Metals (total)
                                    3.1E-02
                                    1.2E-03
                                    1.3E-01
                                    1.8E-01
                                                                       Antimony
                                    2.3E-04
                                    1.3E-05
                                    7.0E-04
                                    6.4E-03
                                                                        Arsenic
                                    2.6E-04
                                    2.7E-04
                                    1.7E-02
                                    1.3E-01
                                                                      Beryllium
                                    1.0E-04
                                    3.5E-06
                                    9.7E-05
                                    5.0E-04
                                                                        Cadmium
                                    1.3E-04
                                    6.8E-06
                                    9.1E-04
                                    4.0E-04
                                                                    Chromium[2]
                                    1.0E-02
                                    2.6E-05
                                    1.4E-02
                                    5.0E-03
                                                                         Cobalt
                                    2.2E-04
                                    1.3E-05
                                    6.1E-04
                                    1.1E-03
                                                                           Lead
                                    8.5E-04
                                    4.3E-04
                                    1.5E-02
                                    1.4E-02
                                                                      Manganese
                                    9.3E-03
                                    1.4E-04
                                    2.3E-02
                                    4.7E-03
                                                                     Mercury[3]
                                    3.6E-04
                                    1.8E-06
                                    1.3E-02
                                    2.1E-03
                                                                         Nickel
                                    6.7E-03
                                    2.7E-04
                                    1.1E-02
                                    4.7E-03
                                                                       Selenium
                                    2.3E-03
                                    6.2E-05
                                    3.0E-02
                                    1.2E-02
HCN
                                    9.8E-01
                                    3.9E-03
                                    1.6E-01
                                    2.9E-01
Naphthalene
                                    4.0E-02
                                    1.4E-04
                                    2.2E-01
                                    4.0E-02
PAH (total)
                                    2.8E-02
                                    2.8E-04
                                    6.5E-02
                                    1.0E-01
VOHAP (total)
                                    6.8E-01
                                    4.4E-03
                                    1.6E+00
                                    6.6E-01
Total HAP by Process
                                      4.2
                                     0.019
                                      31
                                      2.1
Total HAP
                                      37
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)


  Table 17. HAP Emissions by PQBS NESHAP Process (TPY)  -  SC-EastChicago-IN
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                                   HNR HRSG
                                  Main Stacks
                                  HNR HRSG 
                           Bypass/waste heat stacks
                                 Quench Tower
Acid Gases (HCl, HF)
                                    1.1E+00
                                    5.7E-02
                                    2.4E+02
                                    2.8E+02
                                    2.7E-01
Dioxin/furans
                                    8.0E-09
                                    4.1E-10
                                    3.3E-07
                                    1.2E-07
                                    8.5E-08
Formaldehyde
                                    9.1E-03
                                    4.7E-04
                                    2.3E+00
                                    8.3E-01
                                    8.3E-03
HAP Metals (total)
                                    4.5E-02
                                    7.2E-03
                                    1.4E-01
                                       
                                    1.2E+00
                                       
                                    6.3E-02
                                                                       Antimony
                                    1.5E-03
                                    7.6E-05
                                    1.0E-03
                                    2.9E-02
                                    2.2E-03
                                                                        Arsenic
                                    1.3E-02
                                    1.6E-03
                                    3.0E-03
                                    2.4E-01
                                    4.5E-02
                                                                      Beryllium
                                    1.9E-04
                                    2.0E-05
                                    1.7E-04
                                    2.1E-03
                                    1.7E-04
                                                                        Cadmium
                                    9.3E-05
                                    4.0E-05
                                    8.1E-04
                                    1.1E-02
                                    1.4E-04
                                                                    Chromium[2]
                                    3.4E-03
                                    1.5E-04
                                    4.6E-03
                                    1.4E-02
                                    1.7E-03
                                                                         Cobalt
                                    6.0E-04
                                    7.3E-05
                                    9.1E-04
                                    1.0E-02
                                    3.9E-04
                                                                           Lead
                                    1.7E-02
                                    2.5E-03
                                    3.6E-03
                                    6.5E-01
                                    4.8E-03
                                                                      Manganese
                                    4.5E-03
                                    8.2E-04
                                    1.4E-02
                                    9.7E-03
                                    1.6E-03
                                                                     Mercury[3]
                                    8.0E-05
                                    1.1E-05
                                    4.9E-02
                                    2.3E-02
                                    7.4E-04
                                                                         Nickel
                                    2.4E-03
                                    1.6E-03
                                    7.5E-03
                                    6.4E-02
                                    1.6E-03
                                                                       Selenium
                                    2.4E-03
                                    3.6E-04
                                    5.9E-02
                                    1.4E-01
                                    4.2E-03
HCN
                                    1.6E-02
                                    8.2E-04
                                    2.1E+00
                                    2.2E-01
                                    9.9E-02
Naphthalene
                                    1.9E-03
                                    8.1E-04
                                    4.4E-03
                                    4.2E-04
                                    1.4E-02
PAH (total)
                                    8.0E-04
                                    1.6E-03
                                    3.5E-03
                                    2.2E-03
                                    3.5E-02
VOHAP (total)
                                    1.0E-02
                                    5.4E-04
                                    2.5E+00
                                    5.4E-02
                                    2.3E-01
Total HAP by Process
                                      1.2
                                     0.068
                                      242
                                      280
                                     0.72
Total HAP
                                      524
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)


Table 18. HAP Emissions by PQBS NESHAP Process (TPY)  -  SC-FranklinFurnace-OH
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                  HNR Pushing
                               Fugitive Pushing
                                   HNR HRSG
                                  Main Stacks
                       HNR HRSG Bypass/waste heat stacks
                                 Quench Tower
Acid Gases (HCl, HF)
                                    5.7E-01
                                    3.0E-02
                                    3.4E+02
                                    3.4E+01
                                    1.4E-01
Dioxin/furans
                                    4.1E-09
                                    2.2E-10
                                    6.0E-07
                                    1.2E-08
                                    4.5E-08
Formaldehyde
                                    4.7E-03
                                    2.5E-04
                                    4.5E+00
                                    1.7E-01
                                    4.4E-03
HAP Metals (total)
                                    2.3E-02
                                    3.8E-03
                                    2.8E-01
                                    1.2E-01
                                    3.3E-02
                                                                       Antimony
                                    8.0E-04
                                    4.0E-05
                                    3.9E-03
                                    2.7E-03
                                    1.2E-03
                                                                        Arsenic
                                    6.9E-03
                                    8.3E-04
                                    7.2E-03
                                    2.8E-02
                                    2.4E-02
                                                                      Beryllium
                                    9.9E-05
                                    1.1E-05
                                    3.1E-04
                                    2.5E-04
                                    9.0E-05
                                                                        Cadmium
                                    4.8E-05
                                    2.1E-05
                                    1.7E-03
                                    1.1E-03
                                    7.2E-05
                                                                    Chromium[2]
                                    1.8E-03
                                    7.9E-05
                                    2.3E-02
                                    1.4E-03
                                    9.1E-04
                                                                         Cobalt
                                    3.1E-04
                                    3.9E-05
                                    1.7E-03
                                    1.2E-03
                                    2.0E-04
                                                                           Lead
                                    8.6E-03
                                    1.3E-03
                                    1.7E-02
                                    6.5E-02
                                    2.5E-03
                                                                      Manganese
                                    2.4E-03
                                    4.3E-04
                                    4.0E-02
                                    7.9E-04
                                    8.6E-04
                                                                     Mercury[3]
                                    4.2E-05
                                    5.6E-06
                                    7.4E-02
                                    2.7E-03
                                    3.9E-04
                                                                         Nickel
                                    1.3E-03
                                    8.2E-04
                                    2.2E-02
                                    7.4E-03
                                    8.6E-04
                                                                       Selenium
                                    1.2E-03
                                    1.9E-04
                                    8.5E-02
                                    1.3E-02
                                    2.2E-03
HCN
                                    8.2E-03
                                    4.3E-04
                                    2.9E+00
                                    2.3E-02
                                    5.2E-02
Naphthalene
                                    9.9E-04
                                    4.2E-04
                                    6.4E-03
                                    4.4E-05
                                    7.2E-03
PAH (total)
                                    4.2E-04
                                    8.6E-04
                                    6.7E-03
                                    2.3E-04
                                    1.8E-02
VOHAP (total)
                                    5.4E-03
                                    2.8E-04
                                    5.0E+00
                                    5.7E-03
                                    1.2E-01
Total HAP by Process
                                     0.61
                                     0.036
                                      353
                                      34
                                     0.38
Total HAP
                                      389
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)


  Table 19. HAP Emissions by PQBS NESHAP Process (TPY)  -  SC-GraniteCity-IL
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                                   HNR HRSG
                                  Main Stacks
                       HNR HRSG Bypass/waste heat stacks
                                 Quench Tower
Acid Gases (HCl, HF)
                                    3.6E-01
                                    1.9E-02
                                    1.7E+02
                                    2.4E+01
                                    9.0E-02
Dioxin/furans
                                    2.6E-09
                                    1.4E-10
                                    3.0E-07
                                    1.2E-08
                                    2.8E-08
Formaldehyde
                                    3.0E-03
                                    1.6E-04
                                    2.3E+00
                                    1.7E-03
                                    2.7E-03
HAP Metals (total)
                                    2.1E-02
                                    2.4E-03
                                    1.4E-01
                                    1.3E-01
                                    2.1E-02
                                                                       Antimony
                                    6.8E-04
                                    2.5E-05
                                    1.9E-03
                                    3.3E-03
                                    7.3E-04
                                                                        Arsenic
                                    6.2E-03
                                    5.2E-04
                                    3.6E-03
                                    2.3E-02
                                    1.5E-02
                                                                      Beryllium
                                    5.7E-05
                                    6.7E-06
                                    1.5E-04
                                    2.0E-04
                                    5.7E-05
                                                                        Cadmium
                                    5.2E-05
                                    1.3E-05
                                    8.7E-04
                                    1.2E-03
                                    4.5E-05
                                                                    Chromium[2]
                                    1.6E-03
                                    4.9E-05
                                    1.2E-02
                                    1.5E-03
                                    5.7E-04
                                                                         Cobalt
                                    2.7E-04
                                    2.4E-05
                                    8.7E-04
                                    8.9E-04
                                    1.3E-04
                                                                           Lead
                                    8.2E-03
                                    8.4E-04
                                    8.6E-03
                                    7.1E-02
                                    1.6E-03
                                                                      Manganese
                                    2.3E-03
                                    2.7E-04
                                    2.0E-02
                                    1.2E-03
                                    5.4E-04
                                                                     Mercury[3]
                                    4.3E-05
                                    3.5E-06
                                    3.7E-02
                                    2.2E-03
                                    2.4E-04
                                                                         Nickel
                                    9.9E-04
                                    5.1E-04
                                    1.1E-02
                                    5.9E-03
                                    5.4E-04
                                                                       Selenium
                                    1.2E-03
                                    1.2E-04
                                    4.2E-02
                                    1.6E-02
                                    1.4E-03
HCN
                                    5.1E-03
                                    2.7E-04
                                    1.5E+00
                                    2.2E-02
                                    3.3E-02
Naphthalene
                                    6.2E-04
                                    2.7E-04
                                    3.2E-03
                                    4.3E-05
                                    4.5E-03
PAH (total)
                                    2.6E-04
                                    5.4E-04
                                    3.3E-03
                                    2.3E-04
                                    1.1E-02
VOHAP (total)
                                    3.4E-03
                                    1.8E-04
                                    2.5E+00
                                    5.6E-03
                                    7.5E-02
Total HAP by Process
                                     0.39
                                     0.022
                                      177
                                      24
                                     0.24
Total HAP
                                      202
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)


   Table 20. HAP Emissions by Subpart PQBS NESHAP (TPY)  -  SC-Middletown-OH
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                                   HNR HRSG
                                  Main Stacks
                       HNR HRSG Bypass/waste heat stacks
                                 Quench Tower
Acid Gases (HCl, HF)
                                    3.0E-01
                                    1.6E-02
                                    9.1E-03
                                    2.4E+01
                                    7.5E-02
Dioxin/furans
                                    2.2E-09
                                    1.1E-10
                                    1.9E-04
                                    1.0E-08
                                    2.3E-08
Formaldehyde
                                    2.5E-03
                                    1.3E-04
                                    2.3E+00
                                    7.1E-02
                                    2.3E-03
HAP Metals (total)
                                    6.6E-03
                                    2.0E-03
                                    1.2E-01
                                    1.0E-01
                                    1.7E-02
                                                                       Antimony
                                    2.7E-04
                                    2.1E-05
                                    4.1E-03
                                    2.5E-03
                                    6.1E-04
                                                                        Arsenic
                                    2.1E-03
                                    4.3E-04
                                    2.7E-09
                                    2.1E-02
                                    1.2E-02
                                                                      Beryllium
                                    5.6E-05
                                    5.6E-06
                                    5.0E-03
                                    1.8E-04
                                    4.7E-05
                                                                        Cadmium
                                    7.4E-06
                                    1.1E-05
                                    1.2E-04
                                    9.8E-04
                                    3.8E-05
                                                                    Chromium[2]
                                    5.1E-04
                                    4.1E-05
                                    2.8E-02
                                    1.2E-03
                                    4.8E-04
                                                                         Cobalt
                                    1.1E-04
                                    2.0E-05
                                    8.4E-04
                                    8.6E-04
                                    1.1E-04
                                                                           Lead
                                    2.2E-03
                                    7.0E-04
                                    7.9E-04
                                    5.6E-02
                                    1.3E-03
                                                                      Manganese
                                    5.7E-04
                                    2.3E-04
                                    2.0E-02
                                    8.3E-04
                                    4.5E-04
                                                                     Mercury[3]
                                    8.0E-06
                                    2.9E-06
                                    3.6E-02
                                    2.0E-03
                                    2.0E-04
                                                                         Nickel
                                    4.9E-04
                                    4.3E-04
                                    6.2E-03
                                    5.5E-03
                                    4.5E-04
                                                                       Selenium
                                    3.2E-04
                                    1.0E-04
                                    1.9E-02
                                    1.2E-02
                                    1.2E-03
HCN
                                    4.3E-03
                                    2.3E-04
                                    1.9E+01
                                    1.8E-02
                                    2.7E-02
Naphthalene
                                    5.2E-04
                                    2.2E-04
                                    4.6E-06
                                    3.6E-05
                                    3.8E-03
PAH (total)
                                    2.2E-04
                                    4.5E-04
                                    7.8E-02
                                    1.9E-04
                                    9.5E-03
VOHAP (total)
                                    2.8E-03
                                    1.5E-04
                                    2.5E+00
                                    4.7E-03
                                    6.3E-02
Total HAP by Process
                                     0.31
                                     0.019
                                      24
                                      24
                                     0.20
Total HAP
                                      49
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)


    Table 21. HAP Emissions by PQBS NESHAP Process (TPY)  -  SC-Vansant-VA
                                     HAP/
                                 HAP Group[1]
                         PQBS NESHAP HAP Emissions TPY

                                    Pushing
                               Fugitive Pushing
                                  HNR HRSG 
                           Bypass/waste heat stacks
                                 Quench Tower
Acid Gases (HCl, HF)
                                    4.4E-01
                                    3.1E-02
                                    9.6E+02
                                    1.5E-01
Dioxin/furans
                                    3.2E-09
                                    2.3E-10
                                    4.0E-07
                                    4.6E-08
Formaldehyde
                                    3.7E-03
                                    2.6E-04
                                    2.9E+00
                                    4.6E-03
HAP Metals (total)
                                    1.8E-02
                                    3.9E-03
                                    4.1E+00
                                    3.4E-02
                                                                       Antimony
                                    6.3E-04
                                    4.1E-05
                                    9.9E-02
                                    1.2E-03
                                                                        Arsenic
                                    5.4E-03
                                    8.6E-04
                                    8.4E-01
                                    2.5E-02
                                                                      Beryllium
                                    7.8E-05
                                    1.1E-05
                                    7.4E-03
                                    9.4E-05
                                                                        Cadmium
                                    3.8E-05
                                    2.2E-05
                                    3.9E-02
                                    7.5E-05
                                                                    Chromium[2]
                                    1.4E-03
                                    8.2E-05
                                    4.9E-02
                                    9.5E-04
                                                                         Cobalt
                                    2.5E-04
                                    4.0E-05
                                    3.5E-02
                                    2.1E-04
                                                                           Lead
                                    6.8E-03
                                    1.4E-03
                                    2.2E+00
                                    2.6E-03
                                                                      Manganese
                                    1.9E-03
                                    4.5E-04
                                    3.3E-02
                                    8.9E-04
                                                                     Mercury[3]
                                    3.3E-05
                                    5.8E-06
                                    8.0E-02
                                    4.0E-04
                                                                         Nickel
                                    9.9E-04
                                    8.5E-04
                                    2.2E-01
                                    8.9E-04
                                                                       Selenium
                                    9.7E-04
                                    2.0E-04
                                    4.7E-01
                                    2.3E-03
HCN
                                    6.4E-03
                                    4.5E-04
                                    7.4E-01
                                    5.4E-02
Naphthalene
                                    7.7E-04
                                    4.4E-04
                                    1.4E-03
                                    7.5E-03
PAH (total)
                                    3.3E-04
                                    8.9E-04
                                    7.6E-03
                                    1.9E-02
VOHAP (total)
                                    4.2E-03
                                    3.0E-04
                                    1.9E-01
                                    1.2E-01
Total HAP by Process
                                     0.48
                                     0.037
                                      964
                                     0.39
Total HAP
                                      965
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)
                                       
Table 22. HAP Emissions By Facility from HNR HRSG Bypass or Waste Heat Stacks  -  All HNR Facilities
                                     HAP/
                                 HAP Group[1]
 HAP Emissions from HNR HRSG Bypass or Waste Heat Stacks (TPY) in PQBS NESHAP

                              SC-East Chicago-IN
                            SC-Franklin Furnace-OH
                              SC-Granite City-IL
                               SC-Middletown-OH
                                 SC-Vansant-VA
Acid Gases (HCl, HF)
                                      278
                                      34
                                      24
                                      24
                                      956
Dioxin/furans
                                    1.2E-07
                                    1.2E-08
                                    1.2E-08
                                    1.0E-08
                                    4.0E-07
Formaldehyde
                                     0.83
                                     0.17
                                    0.0017
                                     0.071
                                      2.9
HAP Metals (total)
                                      1.2
                                     0.12
                                     0.13
                                     0.10
                                      4.1
                                                                       Antimony
                                     0.029
                                    0.0027
                                    0.0033
                                    0.0025
                                     0.10
                                                                        Arsenic
                                     0.24
                                     0.028
                                     0.023
                                     0.021
                                     0.84
                                                                      Beryllium
                                    0.0021
                                    0.00025
                                    0.00020
                                    0.00018
                                    0.0074
                                                                        Cadmium
                                     0.011
                                    0.0011
                                    0.0012
                                    0.0010
                                     0.039
                                                                    Chromium[2]
                                     0.014
                                    0.0014
                                    0.0015
                                    0.0012
                                     0.049
                                                                         Cobalt
                                     0.010
                                    0.0012
                                    0.00089
                                    0.00086
                                     0.035
                                                                           Lead
                                     0.65
                                     0.065
                                     0.071
                                     0.056
                                      2.2
                                                                      Manganese
                                     0.010
                                    0.00079
                                    0.0012
                                    0.00083
                                     0.033
                                                                     Mercury[3]
                                     0.023
                                    0.0027
                                    0.0022
                                    0.0020
                                     0.080
                                                                         Nickel
                                     0.064
                                    0.0074
                                    0.0059
                                    0.0055
                                     0.22
                                                                       Selenium
                                     0.14
                                     0.013
                                     0.016
                                     0.012
                                     0.47
HCN
                                     0.22
                                     0.023
                                     0.022
                                     0.018
                                     0.74
Naphthalene
                                    0.00042
                                   0.000044
                                   0.000043
                                   0.000036
                                    0.0014
PAH (total)
                                    0.0022
                                    0.00023
                                    0.00023
                                    0.00019
                                    0.0076
VOHAP (total)
                                     0.054
                                    0.0057
                                    0.0056
                                    0.0047
                                     0.19
Total HAP for Bypass/
Waste Heat Stacks
                                      280
                                      34
                                      24
                                      24
                                      964
1 For list of individual HAP in the HAP groups see Appendix Table A-3.
[2] The breakdown of chromium emissions are as follows: 97% chromium III; 3% chromium VI. (EPA, 2016) 
[3] The breakdown of mercury emissions are as follows: 80% divalent PM; 15% divalent vapor; 5% elemental vapor. (EPA, 2020)

                                       
         Table 23. Facility PM Emissions by PQBS NESHAP Process (TPY)
                                   Facility
                              PM Emissions (TPY)
                                       
                                    Pushing
                                     ByP 
                                 Battery Stack
                              HNR HRSG Main Stack
                       HNR HRSG Bypass/Waste Heat Stack
                                 Quench Tower
                                Facility Total
ABC-Tarrant-AL
                                     0.57
                                      26
                                      --
                                      --
                                      4.6
                                      31
CC-Follansbee-WV
                                     0.43
                                      116
                                      --
                                      --
                                      4.9
                                      122
CC-Middletown-OH
                                     0.14
                                      248
                                      --
                                      --
                                      3.5
                                      252
CC-BurnsHarbor-IN
                                      2.1
                                      309
                                      --
                                      --
                                      16
                                      328
CC-Monessen-PA
                                     0.29
                                      3.9
                                      --
                                      --
                                      2.9
                                      7.1
CC-Warren-OH
                                     0.28
                                      74
                                      --
                                      --
                                      3.1
                                      78
BLU-Birmingham-AL
                                     0.38
                                      17
                                      --
                                      --
                                      3.0
                                      21
EES-RiverRouge-MI
                                     0.76
                                      203
                                      --
                                      --
                                      8.5
                                      213
USS-Clairton-PA
                                      2.9
                                      132
                                      --
                                      --
                                      33
                                      168
SC-EastChicago-IN
                                      26
                                      --
                                      10
                                      69
                                      11
                                      117
SC-FranklinFurnace-OH
                                      14
                                      --
                                      33
                                      9.1
                                      5.9
                                      62
SC-GraniteCity-IL
                                      11
                                      --
                                      16
                                      5.3
                                      3.7
                                      37
SC-Middletown-OH
                                      4.7
                                      --
                                      23
                                      5.9
                                      3.1
                                      36
SC-Vansant-VA
                                      11
                                      --
                                       
                                      238
                                      6.2
                                      254
Industry PQBS NESHAP Total
                                      74
                                     1,132
                                      82
                                      327
                                      110
                                     1,725
                                       
                                       
Table 24. Coke Facility Units Providing Test Data for the Coke PQBS NESHAP RTR
                                   Facility
                                     Unit
                                 Type of Coke
                                 Pushing (CD)
CC-Middletown-OH
Pushing Baghouse
Blast furnace
CC-BurnsHarbor-IN
#2 Battery Pushing Baghouse
Blast furnace
CC-Monessen-PA[1]
Pushing Baghouse Stack
Blast furnace
EC-Erie-PA[2]
Coke Side Shed Baghouse (802)
Foundry
SC-GraniteCity-IL
Gateway Flat Push Hot Car
Blast furnace
SC-Middletown-OH
Middletown Flat Push Hot Car
Blast furnace
                               ByP Battery Stack
CC-Middletown-OH
Combustion Stack
Blast furnace
CC-BurnsHarbor-IN
Coke Battery No. 2 Underfire Stack
Blast furnace
CC-Monessen-PA[1]
Battery Combustion Stack #2
Blast furnace
EC-Erie-PA[2]
Battery Combustion Stack (805)
Foundry
USS-Clairton-PA
Battery B Combustion Stack (S012)
Blast furnace
                               HRSG Main Stacks
SC-Middletown-OH
P90-Coke Oven Battery A-C-Main Stack
Blast furnace
CE-EastChicago-IN[4] 
HRSG Main Stack
Blast furnace
                         HRSG Bypass/waste heat stacks
SC-GraniteCity-IL
Coke Oven Battery C - Bypass Vent 5
Blast furnace
SC-FranklinFurnace-OH
Bypass Vent Stack 6
Blast furnace
                                Quench Tower[3]
USS-Clairton-PA
7A Quench Tower (P052) 
Blast furnace
[1] CC-Monessen-PA did not test for two dioxin/furan congeners (2,3,7,8-octachlorodibenzo-p-dioxin and octachlorodibenzofuran) due to an omission in the CAA 114 request instructions. Default emission factors were used instead for this facility. See the Data Memorandum.[2]
2 While Erie Coke data was used to develop foundry emissions for the Coke PQBS NESHAP RTR, because the facility permanently closed after submitting the CAA 114 request, the data for this facility was not modeled for risk purposes.
[3] Despite a conscientious testing effort, the CC-Monessen-PA Quench Tower Stack results were not able to be used. See the Data Memorandum[2] for more explanation.
[4] Located at the SC-EastChicago-IN facility and processing the SunCoke facility's coke oven exhaust.

                                       
             Table 25. Pollutant Control Methods by Coke Processes
                                    Process
                                  PM Control
                                  VOC Control
                                 Work Practice
                               Coke PQBS NESHAP
Pushing
baghouse, scrubbers, multicyclone, shed
--
complete combustion (PM, VOC)
Quenching
baffles
wastewater TDS limit
--
ByP Battery Stacks
opacity limit
--
--
HR HRSG Main
spray dryer/absorber, baghouse
--
--
HR HRSG Bypass
none
none
permit limits on bypass hours
NR Waste Heat
none
none
none
                          Coke Oven Batteries NESHAP
Doors
--
--
maintenance, door jamb seals
Lids
--
--
luting (sealing) agents
Offtakes
--
--
joint seals
Charging  -  ByP
--
--
steam aspiration, staged charging
Charging - HNR
baghouse
--
--

4.0	EPA METHOD 303 DATA

      For the Coke Oven Batteries NESHAP sources (charging, doors, lids, and offtakes), EPA Method 303 data obtained from responses to questions in the 2022 CAA 114 request were used with the benzene-soluble organic (BSO) estimating procedures from AP-42 (EPA, 2001b) to calculate COE from each source. The COETF provided EPA Method 303 data for the facilities not included in the CAA 114 request as part of their review. Relevant documents are included in Coke PQBS NESHAP docket, (EPA-HQ-OAR-2002-0085). Table 26 summarizes the EPA Method 303 charging, door, lids, and offtakes leak data and the Coke Oven Batteries NESHAP limits. Table 27 shows the allowable emissions (tpy) before and after lowering the leak limits from doors, lids, and offtakes for each of nine ByP facilities. Table 28 shows the ratio of allowable-to-actual emissions for leaking doors. Table 29 shows actual COE (TPY) from ByP facility door, lids, and offtake leaks and charging emissions compared to allowable emissions under the Coke Ovens Batteries NESHAP, by facility and total for ByP industry. Table 30 summarizes the average opacity observed for CAA 114 compared to allowable. Appendix D provides battery-specific door leak emissions information. 
Table 26. ByP Facility 2022 EPA Method 303 Performance and COE Emissions Data for the Coke Oven Batteries NESHAP 
                           EPA Method 303 Parameters
2022 CAA 114 Request EPA Method 303 Data by ByP Facility[1] and Process (Actual Emissions)

                                ABC-Tarrant-AL
                               BLU-Birmingham-AL
                               CC-Follansbee-WV
                               CC-Middletown-OH
                               CC-BurnsHarbor-IN
                                CC-Monessen-PA
                                 CC-Warren-OH
                               EES-RiverRouge-MI
                                USS-Clairton-PA
                              Regulatory Track[1]
                                     LAER
                                     LAER
                                     LAER
                                     MACT
                                     LAER
                                     LAER
                                     LAER
                                     LAER
                                     LAER
                                 No. Batteries
                                       3
                                       3
                                       4
                                       1
                                       2
                                       2
                                       1
                                       1
                                      10
                                   No. Ovens
                                      132
                                      120
                                      224
                                      76
                                      164
                                      56
                                      85
                                      85
                                      708
                                   Charging
                              Seconds per Charge
Limit
                                      12
                                      12
                                      12
                                      12
                                      12
                                      12
                                      12
                                      12
                                      12

Facility Average
                                      4.7
                                      4.0
                                      6.6
                                      5.8
                                      8.4
                                      4.4
                                      4.5
                                      1.8
                                      2.4
                        Facility Average as % of Limit
                                      39%
                                      34%
                                      55%
                                      49%
                                      70%
                                      36%
                                      38%
                                      15%
                                      20%
                              COE Emissions (TPY)
                                     0.070
                                     0.056
                                     0.068
                                     0.089
                                     0.29
                                     0.056
                                     0.074
                                     0.035
                                     0.29
                                     Doors
                                Percent Leaking
                                     Limit
                                     4.0%
                                     4.0%
                                 3.3%/4.0%[3]
                                     3.3%
                                     4.0%
                                     3.3%
                                     3.3%
                                     4.0%
                                  3.3/4.0%[4]

                                 Door Type[2]
                                    foundry
                                    foundry
                               all other/tall[3]
                                   all other
                                     tall
                                   all other
                                   all other
                                     tall
                               all other/tall[4]

Facility Average
                                     0.85%
                                     1.4%
                                     0.44%
                                     1.7%
                                     1.8%
                                     0.11%
                                     1.2%
                                     0.12%
                                     0.46%
                        Facility Average as % of Limit
                                      21%
                                      36%
                                  13%/11%[3]
                                      52%
                                      46%
                                     3.4%
                                      36%
                                     2.9%
                                  14%/11%[4]
                              COE Emissions (TPY)
                              Original Equation 
                                      2.3
                                      2.0
                                      3.2
                                      1.4
                                      3.0
                                     0.70
                                      1.4
                                      1.1
                                      9.7
                              COE Emissions (TPY)
                             Alternative Equation
                                      1.0
                                     0.87
                                     0.71
                                     0.70
                                      1.6
                                     0.031
                                     0.54
                                     0.053
                                      1.7
                                     Lids
                                Percent Leaking
                                     Limit
                                     0.4%
                                     0.4%
                                     0.4%
                                     0.4%
                                     0.4%
                                     0.4%
                                     0.4%
                                     0.4%
                                     0.4%

                               Facility Average
                                    0.014%
                                    0.087%
                                    0.0023%
                                    0.053%
                                    0.075%
                                     0.0%
                                    0.084%
                                    0.013%
                                    0.0054%
                        Facility Average as % of Limit
                                     3.5%
                                      22%
                                     0.57%
                                     1.3%
                                      19%
                                     0.0%
                                      21%
                                     3.3%
                                     1.4%
                              COE Emissions (TPY)
                                    0.0032
                                     0.016
                                    0.00095
                                    0.00040
                                     0.019
                                       0
                                    0.0070
                                    0.0015
                                    0.0057
                                   Offtakes
                                Percent Leaking
                                     Limit
                                     2.5%
                                     2.5%
                                     2.5%
                                     2.5%
                                     2.5%
                                     2.5%
                                     2.5%
                                     2.5%
                                     2.5%

Facility Average
                                    0.0061%
                                     0.69%
                                     0.25%
                                    0.014%
                                     0.36%
                                    0.023%
                                     1.3%
                                    0.068%
                                     0.42%
                        Facility Average as % of Limit
                                     0.25%
                                      27%
                                     9.9%
                                     0.56%
                                      14%
                                     0.91%
                                      52%
                                     2.7%
                                      17%
                              COE Emissions (TPY)
                                    0.00020
                                     0.028
                                     0.049
                                    0.00069
                                     0.019
                                    0.00084
                                     0.072
                                    0.0038
                                     0.19
[1]All facilities except CC Middletown-OH are subject to the LAER 1/1/2010 limits. CC Middletown-OH is subject to the MACT Track RTR 7/2005 limits. 
[2]Tall doors are doors greater than 6 meters (20 ft) in height. "All other" doors are either not tall or not at a foundry coke facility. HNR facilities are not permitted to have any leaking doors and do not have lids or offtakes.
[3] Three of four batteries at CC Follansbee WV are "all other" with door limits of 3.3% and the fourth battery is "tall" with door limit of 4.0%. Data presented for both.
[4] Eight of the 10 batteries at USS Clairton PA are "all other" with door limits of 3.3% and two batteries are "tall" with door limits of 4.0%. Data presented for both.

                                       
Table 27. Estimated Allowable Emissions Before and After Proposed Changes to the 
                    Coke Oven Batteries NESHAP Limits for 
         Leaking Doors, Lids, and Offtakes at ByP Coke Oven Facilities
                                  Facility ID
                           Allowable Emissions (TPY)
                                       
                           With Current Leak Limits
                           With Proposed Leak Limits
                                       
                                  Doors[a,b]
                                     Lids
                                   Offtakes
                                     Total
                                   Doors[c]
                                     Lids
                                   Offtakes
                                     Total
ABC-Tarrant-AL
3.4
0.076
0.11
3.6
3.0
0.038
0.052
3.1
BLU-Birmingham-AL
3.1
0.079
0.099
3.3
2.7
0.039
0.047
2.8
CC-Follansbee-WV
5.5
0.12
0.25
5.9
5.1
0.059
0.12
5.2
CC-Middletown-OH
1.8
0.030
0.12
2.0
1.7
0.015
0.060
1.8
CC-BurnsHarbor-IN
4.3
0.086
0.13
4.5
3.7
0.043
0.065
3.8
CC-Monessen-PA
1.3
0.029
0.092
1.4
1.3
0.015
0.044
1.3
CC-Warren-OH
2.0
0.034
0.14
2.2
1.9
0.017
0.067
2.0
EES-RiverRouge-MI
2.2
0.045
0.14
2.4
1.9
0.022
0.067
2.0
USS-Clairton-PA
17
0.38
1.1
19
11
0.19
0.53
12
Total
41
0.88
2.2
44
33
0.44
1.0
34
[a] Door emissions are calculated using the alternate equation.
[b] For doors, two limits apply in the current rule: 4 percent leaking doors for tall ovens (equal to or greater than 6 meters or 29 feet) and 3.3 percent leaking doors for all other shorter ovens (less than 6 meters). c For facilities with coke production capacity more than 3 million tpy coke, proposed limits from doors are 1.5 percent leaking doors for tall ovens and 1.0 percent leaking doors for all other shorter ovens; for facilities with coke production capacity less than 3 million tpy coke, proposed limits from doors is 3.0 percent leaking doors for all doors sizes.
                                       
                                       
      Table 28. Allowable-to-Actual (CAA 114) Ratios for ByP Door Leaks 
          in the Coke Oven Batteries NESHAP  -  Alternative Equation
                                   Facility
                                  Battery ID
             Ratio Allowable-to-Actual (CAA 114) for Leaking Doors
ABC-Tarrant-AL
Battery #1 
                                      1.6

Battery #5 
                                      61

Battery #6 
                                      99
CC-Follansbee-WV
Battery #1,2,3
                                      41

Battery #8
                                      2.6
CC-Middletown-OH
B918 
                                      1.9
CC-BurnsHarbor-IN
EU512-05 #1
                                      1.5

EU512-13 #2
                                      3.7
CC-Monessen-PA
Battery (1B)
                                      39

Battery (2)
                                      24
CC-Warren-OH
No. 4 battery
                                      2.8
BLU-Birmingham-AL
Battery no. 3 & 4
                                      2.5

Battery no. 5 
                                      3.7
EES-RiverRouge-MI
Battery #5 
                                      35
USS-Clairton-PA
Battery 1 
                                      3.8

Battery 2 
                                      3.9

Battery 3 
                                      7.1

Battery 13 
                                      18

Battery 14
                                      15

Battery 15 
                                      8.5

Battery 19 
                                      11

Battery 20
                                      11

Battery B
                                      7.4

Battery C
                                      8.0

Table 29. Actual COE (TPY) from ByP Leaks and Charging Compared to Allowable Limits 
                       in the Coke Oven Batteries NESHAP
                              COE Emission Source
                                    COE TPY
                                       
                                ABC-Tarrant-AL
                               BLU-Birmingham-AL
                               CC-Follansbee-WV
                               CC-Middletown-OH
                               CC-BurnsHarbor-IN
                                CC-Monessen-PA
                                 CC-Warren-OH
                               EES-RiverRouge-MI
                                USS-Clairton-PA
                                 Total COE TPY
                               Actual Emissions
Charging
                                     0.07
                                     0.056
                                     0.068
                                     0.089
                                     0.29
                                     0.056
                                     0.074
                                     0.035
                                     0.29
                                      1.0
Doors
                                                                    Original[1]
                                      2.3
                                       2
                                      3.2
                                      1.4
                                       3
                                      0.7
                                      1.4
                                      1.1
                                      9.7
                                      25
                                                                   Alternate[2]
                                      1.0
                                     0.87
                                     0.71
                                      0.7
                                      1.6
                                     0.031
                                     0.54
                                     0.053
                                      1.7
                                      7.2
Lids
                                    0.0032
                                     0.016
                                    0.00095
                                    0.0004
                                     0.019
                                       0
                                     0.007
                                    0.0015
                                    0.0057
                                      0.1
Offtakes
                                    0.0002
                                     0.028
                                     0.049
                                    0.00069
                                     0.019
                                    0.00084
                                     0.072
                                    0.0038
                                     0.19
                                      0.4
Totals
                                                                    Original[1]
                                      2.4
                                      2.1
                                      3.3
                                      1.5
                                      3.3
                                      0.8
                                      1.6
                                      1.1
                                     10.2
                                      26
                                                                   Alternate[2]
                                      1.1
                                      1.0
                                      0.8
                                      0.8
                                      1.9
                                      0.1
                                      0.7
                                      0.1
                                      2.2
                                      8.6
                            Allowable Emissions[2]
Before Proposal
                                      3.6
                                      3.3
                                      5.9
                                      2.0
                                      4.5
                                      1.4
                                      2.2
                                      2.4
                                     19.0
                                      44
After Proposal
                                      3.1
                                      2.8
                                      5.2
                                      1.8
                                      3.8
                                      1.3
                                      2.0
                                      2.0
                                     12.0
                                      34
[1] Using original door leak equation.
[2] Using alternate door leak equation.






5.0	OPACITY DATA
      
      The pushing, battery combustion, boiler, HRSG Main, HRSG bypass/waste heat, and HNR charging stacks and quench towers were required to conduct opacity observations for the 2016 and 2022 CAA 114 request. Table 30 summarizes the average opacity observations for those sources.
      
      Table 30. Opacity Data for Pushing and Battery Combustion Stacks from the CAA 114
                                  Facility ID
                                    Unit ID
                                  Test Method
                               Average Opacity %
                                 Opacity Limit
                                  PQBS NESHAP
                                       %
                        ByP Battery Combustion Stack[1]
                                       
CC-Middletown-OH
Battery Combustion Stack
COMs
                                      7.4
                                  15% normal
                              20% extended coking
USS-Clairton-PA
Battery B Stack (S012)
COMs
                                     <1
                                       
CC-Burnsharbor-IN
Coke Battery No. 2 Underfire Stack
COMs
                                      3.7
                                       
CC-Monessen-PA
Battery Combustion Stack #2
EPA Method 9
                                     <1
                                       
EC-Erie-PA
Battery Combustion Stack (805)
EPA Method 9
                                      3.6
                                       
                            ByP and HNR Pushing[2] 
                                       
CC-Middletown-OH
Pushing Baghouse
EPA Method 9
                                      4.8
                                  30% short 
                                      35%
                                     tall
CC-Burnsharbor-IN
#2 Battery Pushing Baghouse
EPA Method 9
                                     <1
                                       
CC-Monessen-PA
Pushing Baghouse Stack
EPA Method 9
                                       0
                                       
EC-Erie-PA
Coke-Side Shed Baghouse 802
EPA Method 9
                                       0
                                       
SC-Middletown-OH
Flat Push Hot Car
EPA Method 9
                                      4.2
                                       
                                 Boiler Stack
                                       
CC-Monessen-PA
Tampella Boilers / 032
EPA Method 9
                                     <1
                                      NA
EC-Erie-PA
Boiler #1 Stack
EPA Method 9
                                       0
                                       
                                HRSG Main Stack
                                       
SC-Middletown-OH
P901- Coke Oven (Battery A-C) 
EPA Method 9
                                       0
                                      NA
CE-IndianaHarbor-IN[4]
HNR Main Stack 
COMs
                                    2.9[3]
                                       
                         HRSG Bypass/Waste Heat Stack
                                       
SC-GraniteCity-IL
Coke Oven Battery C - Bypass Vent 5
EPA Method 9
                                       0
                                      NA
SC-FranklinFurnace-OH
Bypass Vent Stack #6
EPA Method 9
                                      5.6
                                       
                                 HNR Charging 
                                       
SC-Middletown-OH
Pushing/Charging Machine (PCM)
EPA Method 9
                                      2.0
                                      20
                                 Quench Tower 
                                       
CC-Monessen-PA
Quench Tower
EPA Method 9
                                     <1
                                      NA
[1] Of the 19 operating ByP batteries at six facilities, 11 batteries are operating under normal coking and 8 batteries are operating under extended coking. Current battery stack opacity limits are: daily average of 15 percent opacity for a battery on a normal coking cycle and daily average of 20 percent opacity for a battery on battery-wide extended coking.
[2] Of the 19 operating ByP batteries at six facilities, 5 batteries are short and 14 batteries are tall. Current ByP coke oven battery with vertical flues are: average opacity for any individual push is 30 percent opacity for any short battery or 35 percent opacity for any tall battery.
[3] Opacity values were reported as maximum %, as 6-minute average.
[4] Located at the SC-EastChicago-IN facility and processing the SunCoke facility's coke oven exhaust.
6.0	REFERENCES

EPA, 2001a. National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery Stacks  -  Background Information for Proposed Standards. EPA-453/R01-006. U.S. Environmental Protection Agency, Research Triangle Park, North Carolina. Docket ID No. EPA-HQ-OAR-2002-0085-0170. February 2001.
EPA, 2001b. Emission Factor Documentation for AP-42, Section 12.2: Coke Production. Revised Draft Version, U.S. Environmental Protection Agency, Research Triangle Park, North Carolina. Updated July 2001.
EPA, 2016. U.S. Environmental Protection Agency. Chromium Speciation Database [Microsoft Access database]. A. Pope. U.S. Environmental Protection Agency, Research Triangle Park, North Carolina. Docket ID No. EPA-HQ-OAR-2002-0085. January 5, 2016.
EPA, 2020. U.S. Environmental Protection Agency. Godfrey, J, E. Goehl, M. Strum, and A. Diem. Development of Mercury Speciation Factors for EPA's Air Emissions Modeling Programs, Technical Support Document Version 1. U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Research Triangle Park, NC. Docket ID No. EPA-HQ-OAR-2002-0085. April 2020.
EPA, 2023. U.S. Environmental Protection Agency. Coke Ovens Risk and Technology Review: Data Summary. Jones, D.L., U.S. Environmental Protection Agency, Research Triangle Park, NC, and G. Raymond, RTI International, Research Triangle Park, NC. U.S. Environmental Protection Agency, Research Triangle Park, NC . May 1, 2023.


                                       
                                  APPENDIX A
                                 Abbreviations

                    Table A-1. Facility Name Abbreviations
                                 Abbreviation
                                   Full Name
ABC-Tarrant-AL
ABC Coke, Tarrant, AL
BLU-Birmingham-AL
Bluestone Coke, Birmingham, AL
CC-Follansbee-WV
Cleveland Cliffs Follansbee Works, Follansbee, WV
CC-Middletown-OH
Cleveland Cliffs Middletown Works, Middletown, OH
CC-BurnsHarbor-IN
Cleveland Cliffs Burns Harbor, Burns Harbor, IN
CC-Monessen-PA
Cleveland Cliffs Monessen, Monessen, PA
CC-Warren-OH
Cleveland Cliffs Warren, Warren, OH
EC-Erie-PA
Erie Coke Corporation, Erie PA
EES-RiverRouge-MI
EES Coke Battery, River Rouge, MI
SC-EastChicago-IN
SunCoke Indiana Harbor Coke, East Chicago, IN
SC-FranklinFurnace-OH
SunCoke Haverhill Coke, Franklin Furnace, OH
SC-GraniteCity-IL
SunCoke Gateway Energy and Coke, Granite City, IL
SC-Middletown-OH
SunCoke Middletown Coke Company, Middletown, OH
SC-Vansant-VA
SunCoke Jewell Coke and Coal, Vansant, VA
USS-Clairton-PA
U.S. Steel Clairton, Clairton, PA
Note: In 2020, Cleveland-Cliffs, Inc., acquired many II&S and cokemaking facilities. This table lists the short names used in the memorandum along with their full names and current ownership, if different.



                        Table A-2. Other Abbreviations
                                 Abbreviation
                                   Full Term
BF
blast furnace
ByP
ByP chemical recovery coke process
CAA
Clean Air Act
CD
control device
COE
coke oven emissions
CU
capacity utilization
HAP
hazardous air pollutant
HCl
hydrogen chloride
HCN
hydrogen cyanide 
HF
hydrogen fluoride
HNR
heat and/or nonrecovery
II&S
integrated iron and steel
lb/ton
pound per ton 
MDL
method detection limit
NESHAP
national emission standards for hazardous air pollutants 
No.
number
NR
nonrecovery
PAH
polycyclic aromatic hydrocarbons
PM
particulate matter
PQBS
pushing, quenching, and battery stacks 
RTR
residual risk and technology review 
TDS
total dissolved solids
tpy
tons per year
U.S.
United States
VOC
volatile organic compound

                                       
                  Table A-3. Individual HAP within HAP Groups
                                   HAP Group
                                Individual HAP
HAP metals
antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, and selenium.
Speciated volatile organic HAP
formaldehyde, acrylonitrile, benzene, bromoform, bromomethane, carbon disulfide, carbon tetrachloride, chlorobenzene, chloroethane, chloroform, chloromethane, 1,2-dichloroethane, 1,1-dichloroethene, 1,2-dichloropropane, ethylbenzene, iodomethane, methylene chloride, styrene, 1,1,2,2-tetrachloroethane, tetrachloroethene, toluene, 1,1,1-trichloroethane, 1,1,2-trichloroethane, trichloroethene, vinyl chloride, and xylenes
PAH
acenaphthene, acenaphthylene, anthracene, benz[a]anthracene, benzo[a]pyrene, benzo[b]fluoranthene, benzo[g,h,i]perylene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, fluoranthene, fluorene, indeno (1,2,3-cd) pyrene, naphthalene, phenanthrene, perylene, pyrene
Dioxin/furans
2,3,7,8-tetrachlorodibenzo-p-dioxin, 1,2,3,7,8-pentachlorodibenzo-p-dioxin, 1,2,3,4,7,8-hexachlorodibenzo-p-dioxin, 1,2,3,6,7,8-hexachlorodibenzo-p-dioxin, 1,2,3,7,8,9-hexachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8-heptachlorodibenzo-p-dioxin, 
octachlorodibenzo-p-dioxin, 2,3,7,8-tetrachlorodibenzofuran, 1,2,3,7,8-pentachlorodibenzofuran, 2,3,4,7,8-pentachlorodibenzofuran, 1,2,3,4,7,8-hexachlorodibenzofuran, 1,2,3,6,7,8-hexachlorodibenzofuran, 2,3,4,6,7,8-hexachlorodibenzofuran, 1,2,3,7,8,9-hexachlorodibenzofuran, 1,2,3,4,6,7,8-heptachlorodibenzofuran, 1,2,3,4,7,8,9-heptachlorodibenzofuran, 
octachlorodibenzofuran
                                       
                                       
                                  APPENDIX B
  Process Units, Annual Production, and Door Leak COE with Original Equation 
                                          
                                          
      
                                          
      Table B-1. Number of PQBS NESHAP Emission Units by Facility and Total Industry
                                   Facility
                     Number of PQBS NESHAP Emission Units
                                       
                                   Batteries
                                     Ovens
                                      ByP
                                Battery Stacks
                                 Quench Towers
                                   H&NR
                                     HRSG
                                     Units
                                   H&NR
                                     HRSG
                                  Main Stacks
                                      HNR
                           Bypass/ Waste Heat Stacks
ABC-Tarrant-AL
                                       3
                                      132
                                       2
                                       2
                                      --
                                      --
                                      --
BLU-Birmingham-AL
                                       3
                                      120
                                       2
                                       2
                                      --
                                      --
                                      --
CC-Follansbee-WV
                                       4
                                      224
                                       4
                                       3
                                      --
                                      --
                                      --
CC-Middletown-OH
                                       1
                                      76
                                       1
                                       1
                                      --
                                      --
                                      --
CC-BurnsHarbor-IN
                                       2
                                      164
                                       2
                                       2
                                      --
                                      --
                                      --
CC-Monessen-PA
                                       2
                                      56
                                       2
                                       1
                                      --
                                      --
                                      --
CC-Warren-OH
                                       1
                                      85
                                       1
                                       1
                                      --
                                      --
                                      --
EES-RiverRouge-MI
                                       1
                                      85
                                       1
                                       1
                                      --
                                      --
                                      --
SC-EastChicago-IN
                                       4
                                      268
                                      --
                                       2
                                      16
                                       1
                                      16
SC-FranklinFurnace-OH
                                       4
                                      200
                                      --
                                       2
                                      12
                                       2
                                      10
SC-GraniteCity-IL
                                       3
                                      120
                                      --
                                       1
                                       7
                                       1
                                       6
SC-Middletown-OH
                                       3
                                      100
                                      --
                                       1
                                       5
                                       1
                                       5
SC-Vansant-VA
                                       6
                                      143
                                      --
                                       2
                                       0
                                       0
                                      16
USS-Clairton-PA
                                      10
                                      708
                                      10
                                       7
                                      --
                                      --
                                      --
Total Industry 
PQBS NESHAP Units
                                      47
                                     2,480
                                      25
                                      28
                                      40
                                       5
                                      53
                                          
                                          
                                          
      Table B-2. Number of Noncategory Emission Units by Facility for Risk Modeling
                                   Facility
                     Number of Noncategory Emission Units
                                       
                                   Batteries
                                     Ovens
                                   ByP Doors
                                    ByP Lids
                                  ByP Offtakes
                                    Boilers
                                    Flares
                                      ByP
                            Chemical Recovery Plant
                                     Other
                                  Misc. Units
                                II&S Plants
ABC-Tarrant-AL
                                       3
                                      132
                                      264
                                      582
                                      132
                                       3
                                       1
                                       1
                                      --
                                      --
BLU-Birmingham-AL
                                       3
                                      120
                                      240
                                      600
                                      120
                                       3
                                       1
                                       1
                                      --
                                      --
CC-Follansbee-WV
                                       4
                                      224
                                      448
                                      896
                                      303
                                       5
                                       1
                                       1
                                       1
                                      --
CC-Middletown-OH
                                       1
                                      76
                                      152
                                      228
                                      152
                                       4
                                       1
                                       1
                                      20
                                       1
CC-BurnsHarbor-IN
                                       2
                                      164
                                      328
                                      656
                                      164
                                       6
                                       1
                                       1
                                      12
                                       1
CC-Monessen-PA
                                       2
                                      56
                                      112
                                      224
                                      112
                                       2
                                       1
                                       1
                                      --
                                      --
CC-Warren-OH
                                       1
                                      85
                                      170
                                      255
                                      170
                                       3
                                       1
                                       1
                                       2
                                      --
EES-RiverRouge-MI
                                       1
                                      85
                                      170
                                      340
                                      170
                                      --
                                       1
                                       1
                                      --
                                      --
SC-EastChicago-IN
                                       4
                                      268
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                       1
                                       1
SC-FranklinFurnace-OH
                                       4
                                      200
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                       2
                                      --
SC-GraniteCity-IL
                                       3
                                      120
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                       1
                                      --
SC-Middletown-OH
                                       3
                                      100
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
SC-Vansant-VA
                                       6
                                      143
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                       2
                                      --
USS-Clairton-PA
                                      10
                                      708
                                     1,416
                                     2,916
                                     1,332
                                       6
                                      --
                                       1
                                       1
                                      --
Total Noncategory Units
                                      47
                                     2,480
                                     3,300
                                     6,697
                                     2,655
                                      32
                                       8
                                       9
                                      42
                                       3
                                          
   Table B-3. Unit Counts by Oven and Battery for Coke Oven Batteries NESHAP
                                   Facility
                                 Battery Name
                             No. Ovens Per Battery
                                 Type of Coke
                              No. Units Per Oven
                             No. Units Per Battery




                                     Lids
                                   Offtakes
                                     Doors
                                     Lids
                                   Offtakes
ABC-Tarrant-AL
Coke Battery #1
                                      78
                                    foundry
                                       4
                                       1
                                      156
                                      312
                                      78
ABC-Tarrant-AL
Coke Battery #5
                                      25
                                    foundry
                                       5
                                       1
                                      50
                                      125
                                      25
ABC-Tarrant-AL
Coke Battery #6
                                      29
                                    foundry
                                       5
                                       1
                                      58
                                      145
                                      29
CC-Follansbee-WV
No. 1 Battery
                                      47
                                      BF
                                       4
                                       1
                                      94
                                      188
                                      47
CC-Follansbee-WV
No. 2 Battery
                                      47
                                      BF
                                       4
                                       1
                                      94
                                      188
                                      47
CC-Follansbee-WV
No. 3 Battery
                                      51
                                      BF
                                       4
                                       1
                                      102
                                      204
                                      51
CC-Follansbee-WV
No. 8 Battery
                                      79
                                      BF
                                       4
                                       2
                                      158
                                      316
                                      158
CC-Middletown-OH
Coke Oven Battery
                                      76
                                      BF
                                       3
                                       2
                                      152
                                      228
                                      152
CC-BurnsHarbor-IN
Battery #1
                                      82
                                      BF
                                       4
                                       1
                                      164
                                      328
                                      82
CC-BurnsHarbor-IN
Battery #2
                                      82
                                      BF
                                       4
                                       1
                                      164
                                      328
                                      82
CC-Monessen-PA
Battery 1B
                                      37
                                      BF
                                       4
                                       2
                                      74
                                      148
                                      74
CC-Monessen-PA
Battery 2
                                      19
                                      BF
                                       4
                                       2
                                      38
                                      76
                                      38
CC-Warren-OH
No. 4 Battery
                                      85
                                      BF
                                       3
                                       2
                                      170
                                      255
                                      170
BLU-Birmingham-AL
Coke Battery No. 3
                                      30
                                    foundry
                                       5
                                       1
                                      60
                                      150
                                      30
BLU-Birmingham-AL
Coke Battery No. 4
                                      30
                                    foundry
                                       5
                                       1
                                      60
                                      150
                                      30
BLU-Birmingham-AL
Coke Battery No. 5
                                      60
                                    foundry
                                       5
                                       1
                                      120
                                      300
                                      60
EES-RiverRouge-MI
Coke Battery #5
                                      85
                                      BF
                                       4
                                       2
                                      170
                                      340
                                      170
USS-Clairton-PA
Battery 1
                                      64
                                      BF
                                       4
                                       2
                                      128
                                      256
                                      128
USS-Clairton-PA
Battery 2
                                      64
                                      BF
                                       4
                                       2
                                      128
                                      256
                                      128
USS-Clairton-PA
Battery 3
                                      64
                                      BF
                                       4
                                       2
                                      128
                                      256
                                      128
USS-Clairton-PA
Battery 13
                                      61
                                      BF
                                       4
                                       2
                                      122
                                      244
                                      122
USS-Clairton-PA
Battery 14
                                      61
                                      BF
                                       4
                                       2
                                      122
                                      244
                                      122
USS-Clairton-PA
Battery 15
                                      61
                                      BF
                                       4
                                       2
                                      122
                                      244
                                      122
USS-Clairton-PA
Battery 19
                                      87
                                      BF
                                       4
                                       2
                                      174
                                      348
                                      174
USS-Clairton-PA
Battery 20
                                      87
                                      BF
                                       4
                                       2
                                      174
                                      348
                                      174
USS-Clairton-PA
B Battery
                                      75
                                      BF
                                       4
                                       2
                                      150
                                      300
                                      150
USS-Clairton-PA
C Battery
                                      84
                                      BF
                                       5
                                       1
                                      168
                                      420
                                      84
                                          
      Table B-4. Annual Coke Production Values by Battery for Coke Oven Facilities
                                   Facility
                                 Battery Name
                 Coke Production Value Used for "Actuals" TPY
ABC-Tarrant-AL
Coke Battery #1
                                  377,606[1]
ABC-Tarrant-AL
Coke Battery #5
                                   68,555[1]
ABC-Tarrant-AL
Coke Battery #6
                                   79,524[1]
CC-Follansbee-WV
No. 1 Battery
                                   36,264[1]
CC-Follansbee-WV
No. 2 Battery
                                   36,264[1]
CC-Follansbee-WV
No. 3 Battery
                                   36,264[1]
CC-Follansbee-WV
No. 8 Battery
                                  453,069[2]
CC-Middletown-OH
Coke Oven Battery
                                  401,752[2]
CC-BurnsHarbor-IN
Battery #1
                                  932,178[2]
CC-BurnsHarbor-IN
Battery #2
                                  955,975[2]
CC-Monessen-PA
Battery 1B
                                  222,015[2]
CC-Monessen-PA
Battery 2
                                CAA 114,007[2]
CC-Warren-OH
No. 4 Battery
                                  359,281[2]
BLU-Birmingham-AL
Coke Battery No. 3
                                  105,038[1]
BLU-Birmingham-AL
Coke Battery No. 4
                                   98,007[1]
BLU-Birmingham-AL
Coke Battery No. 5
                                  145,668[1]
EC-Erie-PA
Battery A
                                   48,533[2]
EC-Erie-PA
Battery B
                                   73,854[2]
EES-RiverRouge-MI
Coke Battery #5
                                  981,765[2]
SC-EastChicago-IN
Battery A
                                  325,000[3]
SC-EastChicago-IN
Battery B
                                  325,000[3]
SC-EastChicago-IN
Battery C
                                  325,000[3]
SC-EastChicago-IN
Battery D
                                  325,000[3]
SC-FranklinFurnace-OH
A Battery
                                  204,994[4]
SC-FranklinFurnace-OH
B Battery
                                  136,663[4]
SC-FranklinFurnace-OH
C Battery
                                  204,994[4]
SC-FranklinFurnace-OH
D Battery
                                  136,663[4]
SC-GraniteCity-IL
Battery A
                                  142,804[4]
SC-GraniteCity-IL
Battery B
                                  142,804[4]
SC-GraniteCity-IL
Battery C
                                  142,804[4]
SC-Middletown-OH
A Battery
                                  142,804[4]
SC-Middletown-OH
B Battery
                                   71,402[4]
SC-Middletown-OH
C Battery
                                  142,804[4]
SC-Vasant-VA
Battery 2D
                                   90,000[3]
SC-Vasant-VA
Battery 2E
                                  135,000[3]
SC-Vasant-VA
Battery 3B
                                  130,000[3]
SC-Vasant-VA
Battery 3C
                                  180,000[3]
SC-Vasant-VA
Battery 3F
                                   85,000[3]
SC-Vasant-VA
Battery 3G
                                   90,000[3]
USS-Clairton-PA
Battery 1
                                  217,224[2]
USS-Clairton-PA
Battery 2
                                  217,224[2]
USS-Clairton-PA
Battery 3
                                  217,224[2]
USS-Clairton-PA
Battery 13
                                  225,724[2]
USS-Clairton-PA
Battery 14
                                  225,724[2]
USS-Clairton-PA
Battery 15
                                  225,724[2]
USS-Clairton-PA
Battery 19
                                  424,307[2]
USS-Clairton-PA
Battery 20
                                  424,307[2]
USS-Clairton-PA
B Battery
                                  718,216[2]
USS-Clairton-PA
C Battery
                                  880,570[2]
[1] Value reported by industry (Coke Oven Task Force (COETF) of the American Coke and Coal Chemicals Institute (ACCCI)). 
[2] Value reported by the facility in CAA 114 request (Enclosure 1, Q29.b-pt.8). Total production for year 2015 (tpy).
[3] 1998 coke production values from the NESHAP for Coke Ovens: Pushing, Quenching, and Battery Stacks  -  Background Information for Proposed Standards, February 2001, EPA-453/R01-006 (EPA, 2001a).
[4] Typical operation using CAA 114 request (Enclosure 1, Q28.i). Coke production design capacity multiplied by average CU (55%).


                                       
                                       
                                  APPENDIX C
            Facility and Industry-wide Process and Total Emissions 
                Including Door Leak COE with Original Equation
                                       
Table C-1. Coke Oven Facility Emissions, Including Door Leak COE with Original Equation (TPY)
                          Facility Name-City-State[1]
                              Facility Type2 and 
                                  Coke Type 
                              Coke Capacity (TPY)
                       HAP Emissions (TPY) - Actuals[3]



                           Source Category CCCCC[4]
                               Non-category[5,6]
                               Total Facility[7]
ABC-Tarrant-AL
ByP-foundry coke
                                    699,967
                                      9.3
                                      14
                                      23
CC-Follansbee-WV
ByP-blast furnace coke
                                   1,346,000
                                      11
                                      10
                                      21
CC-Middletown-OH
ByP-blast furnace coke
                                    456,000
                                      20
                                      10
                                      30
CC-BurnsHarbor-IN
ByP-blast furnace coke
                                   1,900,000
                                      26
                                      89
                                      116
CC-Monessen-PA
ByP-blast furnace coke
                                    372,581
                                      2.5
                                      5.1
                                      7.6
CC-Warren-OH
ByP-blast furnace coke
                                    549,000
                                      7.2
                                      8.0
                                      15
BLU-Birmingham-AL
ByP-foundry coke
                                    596,775
                                      6.3
                                      11
                                      17
EES-RiverRouge-MI
ByP-blast furnace coke
                                   1,050,000
                                      20
                                      5.4
                                      25
USS-Clairton-PA
ByP-blast furnace coke
                                   6,422,997
                                      37
                                      37
                                      74
SC-EastChicago-IN
HNR-blast furnace coke
                                   1,300,000
                                      524
                                    0.0067
                                      524
SC-FranklinFurnace-OH
HNR-blast furnace coke
                                   1,100,000
                                      389
                                     0.66
                                      389
SC-GraniteCity-IL
HNR-blast furnace coke
                                    650,000
                                      202
                                     0.36
                                      202
SC-Middletown-OH
HNR-blast furnace coke
                                    550,000
                                      49
                                    0.0028
                                      49
SC-Vansant-VA
HNR-blast furnace coke
                                    745,000
                                      965
                                      11
                                      976
Total
 
 
                                     2,267
                                      201
                                     2,468
[1] CC = Cleveland Cliffs. BLU = Bluestone. SC = SunCoke. USS = U.S. Steel.
[2] ByP = ByP; HNR = heat and/or nonrecovery.	
[3] HAP emissions have been adjusted for nondetected values.
[4] Includes category emissions from ByP pushing, ByP combustion (battery) stack, HNR operations (HNR pushing, HRSG main stack, HRSG bypass/waste heat stack), quench towers and fugitive pushing.
[5] Includes noncategory emissions from Coke Oven Batteries NESHAP sources (charging, doors (using original equation), lids, offtakes, charging), boilers, flares, 40 CFR part 61 subpart L NESHAP ByP chemical plant, co-located II&S facilities, and other operations. 
[6] Co-located II&S (noncategory) emissions: CC-Middletown-OH = 1.4 TPY; CC-BurnsHarbor-IN = 78 TPY (with sinter plant).
[7] 931 tpy emissions from HCl (out of 976 total HAP for the facility) are from 16 HRSG bypass/waste heat stacks at SC-Vansant-VA, a HNR facility. The footprint of the SC-Vansant-VA facility, among other factors, does not allow for HRSGs. As such, all combusted flue gases are ducted continuously (8,760 hr/yr) to the HRSG bypass/waste heat stacks. Other HNR SunCoke facilities route combusted flue gas to HRSGs and then to a spray dryer absorber (SDA) and baghouse for SO2 and PM control. The SDA also controls HCl.

                                       
                                       
                                       
                                       
                                       
                                       
Table C-2. Coke Oven Emissions by Process, Facility, and Total, with Door Leak COE from Original Equation (TPY)
                                  Process ID
                      HAP Emissions (TPY)  -  Actuals[1]
                                       
                                ABC-Tarrant-AL
                               CC-Follansbee-WV
                               CC-Middletown-OH
                               CC-BurnsHarbor-IN
                                CC-Monessen-PA
                                 CC-Warren-OH
                               BLU-Birmingham-AL
                               EES-RiverRouge-MI
                               SC-EastChicago-IN
                             SC-FranklinFurnace-OH
                               SC-GraniteCity-IL
                               SC-Middletown-OH
                                 SC-Vansant-VA
                                USS-Clairton-PA
                            Process ID Total (TPY)
ByP Pushing (CD)
                                      3.7
                                     0.62
                                     0.13
                                      3.3
                                     0.44
                                     0.40
                                      2.4
                                      1.1
                                      --
                                      --
                                      --
                                      --
                                      --
                                      4.2
                                      16
ByP Battery (Combustion) Stack
                                      5.1
                                      10
                                      20
                                      22
                                      1.8
                                      6.6
                                      3.4
                                      18
                                      --
                                      --
                                      --
                                      --
                                      --
                                      31
                                      117
HRSG Main Stacks[2]
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      242
                                      353
                                      177
                                      24
                                       0
                                       0
                                      796
HRSG Bypass/waste Heat Stacks
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      280
                                      34
                                      24
                                      24
                                      964
                                      --
                                     1,326
HNR Pushing (CD)
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      1.2
                                     0.61
                                     0.39
                                     0.31
                                     0.48
                                      --
                                      3.0
Quench Tower
                                     0.29
                                     0.31
                                     0.22
                                      1.0
                                     0.19
                                     0.20
                                     0.19
                                     0.55
                                     0.72
                                     0.38
                                     0.24
                                     0.20
                                     0.39
                                      2.1
                                      7.0
Fugitive Pushing
                                     0.19
                                     0.045
                                     0.019
                                     0.13
                                     0.014
                                     0.031
                                     0.27
                                     0.087
                                     0.068
                                     0.036
                                     0.022
                                     0.019
                                     0.037
                                     0.019
                                      1.0
ByP Charging (oven port only)
                                     0.070
                                     0.068
                                     0.089
                                     0.29
                                     0.056
                                     0.074
                                     0.056
                                     0.035
                                      --
                                      --
                                      --
                                      --
                                      --
                                     0.29
                                      1.0
HNR Charging (CD)
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                    0.0067
                                    0.0053
                                    0.0033
                                    0.0028
                                    0.0032
                                       0
                                     0.021
Doors-Coke-Side
Original Equation
                                      1.1
                                      1.6
                                     0.69
                                      1.5
                                     0.35
                                     0.69
                                      1.0
                                     0.53
                                      --
                                      --
                                      --
                                      --
                                      --
                                      4.8
                                      12
Doors-Push-Side
 Original Equation
                                      1.1
                                      1.6
                                     0.69
                                      1.5
                                     0.35
                                     0.69
                                      1.0
                                     0.53
                                      --
                                      --
                                      --
                                      --
                                      --
                                      4.8
                                      12
Lids[3]
                                    0.0032
                                    0.00095
                                    0.00040
                                     0.019
                                       0
                                    0.0070
                                     0.016
                                    0.0015
                                      --
                                      --
                                      --
                                      --
                                      --
                                    0.0057
                                     0.054
Offtakes
                                    0.00020
                                     0.049
                                    0.00069
                                     0.019
                                    0.00084
                                     0.072
                                     0.028
                                    0.0038
                                      --
                                      --
                                      --
                                      --
                                      --
                                     0.19
                                     0.37
ByP Boiler Stacks[4]
                                      7.0
                                     0.57
                                     0.18
                                      1.8
                                     0.23
                                     0.47
                                      5.8
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      1.8
                                      18
Flare[5]
                                      1.7
                                      1.3
                                      1.5
                                      1.5
                                      2.3
                                      1.5
                                      1.0
                                      1.5
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      12
ByP Chemical Plant
                                      3.1
                                      4.6
                                      2.0
                                      4.1
                                      1.8
                                      4.4
                                      2.1
                                      2.8
                                      --
                                      --
                                      --
                                      --
                                      --
                                      23
                                      48
Co-located II&S[6]
                                      --
                                      --
                                      1.4
                                      78
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      --
                                      80
Other
                                       0
                                    0.00036
                                      3.7
                                     0.47
                                       0
                                     0.080
                                       0
                                       0
                                   0.0000075
                                     0.65
                                     0.36
                                       0
                                      11
                                     0.17
                                      16
Facility Total (TPY)
                                      23
                                      21
                                      30
                                      116
                                      7.6
                                      15
                                      17
                                      25
                                      302
                                      74
                                      45
                                      44
                                      976
                                      73
                                     2,468
                                       
[1] HAP emissions have been adjusted for nondetected values by using half of the MDL.
[2] No HRSG main stacks at SC-Vansant-VA.
[3] For Lids: ABC-Tarrant-AL and CC-Monessen-PA all batteries had no actual COE.
[4] No boiler at EES-RiverRouge-MI.
[5] No flares at USS-Clairton-PA.
[6] Co-located II&S at CC-Middletown-OH and CC-BurnsHarbor-IN.

                                  APPENDIX D
           Door Leak Emissions with Original and Alternate Equation
                                       

      Table D-1. Comparison of 2022 Door Leak Actual COE Estimates (TPY) 
                     With Original and Alternate Equation
                                   Facility
                               Coke Capacity TPY
                                Number of Ovens
                            Facility 2022 Average 
                            % Leaking Doors (Yard)
                              Estimated Door COE 
                                      TPY
                                       
                                       
                                       
                                       
                               Original Equation
                             Alternative Equation
ABC-Tarrant-AL
                                                                        699,967
                                      132
                                     0.82%
                                      2.3
                                      1.0
CC-Follansbee-WV
                                                                      1,346,000
                                      224
                                     0.44%
                                      3.2
                                     0.71
CC-Middletown-OH
                                                                        456,000
                                      76
                                     1.70%
                                      1.4
                                     0.70
CC-BurnsHarbor-IN
                                                                      1,900,000
                                      164
                                     2.30%
                                      3.0
                                      1.6
CC-Monessen-PA
                                                                        372,581
                                      56
                                     0.75%
                                     0.70
                                     0.031
CC-Warren-OH
                                                                        549,000
                                      85
                                     1.70%
                                      1.4
                                     0.54
BLU-Birmingham-AL
                                                                        596,775
                                      120
                                     1.40%
                                      2.0
                                     0.87
EES-RiverRouge-MI
                                                                      1,050,000
                                      85
                                     0.02%
                                      1.1
                                     0.053
USS-Clairton-PA
                                                                      6,422,997
                                      708
                                     0.54%
                                      9.7
                                      1.7






Table D-2. Door Leak Test and Emission Data (2022) by Battery and Facility  -  Alternative Equation
                                   Facility
                                  Battery ID
                     Total Number of Battery Doors (ND)[1]
                          2022 Percent Leaking Doors 
                             from Yard (PLDYARD) 
                        Determined by EPA Method 303[1]
                     COE Emission Rate from Door Leaks[2]
                                       
                                       
                                       
                                  By Battery
                               Facility Average
                                     lb/hr
                                      TPY
                                       
                                       
                                       
                                       
                                       
                                       
                                  By Battery
                                  By Facility
ABC-Tarrant-AL
Coke Battery #1
                                      156
                                     2.4%
                                     0.85%
                                     0.23
                                      1.0
                                      1.0
ABC-Tarrant-AL
Coke Battery #5
                                      50
                                    0.066%
                                       
                                    0.0020
                                    0.0089
                                       
ABC-Tarrant-AL
Coke Battery #6
                                      58
                                    0.040%
                                       
                                    0.0014
                                    0.0063
                                       
CC-Follansbee-WV
No. 1 Battery
                                      94
                                    0.081%
                                     0.44%
                                    0.0047
                                     0.021
                                     0.71
CC-Follansbee-WV
No. 2 Battery
                                      94
                                    0.081%
                                       
                                    0.0047
                                     0.021
                                       
CC-Follansbee-WV
No. 3 Battery
                                      102
                                    0.081%
                                       
                                    0.0051
                                     0.022
                                       
CC-Follansbee-WV
No. 8 Battery
                                      158
                                     1.5%
                                       
                                     0.15
                                     0.65
                                       
CC-Middletown-OH
Coke Oven Battery
                                      152
                                     1.7%
                                     1.7%
                                     0.16
                                     0.70
                                     0.70
CC-BurnsHarbor-IN
Battery #1
                                      164
                                     2.6%
                                     1.8%
                                     0.26
                                      1.1
                                      1.6
CC-BurnsHarbor-IN
Battery #2
                                      164
                                     1.1%
                                       
                                     0.11
                                     0.47
                                       
CC-Monessen-PA
Battery 1B
                                      74
                                    0.086%
                                     0.11%
                                    0.0039
                                     0.017
                                     0.031
CC-Monessen-PA
Battery 2
                                      38
                                     0.14%
                                       
                                    0.0032
                                     0.014
                                       
CC-Warren-OH
No. 4 Battery
                                      170
                                     1.2%
                                     1.2%
                                     0.12
                                     0.54
                                     0.54
BLU-Birmingham-AL
Coke Battery No. 3
                                      60
                                     1.63%
                                     1.4%
                                     0.060
                                     0.26
                                     0.87
BLU-Birmingham-AL
Coke Battery No. 4
                                      60
                                     1.62%
                                       
                                     0.060
                                     0.26
                                       
BLU-Birmingham-AL
Coke Battery No. 5
                                      120
                                     1.07%
                                       
                                     0.079
                                     0.35
                                       
EES-RiverRouge-MI
Coke Battery #5
                                      170
                                     0.12%
                                     0.12%
                                     0.012
                                     0.053
                                     0.053
USS-Clairton-PA
Battery 1
                                      128
                                     0.87%
                                     0.46%
                                     0.068
                                     0.30
                                      1.7
USS-Clairton-PA
Battery 2
                                      128
                                     0.85%
                                       
                                     0.067
                                     0.29
                                       
USS-Clairton-PA
Battery 3
                                      128
                                     0.47%
                                       
                                     0.037
                                     0.16
                                       
USS-Clairton-PA
Battery 13
                                      122
                                     0.18%
                                       
                                     0.014
                                     0.060
                                       
USS-Clairton-PA
Battery 14
                                      122
                                     0.22%
                                       
                                     0.016
                                     0.071
                                       
USS-Clairton-PA
Battery 15
                                      122
                                     0.39%
                                       
                                     0.029
                                     0.13
                                       
USS-Clairton-PA
Battery 19
                                      174
                                     0.29%
                                       
                                     0.031
                                     0.14
                                       
USS-Clairton-PA
Battery 20
                                      174
                                     0.29%
                                       
                                     0.031
                                     0.14
                                       
USS-Clairton-PA
B Battery
                                      150
                                     0.54%
                                       
                                     0.050
                                     0.22
                                       
USS-Clairton-PA
C Battery
                                      168
                                     0.50%
                                       
                                     0.052
                                     0.23
                                       
[1] From CAA 114 request .
[2] COEdoors (lb/hr) = ND x (PLDYARD/100) x (0.04 lb/hr) + ND x 0.94 x (PLDYARD/100) x (0.023 lb/hr). Leaks are assumed to occur 8,760 hours per year.

